Combustion of fat and vegetable oil derived fuels in diesel engines
TL;DR: In this paper, the status of fat and oil derived diesel fuels with respect to fuel properties, engine performance, and emissions is reviewed, and it is concluded that the price of the feedstock fat or oil is the major factor determining biodiesel price.
About: This article is published in Progress in Energy and Combustion Science.The article was published on 1998-01-01. It has received 1869 citations till now. The article focuses on the topics: Diesel fuel & Biodiesel.
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TL;DR: The most important variables affecting methyl ester yield during the transesterification reaction are the molar ratio of alcohol to vegetable oil and the reaction temperature as discussed by the authors, which is the commonly used alcohol in this process, due to its low cost.
1,798 citations
Cites background from "Combustion of fat and vegetable oil..."
...Methanol is preferred because it is less expensive than ethanol [158]....
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TL;DR: In this article, the authors collected and analyzed the body of work written mainly in scientific journals about diesel engine emissions when using biodiesel fuels as opposed to conventional diesel fuels, focusing on the most concerning emissions: nitric oxides and particulate matter.
1,768 citations
TL;DR: A review of the research related to biodiesel can be found in this paper, where solid acid catalysts are used to replace liquid acids, reducing the corrosion and environmental problems associated with them.
Abstract: Biodiesel is synthesized via the transesterification of lipid feedstocks with low molecular weight alcohols. Currently, alkaline bases are used to catalyze the reaction. These catalysts require anhydrous conditions and feedstocks with low levels of free fatty acids (FFAs). Inexpensive feedstocks containing high levels of FFAs cannot be directly used with the base catalysts currently employed. Strong liquid acid catalysts are less sensitive to FFAs and can simultaneously conduct esterification and transesterification. However, they are slower and necessitate higher reaction temperatures. Nonetheless, acid-catalyzed processes could produce biodiesel from low-cost feedstocks, lowering production costs. Better yet, if solid acid catalysts could replace liquid acids, the corrosion and environmental problems associated with them could be avoided and product purification protocols reduced, significantly simplifying biodiesel production and reducing cost. This article reviews some of the research related to biodi...
1,606 citations
TL;DR: In this article, a detailed review has been conducted to highlight different related aspects to the biodiesel industry, including, biodiesel feedstocks, extraction and production methods, properties and qualities of biodiesel, problems and potential solutions of using vegetable oil, advantages and disadvantages of biodies, the economical viability and finally the future of the future biodiesel.
Abstract: As the fossil fuels are depleting day by day, there is a need to find out an alternative fuel to fulfill the energy demand of the world. Biodiesel is one of the best available resources that have come to the forefront recently. In this paper, a detailed review has been conducted to highlight different related aspects to biodiesel industry. These aspects include, biodiesel feedstocks, extraction and production methods, properties and qualities of biodiesel, problems and potential solutions of using vegetable oil, advantages and disadvantages of biodiesel, the economical viability and finally the future of biodiesel. The literature reviewed was selective and critical. Highly rated journals in scientific indexes were the preferred choice, although other non-indexed publications, such as Scientific Research and Essays or some internal reports from highly reputed organizations such as International Energy Agency (IEA), Energy Information Administration (EIA) and British Petroleum (BP) have also been cited. Based on the overview presented, it is clear that the search for beneficial biodiesel sources should focus on feedstocks that do not compete with food crops, do not lead to land-clearing and provide greenhouse-gas reductions. These feedstocks include non-edible oils such as Jatropha curcas and Calophyllum inophyllum , and more recently microalgae and genetically engineered plants such as poplar and switchgrass have emerged to be very promising feedstocks for biodiesel production. It has been found that feedstock alone represents more than 75% of the overall biodiesel production cost. Therefore, selecting the best feedstock is vital to ensure low production cost. It has also been found that the continuity in transesterification process is another choice to minimize the production cost. Biodiesel is currently not economically feasible, and more research and technological development are needed. Thus supporting policies are important to promote biodiesel research and make their prices competitive with other conventional sources of energy. Currently, biodiesel can be more effective if used as a complement to other energy sources.
1,496 citations
01 Mar 2011
TL;DR: The conceptual design presented in this paper reports ethanol production economics as determined by 2012 conversion targets and 'nth-plant' project costs and financing for the biorefinery described here, processing 2,205 dry ton/day at 76% theoretical ethanol yield.
Abstract: This report describes one potential biochemical ethanol conversion process, conceptually based upon core conversion and process integration research at NREL. The overarching process design converts corn stover to ethanol by dilute-acid pretreatment, enzymatic saccharification, and co-fermentation. Building on design reports published in 2002 and 1999, NREL, together with the subcontractor Harris Group Inc., performed a complete review of the process design and economic model for the biomass-to-ethanol process. This update reflects NREL's current vision of the biochemical ethanol process and includes the latest research in the conversion areas (pretreatment, conditioning, saccharification, and fermentation), optimizations in product recovery, and our latest understanding of the ethanol plant's back end (wastewater and utilities). The conceptual design presented here reports ethanol production economics as determined by 2012 conversion targets and 'nth-plant' project costs and financing. For the biorefinery described here, processing 2,205 dry ton/day at 76% theoretical ethanol yield (79 gal/dry ton), the ethanol selling price is $2.15/gal in 2007$.
1,220 citations
References
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Book•
01 Jan 1988
TL;DR: In this article, the authors describe real engine flow and combustion processes, as well as engine operating characteristics and their operation, including engine design and operating parameters, engine characteristics, and operating characteristics.
Abstract: 1 Engine Types and Their Operations 2 Engine Design and Operating Parameters 3 Thermochemistry of Fuel-Air Mixtures 4 Properties of Working Fluids 5 Ideal Models of Engine Cycles 6 Gas Exchange Processes 7 SI Engine Fuel Metering and Manifold Phenomena 8 Charge Motion within the Cylinder 9 Combustion in Ignition Engines 10 Combustion in Compression Ignition Engines 11 Pollutant Formation and Control 12 Engine Heat Transfer 13 Engine Friction and Lubrication 14 Modeling Real Engine Flow and Combustion Processes 15 Engine Operating Characteristics Appendixes
14,372 citations
Book•
01 Jan 1958
TL;DR: Plant design and economics for chemical engineers, Plant design for chemical engineering, and plant design for plant design and economic analysis are discussed in this paper, where the authors propose a plant design approach based on chemical engineering.
Abstract: Plant design and economics for chemical engineers , Plant design and economics for chemical engineers , مرکز فناوری اطلاعات و اطلاع رسانی کشاورزی
3,016 citations
TL;DR: In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.
2,843 citations
TL;DR: In this paper, the authors showed that the conversion to methyl, ethyl and butyl esters from cottonseed, peanut, soybean and sunflower oils can be done in 1 hr with an alkaline catalyst.
Abstract: Transesterification reaction variables that affect yield and purity of the product esters from cottonseed, peanut, soybean and sunflower oils include molar ratio of alcohol to vegetable oil, type of catalyst (alkaline vs acidic), temperature and degree of refinement of the vegetable oil. With alkaline catalysts (either sodium hydroxide or methoxide), temperatures of 60 C or higher, molar ratios of at least 6 to 1 and with fully refined oils, conversion to methyl, ethyl and butyl esters was essentially complete in 1 hr. At moderate temperatures (32 C), vegetable oils were 99% transesterified in ca. 4 hr with an alkaline catalyst. Transesterification by acid catalysis was much slower than by alkali catalysis. Although the crude oils could be transesterified, ester yields were reduced because of gums and extraneous material present in the crude oils.
1,990 citations
TL;DR: In this paper, the authors compared the performance of soybean oil with diesel fuel and found that the diesel engine performance with soybean ester fuels differed little from engine performance when compared with diesel.
Abstract: The primary problems associated with using straight soybean oil as a fuel in a compression ignition internal combustion engine are caused by high fuel viscosity. Transesterification of soybean oil with an alcohol provides a significant reduction in viscosity, thereby enhancing the physical properties of the renewable fuel to improve engine performance. The ethyl and methyl esters of soybean oil with commercial diesel fuel additives revealed fuel properties that compared very well with diesel fuel, with the exception of gum formation, which manifested itself in problems with the plugging of fuel filters. Engine performance using soybean ester fuels differed little from engine performance with diesel fuel. A slight power loss combined with an increase in fuel consumption were experienced with the esters, primarily because of the lower heating value of the esters than for diesel fuel. Emissions for the 2 fuels were similar, with nitrous oxide emissions higher for the esters. Measurements of engine wear and fuel-injection system tests showed no abnormal characteristics for any of the fuels after the 200-hr tests. Engine deposits were comparable in amount, but slightly different in color and texture, with the methyl ester engine experiencing greater carbon and varnish deposits on the pistons.
341 citations