Complexes of molybdenum (V) oxide trichloride with nitrogen and phosphorus ligands
TL;DR: In this article, the reaction of molybdenum (V) oxidetrichloride with aliphatic nitriles (RCN, R = Me, Et, Pr) results in the formation of the complexes, MoOCl 3, 2RCN.
About: This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1965-02-01. It has received 27 citations till now. The article focuses on the topics: Phenanthroline & Nitrile.
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TL;DR: A review of the metal-to-ligand bonding is given in this article, with an emphasis on the analytical uses of these ligands, such as the synthesis of ring-substituted derivatives of the parent ligands.
Abstract: Publisher Summary In this chapter, one attempts to present a review giving emphasis to these new fields, and to this end as much material as possible has been subdivided under the headings of the various techniques and types of information. As a result of the chosen subdivision, certain aspects, such as the nature of the metal-to-ligand bonding are discussed in more than one section. Little mention will be made of the analytical uses of these ligands, which have recently been reviewed separately (711), of the synthesis of ring-substituted derivatives of the parent ligands, although a potentially useful method using transition-metal complexes has been reported; or of related species, such as 4,4‘-bipyridyl. The coverage of the literature is complete up to the end of 1967, and usually to the end of April 1968, and although many publications have regretfully not been mentioned, one have attempted to discuss the great majority of those papers which one believe to be of special importance.
235 citations
09 Mar 2007
78 citations
TL;DR: In this paper, it has been shown that the oxometal entity MoO3+ remains intact under various physicochemical methods and that the expected cis-trans isomers of MoOCl3·bipy has also been discussed.
25 citations
TL;DR: The mechanism of the conversion of 1 to 3 is complex, but one of the intermediates, MoOCl3(PMe3)2 (4), can be isolated and crystallized, if 1 is reacted only with 3 instead of 5 equiv of PMe3 as discussed by the authors.
Abstract: The reaction of [Cl2OMo(μ-OC2H5)2(μ-HOC2H5)MoOCl2] (1) with 5 equiv of PMe3 provides a simple route to pure mer-MoOCl2(PMe3)3 (3), so that its crystal structure could be determined [C9H27Cl2MoOP3, monoclinic, P21/c, a = 17.138(3) A, b = 12.808(3) A, c = 19.226(4) A, β = 115.99(1)°, Z = 8]. The mechanism of the conversion of 1 to 3 is complex, but one of the intermediates, MoOCl3(PMe3)2 (4), can be isolated and crystallized, if 1 is reacted only with 3 instead of 5 equiv of PMe3. 4 further reacts with an excess of PMe3 to yield 3, providing additional evidence for its intermediacy. The crystal structure of 4 could be determined [C6H18Cl3MoOP2, monoclinic, P21/n, a = 6.468(1) A, b = 12.677(2) A, c = 17.791(2) A, β = 92.64(1)°, Z = 4]. If 4 is not isolated directly after the reaction and its crystallization is attempted from the raw mixture, two different compounds are obtained and their crystal structures were determined: MoOCl3(OPMe3)(PMe3) (5) [C6H18Cl3MoO2P2, monoclinic, P21/n, a = 6.783(3) A, b = 12.62...
24 citations
TL;DR: In this article, it has been shown that the oxometal entity MoO 3+ remains intact under various physicochemical methods and the probable constitution of expected cis-trans isomers of MoOCl 3 ·phen has also been discussed.
21 citations
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TL;DR: In this paper, the preparation and chemical properties of molybdenum(V) with 2:2′-dipyridyl are described and possible structures of the complexes are discussed.
57 citations