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Patent

Coatings on glass

TL;DR: In this paper, a method of producing mirrors comprising depositing onto a ribbon of hot glass during the production process a coating comprising at least one pyrolytic reflecting layer and at least 1 color modifying layer whereby the mirrors exhibit color in reflectance and have a visible light reflection of at least 35 % and less than 70 %.
Abstract: A method of producing mirrors comprising depositing onto a ribbon of hot glass during the production process a coating comprising at least one pyrolytic reflecting layer and at least one color modifying layer whereby the mirrors exhibit color in reflectance and have a visible light reflection of at least 35 % and less than 70 %. There is also provided a mirror having such a coating.
Citations
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Journal ArticleDOI
TL;DR: Transparent conductors (TCs) have a multitude of applications for solar energy utilization and for energy savings, especially in buildings as discussed by the authors, which leads naturally to considerations of spectral selectivity, angular selectivity, and temporal variability of TCs, as covered in three subsequent sections.

1,471 citations

Journal ArticleDOI
TL;DR: In this paper, the photocatalytic degradation of malic acid was investigated on several rigid substrates, including glass and stainless steel, and the resulting materials have been characterized by XPS, SEM/EDX, XRD and UV-vis absorption spectroscopy.
Abstract: In the present study TiO 2 has been supported on several rigid substrates. Deposition on glass and quartz was carried out by a dip coating procedure and the deposition on stainless steel by an electrophoretic deposition process. The resulting materials have been characterized by XPS, SEM/EDX, XRD and UV-vis absorption spectroscopy. The materials were then tested for the photocatalytic degradation of malic acid. For this reaction, the sample supported on quartz showed the highest catalytic activity. The photocatalytic activity pattern as a function of the nature of the support (fused silica, glass, stainless steel) followed the decreasing order: TiO 2 /quartz > TiO 2 /steel ≈ TiO 2 /glassaphotolysis. This decline in activity has been correlated with the presence of cationic impurities (Si 4+ , Na + , Cr 3+ , Fe 3+ ) in the layer as a consequence of the necessary thermal treatments to improve the cohesion of the titania layer and its adhesion onto the support.

471 citations

Journal ArticleDOI
TL;DR: In this article, ZnO:Al films were prepared on glass substrates with different sputter techniques from ceramic and metallic targets using a wide range of deposition parameters and the correlation of sputter parameters, film growth and structural properties was discussed in terms of a modified Thornton model.

367 citations

Patent
22 Feb 2002
TL;DR: In this article, the subject of the paper is a glass-, ceramic, or vitroceramic-based substrate provided on at least part of at least one of its faces with a coating with a photocatalytic property containing at least partially crystalline titanium oxide.
Abstract: The subject of the invention is a glass-, ceramic- or vitroceramic-based substrate (1) provided on at least part of at least one of its faces with a coating (3) with a photocatalytic property containing at least partially crystalline titanium oxide. It also relates to the applications of such a substrate and to its method of preparation.

299 citations

Book ChapterDOI
TL;DR: Ortiz and Gioia as discussed by the authors reviewed some recent developments based on the use of direct methods of the calculus of variations which have proven useful for understanding the mechanics of folding of thin films.
Abstract: In this article, we specifically concern ourselves with the buckling-driven delamination mechanism, whereby a portion of the film buckles away from the substrate, thereby forming a blister (also termed buckle or wrinkle). Blisters may grow by interfacial fracture, a process which, under the appropriate conditions, may result in the catastrophic failure of the component. Blisters are often observed to adopt convoluted-even bizarre shapes and to fold into intricate patterns. A principal objective of this article is to review some recent developments based on the use of direct methods of the calculus of variations which have proven useful for understanding the mechanics of folding of thin films (Ortiz and Gioia, 1994). These developments are reviewed in Section III, which is extracted from the original publication. The remaining sections are devoted to the application of these principles to the problem of predicting the shape of thin-film blisters.

249 citations

References
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Patent
07 May 1981
TL;DR: In this article, the authors describe transparent glass window structures of the type bearing a coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a reflective coating is markedly reduced by provision of a very thin coating system beneath said infra red reflective coating.
Abstract: This disclosure describes transparent glass window structures of the type bearing a coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a reflective coating is markedly reduced by provision of a very thin coating system beneath said infra-red reflective coating. The thin coating system forms means to reflect and refract light to interfere with the observation of iridescence. A particular advantage of the invention is the ability of the thin coating system to be coated in a fraction of time presently required to coat anti-iridescent interlayers of the prior art.

316 citations

Patent
25 Oct 1990
TL;DR: A spectrally selective, glare-reducing mirror for vehicles which includes a substrate having a multi-layer coating on one side was proposed in this paper. But the results were limited to a blue reflecting mirror with luminous reflectance between about 35% and 60%.
Abstract: A spectrally selective, glare-reducing mirror for vehicles which includes a substrate having a multi-layer coating on one side. The multi-layer coating includes a thin, transparent dielectric layer, preferably of titanium dioxide at a thickness of about 600-650 angstroms, and a very thin layer of metal, preferably of aluminum or silver, at a thickness of between about 25 and 150 angstroms. The dielectric layer is closest to a source of incident light to be reflected by the mirror. When applied to the rear surface of a transparent substrate such as glass, the metal layer may also be coated with light absorbing material such as paint for protection and reduction in unwanted reflections. In the preferred dielectric and metal thicknesses, a blue reflecting mirror results having a glare-reducing luminous reflectance between about 35% and 60%, while costs are reduced due to lesser required amounts of metal than in prior known mirrors.

195 citations

Patent
20 Apr 1990
TL;DR: A two-layer antireflective coating composition stacked on a substrate consisting of allyl diglycol carbonate polymer (CR-39) or glass and comprising a bottom layer containing less than 10% by weight of titanium dioxide equivalent weight and a titanium-free top layer containing polysiloxane resin is presented in this paper.
Abstract: A two-layer antireflective coating composition stacked on a substrate consisting of allyl diglycol carbonate polymer (CR-39) or glass and comprising a bottom layer containing less than 10% by weight of titanium dioxide equivalent weight and a titanium-free top layer containing polysiloxane resin; and a process for preparing said antireflective coating with improved adhesion on a substrate consisting of allyl diglycol carbonate polymer (CR-39) or glass. The thicknesses of each of said coating layers is in accordance with preselected equations, and the refractive indices of a said coating layers satisfy the following requirements: n.sub.s n.sub.t wherein n s represents the refractive index of the substrate consisting of allyl diglycol carbonate polymer (CR-39) or glass, n b represents the refractive index of the bottom layer, and n t represents the refractive index of the top layer.

131 citations

Patent
19 Jan 1976
TL;DR: In this article, an optically clear, electrically conductive, transparent coating on a substrate and a method of coating were disclosed, which comprises a first transparent layer deposited as TiO x on the substrate, where x preferably has a value within the range of 1.3 to 1.7, a layer of silver or gold deposited on the first layer, and a third transparent layer of TiO X on the second layer.
Abstract: An optically clear, electrically conductive, transparent coating on a substrate and a method of coating are disclosed. The coating comprises a first transparent layer deposited as TiO x on the substrate, where x preferably has a value within the range of 1.3 to 1.7, a layer of silver or gold deposited on the first layer, and a third transparent layer deposited as TiO x on the second layer, where x preferably has a value within the range of 1.3 to 1.7. The coating is deposited under vacuum in a partial pressure of oxygen on a rigid transparent substrate such as glass or a flexible plastic substrate and the resultant coated substrate used in electrically heated windows.

104 citations

Patent
10 Apr 1986
TL;DR: In this article, a drug releasing system in the form of a medical patch comprised of a drug dispensing polyurethane member as a matrix for a therapeutically effective amount of drug dispersed therein.
Abstract: A drug releasing system in the form of a medical patch comprised of a drug dispensing polyurethane member as a matrix for a therapeutically effective amount of drug dispersed therein. The polyurethane of the drug dispensing or releasing member is a polyurethane acrylic copolymer which is the reaction product of an oligomer of a diisocyanate, a glycol with a molecular weight between the range of 500-5,000 molecular weight units and an acrylyl chain terminator having a molecular weight between the range of 40-200 molecular weight units cured by actinic radiation. In its preferred embodiment, the foregoing drug releasing or dispensing member is incorporated into a medical patch or drug release system comprised of successive layers of an ultrathin polyurethane substrate, pressure sensitive adhesive, the above-described drug releasing member and optionally a second layer of adhesive. The drug release system of the present invention is biocompatible, oxygen and water vapor permeable, flexible and can incorporate a wide variety of drugs for a controlled, sustained release to the wearer.

82 citations