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Complexes of rhenium with benzoylazo and related ligands. Crystal and molecular structures of...

Terence Nicholson, +1 more
- 01 Jan 1988 - 
- Vol. 7, Iss: 3, pp 171-185
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Technetium and gallium derived radiopharmaceuticals: comparing and contrasting the chemistry of two important radiometals for the molecular imaging era.

TL;DR: Mark Daniel Bartholomä was born in Neunkirchen (Germany) and received his diploma (2002) and his doctoral degree (2007) from the Saarland University in Saarbrücken ( Germany) under the supervision of Prof. Kaspar Hegetschweiler on the synthesis and complex formation of multidentate derivatives of 1,3,5-triamino-1,3-5-trideoxy-cis-inositol.
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Single amino acid chelates (SAAC): a strategy for the design of technetium and rhenium radiopharmaceuticals.

TL;DR: This work focuses on the design of single amino acid chelates (SAACs), novel bifunctional chelators constructed from derivatized amino acids or amino acid analogues, and affords significant flexibility in the choice of donors for (99m)Tc coordination combined with the considerable advantages of routine solid phase synthetic techniques.
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New directions in the coordination chemistry of 99mTc: a reflection on technetium core structures and a strategy for new chelate design.

TL;DR: It is concluded that the single amino acid analogue chelates (SAAC), which are readily conjugated to small peptides by solid-phase synthesis methods and which form robust complexes with the {Tc(CO)3}1+ core, offer an effective alternative to the previously described methods.
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Preparation of hydrazino-modified proteins and their use for the synthesis of 99mTc-protein conjugates.

TL;DR: The syntheses and protein linking properties of succinimidyl 4-hydrazinobenzoate hydrochloride (SHBH) and SHNH, two new heterobifunctional linkers which lead to hydrazino-modified proteins, are described.
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The coordination chemistry of substituted hydrazines

TL;DR: In this paper, a simple co-ordinative behaviour of bidentate figands is described, and the authors show that it is possible to construct dithiolene-like complexes with co-coordinated ligands.
Journal ArticleDOI

Some benzoylazo-complexes of rhenium halides with tertiary phosphines, and related compounds

TL;DR: In this paper, it was shown that oxotrichlorobis(triphenylphosphine) rhenium(V) reacts with monobenzoylhydrazine and dibenzoy-lhydroxine in benzene-ethanol in the presence of hydrochloric acid to give [N-benzoyl-hydrazido(3)-O,N′]dichloro-naphrin(trihexine)rhenium (V)
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