Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates
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This article is published in Chemical Reviews.The article was published on 2014-09-09 and is currently open access. It has received 1397 citations till now. The article focuses on the topics: Catalysis.read more
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Catalysis of Radical Reactions: A Radical Chemistry Perspective.
Armido Studer,Dennis P. Curran +1 more
TL;DR: This work critically address both catalyst-free and catalytic radical reactions through the lens of radical chemistry, using basic principles of kinetics and thermodynamics to address problems of initiation, propagation, and inhibition of radical chains.
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Stronger Brønsted Acids: Recent Progress.
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Enantioselective catalysis of photochemical reactions.
TL;DR: This Review outlines the two major concepts of homogenously catalyzed enantioselective processes and reactions are presented in which the photochemical excitation is mediated by an achiral photocatalyst and the transfer of chirality is ensured by a second chiral catalyst (dual catalysis).
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Bifunctional Amine‐Squaramides: Powerful Hydrogen‐Bonding Organocatalysts for Asymmetric Domino/Cascade Reactions
TL;DR: This review highlights the advances in the rapidly growing field of amine-squaramide-catalyzed domino/cascade reactions and their mode of action.
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Enhancing the potential of enantioselective organocatalysis with light
Mattia Silvi,Paolo Melchiorre +1 more
TL;DR: The historical context, scientific reasoning and landmark discoveries that were essential in expanding the functions of organocatalysis to include one-electron-mediated chemistry and excited-state reactivity are described.
References
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Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
TL;DR: The focus of this review is on the area of enantioselective transition metal-catalyzed allylic alkylations which may involve C-C as well as C-X (X ) H or heteroatom) bond formation.
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In the Golden Age of Organocatalysis
Peter I. Dalko,Lionel Moisan +1 more
TL;DR: The diverse examples show that in recent years organocatalysis has developed within organic chemistry into its own subdiscipline, whose "Golden Age" has already dawned.
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Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
TL;DR: Alkylations with Phenols, Nitrogen Nucleophiles in AAA Total Synthesis, and Considerations for Enantioselective Allylic Alkylation are presented.
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Small-molecule H-bond donors in asymmetric catalysis.
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The advent and development of organocatalysis
TL;DR: My opinion on why the field of organocatalysis has blossomed so dramatically over the past decade is presented.