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Comparison of the state of Lithium-Sulphur and lithium-ion batteries applied to electromobility.

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TLDR
This paper presents a review of the state of art of Li-Sulphur battery on EVs compared to Li-ion ones, considering technical, modelling, environmental and economic aspects with the aim of depicting the challenges this technology has to overcome to substituteLi-ion in the near future.
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This article is published in Journal of Environmental Management.The article was published on 2018-11-15 and is currently open access. It has received 55 citations till now. The article focuses on the topics: Electric vehicle & Battery (electricity).

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Citations
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Journal ArticleDOI

Towards establishing standard performance metrics for batteries, supercapacitors and beyond.

TL;DR: An overview of the energy storage devices from conventional capacitors to supercapacitors to hybrid systems and ultimately to batteries is provided, although the focus is kept on capacitive and hybrid energy storage systems.
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Lithium-Sulfur Batteries under Lean Electrolyte Conditions: Challenges and Opportunities.

TL;DR: In this article, the impact of the electrolyte/sulfur ratio on the actual energy density and the economic cost of Li-S batteries is addressed, and challenges and recent progress are presented in terms of the sulfur electrochemical processes: the dissolution-precipitation conversion and the solid-solid multi-phasic transition.
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Future material demand for automotive lithium-based batteries

TL;DR: In this paper, the authors quantify the future demand for key battery materials, considering potential electric vehicle fleet and battery chemistry developments as well as second-use and recycling of electric vehicle batteries.
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Second life batteries lifespan: Rest of useful life and environmental analysis

TL;DR: 2nd life battery lifespan clearly depends on its use, going from about 30 years in fast electric vehicle charge support applications to around 6 years in area regulation grid services, and this study states that grid oriented energy storage applications will hardly offer environmental benefits in the nearby future.
Journal ArticleDOI

Review of energy storage systems for vehicles based on technology, environmental impacts, and costs

TL;DR: A review of energy systems for light-duty vehicles and highlights the main characteristics of electric and hybrid vehicles based on power train structure, environmental perspective, and cost is presented in this paper.
References
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Journal ArticleDOI

Li-O2 and Li-S batteries with high energy storage.

TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
Journal ArticleDOI

Towards greener and more sustainable batteries for electrical energy storage

TL;DR: The notion of sustainability is introduced through discussion of the energy and environmental costs of state-of-the-art lithium-ion batteries, considering elemental abundance, toxicity, synthetic methods and scalability.
Journal ArticleDOI

Li-ion battery materials: present and future

TL;DR: In this article, a review of the key technological developments and scientific challenges for a broad range of Li-ion battery electrodes is presented, and the potential/capacity plots are used to compare many families of suitable materials.
Journal ArticleDOI

Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries

TL;DR: In this article, the authors show that 2 and 5 times higher energy densities are required to meet the performance goals of a future generation of plug-in hybrid-electric vehicles (PHEVs) with a 40-80 mile all-electric range, and all-EVs with a 300-400 mile range, respectively.
Journal ArticleDOI

Accurate electrical battery model capable of predicting runtime and I-V performance

TL;DR: An accurate, intuitive, and comprehensive electrical battery model is proposed and implemented in a Cadence environment that accounts for all dynamic characteristics of the battery, from nonlinear open-circuit voltage, current-, temperature-, cycle number-, and storage time-dependent capacity to transient response.
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Frequently Asked Questions (12)
Q1. What have the authors contributed in "Comparison of the state of lithium-sulphur and lithium-ion batteries applied to electromobility" ?

Although EVs are suitable for the day-to-day needs of the typical urban driver, their range is still lower than ICEV, because batteries are not able to store and supply enough energy to the vehicle and provide the same autonomy as ICEV. At present, the most promising technology is the Lithium-Sulphur ( Li-S ) 

Power limitations of Li-ion batteries are governed by the diffusion of ions into the electrodes, which is mainly defined by the battery design and therefore not considered to vary rapidly with normal usage. 

Li-S batteries are theoretically considered to have lower environmental impact due to the use of Sulphur, which is an element relatively abundant on Earth, that makes of it a non-toxic inexpensive material (Peled et al., 2017b). 

Li-S battery modelling focus the attention on electrochemical models, to fully understand its behaviour, and are now doing their first steps into ECN models, which are the ones preferred for EV applications. 

Li-S batteries have emerged as a promising battery technology due to the positive consequences of replacing metals in the cathode of typical Li-ion batteries by Sulphur. 

At present, one of the most promising technologies is Lithium-Sulphur (Li-S) not only for their higher theoretical energy density (about 2600 Wh/kg) but also for the relatively inexpensive and nonpoisonous materials used in their manufacture that are expected to reduce the overall battery price and environmental impact (Peng et al., 2017). 

EVs have an average driving distance of 250 Km (Fotouhi et al., 2017b)(Bonges and Lusk, 2016), while conventional ICEVs may achieve 1000 Km. 

EVs technology development and its deployment goes hand by hand with the advances in portable energy storage devices: the battery. 

Li-S batteries have a theoretical energy density of around 2600 Wh/kg, an entire magnitude of order higher than typical Li-ion batteries (Manthiram et al., 2013). 

Li-S batteries have 8-15% self-discharge rate per month (Kolosnitsyn and Karaseva, 2008)(V. Knap et al., 2016) due to polysulfide shuttle (Mikhaylik and Akridge, 2004) and collector corrosion (Song et al., 2013), (Vaclav Knap et al., 2016), (Marinescu et al., 2015), which is between 10 and 15 times higher than the selfdischarge of Li-ion batteries (Table 1). 

For a consistent environmental assessment, LCA should define clear boundary conditions to delimit the scope of the analysis and then consider all the steps within, such as raw materials acquisition, energy consumption to produce parts, transportation, etc...LCA studies may then cover life cycle stages up to the production of the battery (cradle-to- gate studies) or their full life cycle, including use-phase and end of life (cradle-to- grave)The environmental impact of actual Li-ion batteries is said to be responsible of almost half of the whole environmental impact of the EV manufacture. 

the current knowledge in Li-S battery behaviour has to improve in order to be applied in such ECN models and, it needs to be improved for its further application in EVs.