Chiral metamaterials: simulations and experiments
TL;DR: In this article, the wave propagation properties of chiral metamaterials were studied and negative refraction was demonstrated in 3D isotropic chirality, with neither negative nor negative μ negative required.
Abstract: Electromagnetic metamaterials are composed of periodically arranged artificial structures. They show peculiar properties, such as negative refraction and super-lensing, which are not seen in natural materials. The conventional metamaterials require both negativeand negative μ to achieve negative refraction. Chiral metamaterial is a new class of metamaterials offering a simpler route to negative refraction. In this paper, we briefly review the history of metamaterials and the developments on chiral metamaterials. We study the wave propagation properties in chiral metamaterials and show that negative refraction can be realized in chiral metamaterials with a strong chirality, with neithernor μ negative required. We have developed a retrieval procedure, adopting a uniaxial bi-isotropic model to calculate the effective parameters such as n±, κ, � and μ of the chiral metamaterials. Our work on the design, numerical calculations and experimental measurements of chiral metamaterials is introduced. Strong chiral behaviors such as optical activity and circular dichroism are observed and negative refraction is obtained for circularly polarized waves in these chiral metamaterials. We show that 3D isotropic chiral metamaterials can eventually be realized.
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TL;DR: A number of intriguing phenomena and applications associated with metamaterials are discussed, including negative refraction, sub-diffraction-limited imaging, strong optical activities in chiral metamMaterials, interaction of meta-atoms and transformation optics.
Abstract: Metamaterials, artificial composite structures with exotic material properties, have emerged as a new frontier of science involving physics, material science, engineering and chemistry. This critical review focuses on the fundamentals, recent progresses and future directions in the research of electromagnetic metamaterials. An introduction to metamaterials followed by a detailed elaboration on how to design unprecedented electromagnetic properties of metamaterials is presented. A number of intriguing phenomena and applications associated with metamaterials are discussed, including negative refraction, sub-diffraction-limited imaging, strong optical activities in chiral metamaterials, interaction of meta-atoms and transformation optics. Finally, we offer an outlook on future directions of metamaterials research including but not limited to three-dimensional optical metamaterials, nonlinear metamaterials and “quantum” perspectives of metamaterials (142 references).
840 citations
TL;DR: This Progress Report highlights four different strategies which have been used to achieve giant chiroptical effects in chiral nanostructures, and presents two examples of chiral switches, where switching the chirality of incoming light causes a reversal of the handedness in the nanostructure.
Abstract: Strong chiroptical effects recently reported result from the interaction of light with chiral plasmonic nanostructures. Such nanostructures can be used to enhance the chiroptical response of chiral molecules and could also significantly increase the enantiomeric excess of direct asymmetric synthesis and catalysis. Moreover, in optical metamaterials, chirality leads to negative refractive index and all the promising applications thereof. In this Progress Report, we highlight four different strategies which have been used to achieve giant chiroptical effects in chiral nanostructures. These strategies consecutively highlight the importance of chirality in the nanostructures (for linear and nonlinear chiroptical effects), in the experimental setup and in the light itself. Because, in the future, manipulating chirality will play an important role, we present two examples of chiral switches. Whereas in the first one, switching the chirality of incoming light causes a reversal of the handedness in the nanostructures, in the second one, switching the handedness of the nanostructures causes a reversal in the chirality of outgoing light.
581 citations
TL;DR: In this article, the authors review the concepts, synthetic methods, and theoretical predictions underlying the chirality of metal colloids with a particular emphasis on the size range of 10-100 nanometers.
283 citations
TL;DR: The fundamental principles of chiral metamaterials are discussed, various optical chiral materials realized by different nanofabrication approaches, and the applications and future prospects of this emerging field are discussed.
Abstract: Optical chiral metamaterials have recently attracted considerable attention because they offer new and exciting opportunities for fundamental research and practical applications. Through pragmatic designs, the chiroptical response of chiral metamaterials can be several orders of magnitude higher than that of natural chiral materials. Meanwhile, the local chiral fields can be enhanced by plasmonic resonances to drive a wide range of physical and chemical processes in both linear and nonlinear regimes. In this review, we will discuss the fundamental principles of chiral metamaterials, various optical chiral metamaterials realized by different nanofabrication approaches, and the applications and future prospects of this emerging field.
268 citations
TL;DR: In this paper, the authors demonstrate tailored chiro-optical effects in plasmonic nanohelices, by a fabrication process providing a nanometer scale control on geometrical features, that leads to a fine tuning of operation band even in the visible range.
Abstract: The nanoscaling of metamaterial structures represents a technological challenge toward their application in the optical frequency range. In this work we demonstrate tailored chiro-optical effects in plasmonic nanohelices, by a fabrication process providing a nanometer scale control on geometrical features, that leads to a fine tuning of operation band even in the visible range. Helicoidal 3D nanostructures have been prototyped by a bottom-up approach based on focused ion and electron beam induced deposition, investigating resolution limits, growth control and 3D proximity effects as a function of the interactions between writing beam and deposition environment. The fabricated arrays show chiro-optical properties at the optical frequencies and extremely high operation bandwidth tailoring dependent on the dimensional features of these 3D nanostructures: with the focused ion beam we obtained a broadband polarization selection of about 600 nm and maximum dissymmetry factor up to 40% in the near-infrared regio...
215 citations
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TL;DR: The authors' simulations show that a version of the lens operating at the frequency of visible light can be realized in the form of a thin slab of silver, which resolves objects only a few nanometers across.
Abstract: Optical lenses have for centuries been one of scientists’ prime tools. Their operation is well understood on the basis of classical optics: curved surfaces focus light by virtue of the refractive index contrast. Equally their limitations are dictated by wave optics: no lens can focus light onto an area smaller than a square wavelength. What is there new to say other than to polish the lens more perfectly and to invent slightly better dielectrics? In this Letter I want to challenge the traditional limitation on lens performance and propose a class of “superlenses,” and to suggest a practical scheme for implementing such a lens. Let us look more closely at the reasons for limitation in performance. Consider an infinitesimal dipole of frequency v in front of a lens. The electric component of the field will be given by some 2D Fourier expansion,
10,974 citations
10,495 citations
TL;DR: These experiments directly confirm the predictions of Maxwell's equations that n is given by the negative square root ofɛ·μ for the frequencies where both the permittivity and the permeability are negative.
Abstract: We present experimental scattering data at microwave frequencies on a structured metamaterial that exhibits a frequency band where the effective index of refraction (n) is negative. The material consists of a two-dimensional array of repeated unit cells of copper strips and split ring resonators on interlocking strips of standard circuit board material. By measuring the scattering angle of the transmitted beam through a prism fabricated from this material, we determine the effective n, appropriate to Snell's law. These experiments directly confirm the predictions of Maxwell's equations that n is given by the negative square root of epsilon.mu for the frequencies where both the permittivity (epsilon) and the permeability (mu) are negative. Configurations of geometrical optical designs are now possible that could not be realized by positive index materials.
8,477 citations
TL;DR: In this paper, it was shown that microstructures built from nonmagnetic conducting sheets exhibit an effective magnetic permeability /spl mu/sub eff/, which can be tuned to values not accessible in naturally occurring materials.
Abstract: We show that microstructures built from nonmagnetic conducting sheets exhibit an effective magnetic permeability /spl mu//sub eff/, which can be tuned to values not accessible in naturally occurring materials, including large imaginary components of /spl mu//sub eff/. The microstructure is on a scale much less than the wavelength of radiation, is not resolved by incident microwaves, and uses a very low density of metal so that structures can be extremely lightweight. Most of the structures are resonant due to internal capacitance and inductance, and resonant enhancement combined with compression of electrical energy into a very small volume greatly enhances the energy density at critical locations in the structure, easily by factors of a million and possibly by much more. Weakly nonlinear materials placed at these critical locations will show greatly enhanced effects raising the possibility of manufacturing active structures whose properties can be switched at will between many states.
8,135 citations
TL;DR: A composite medium, based on a periodic array of interspaced conducting nonmagnetic split ring resonators and continuous wires, that exhibits a frequency region in the microwave regime with simultaneously negative values of effective permeability and permittivity varepsilon(eff)(omega).
Abstract: We demonstrate a composite medium, based on a periodic array of interspaced conducting nonmagnetic split ring resonators and continuous wires, that exhibits a frequency region in the microwave regime with
8,057 citations