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Journal ArticleDOI

Conditions of Magma Storage, Degassing and Ascent at Stromboli: New Insights into the Volcano Plumbing System with Inferences on the Eruptive Dynamics

TL;DR: In this paper, an extensive dataset on major elements and volatiles (CO2, H2O, S and Cl) in olivine-hosted melt inclusions and embayments from pyroclasts emplaced during explosive eruptions of variable magnitude is presented.
Abstract: Stromboli is known for its persistent degassing and rhythmic strombolian activity occasionally punctuated by paroxysmal eruptions. The basaltic pumice and scoria emitted during paroxysms and strombolian activity, respectively, differ in their textures, crystal contents and glass matrix compositions, which testify to distinct conditions of crystallization, degassing and magma ascent. We present here an extensive dataset on major elements and volatiles (CO2, H2O, S and Cl) in olivine-hosted melt inclusions and embayments from pyroclasts emplaced during explosive eruptions of variable magnitude. Magma saturation pressures were assessed from the dissolved amounts of H2 Oa nd CO2 taking into account the melt composition evolution. Both pressures and melt inclusion compositions indicate that (1) Ca-basaltic melts entrapped in high-Mg olivines (Fo89^90) generate Stromboli basalts through crystal fractionation, and (2) the Stromboli plumbing system can be imaged as a succession of magma ponding zones connected by dikes. The 7^10 km interval, where magmas are stored and differentiate, is periodically recharged by new magma batches, possibly ranging from Ca-basalts to basalts, with a CO2-rich gas phase.These deep recharges promote the formation of bubbly basalt blobs, which are able to intrude the shallow plumbing system (2^4 km), where CO2 gas fluxing enhances H2O loss, crystallization and generation of crystal-rich, dense, degassed magma. Chlorine partitioning into the H2O^CO2-bearing gas phase accounts for its efficient degassing (� 69%) under the open-system conditions of strombolian activity. Paroxysms, however, are generated through predominantly closed-system ascent of basaltic magma batches from the deep storage zone. In this situation crystallization is negligible and sulfur exsolution starts at � 170 MPa. Chlorine remains dissolved in the melt until lower pressures, only 16% being lost upon eruption. Finally, we propose a continuum in explosive eruption energy, from strombolian activity to large paroxysmal events, ultimately controlled by variable pressurization of the deep feeding system associated with magma and gas recharges.
Citations
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Journal ArticleDOI
TL;DR: In this article, the authors studied the H2O contents of the least degassed melt inclusions from each volcano and found that the mean and common average values for H2Os are within one s.d.

400 citations


Cites background from "Conditions of Magma Storage, Degass..."

  • ...…Portnyagin et al., 2007; Johnson et al., 2009; Ruscitto et al., 2010), cross-arc water variations (Walker et al., 2003) the ascent of arc magmas (Blundy and Cashman, 2005), their differentiation (Zimmer et al., 2010) and eruption (Blundy et al., 2006; Metrich et al., 2010; Spilliaert et al., 2006)....

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Journal ArticleDOI
TL;DR: In this article, an alternative experimental approach aimed at directly simulating decompression-driven, closed-system degassing of basaltic magma in equilibrium with an H^C^O^S^Cl fluid under oxidized conditions (fO2 of 1·0^2· 4l og units above the Ni^NiO buffer).
Abstract: Magma degassing processes are commonly elucidated by studies of melt inclusions in erupted phenocrysts and measurements of gas discharge at volcanic vents, allied to experimentally constrained models of volatile solubility. Here we develop an alternative experimental approach aimed at directly simulating decompression-driven, closed-system degassing of basaltic magma in equilibrium with an H^C^O^S^Cl fluid under oxidized conditions (fO2 of 1·0^2· 4l og units above the Ni^NiO buffer). Synthetic experimental starting materials were based on basaltic magmas erupted at the persistently degassing volcanoes of Stromboli (Italy) and Masaya (Nicaragua) with an initial volatile inventory matched to the most undegassed melt inclusions from each volcano. Experiments were run at 25^400 MPa under super-liquidus conditions (11508C). Run product glasses and starting materials were analysed by electron microprobe, secondary ion mass spectrometry, Fourier transform infrared spectroscopy, Karl-Fischer titration, Fe 2þ /Fe 3þ colorimetry and CS analyser. The composition of the exsolved vapour in each run was determined by mass balance. Our results show that H2O/ CO2 ratios increase systematically with decreasing pressure, whereas CO2/S ratios attain a maximum at pressures of 100^300 MPa. S is preferentially released over Cl at low pressures, leading to a sharp increase in vapour S/Cl ratios and a sharp drop in the S/Cl ratios of glasses. This accords with published measurements of volatile concentrations in melt inclusion and groundmass glasses at Stromboli (and Etna). Experiments with different S abundances show that the H2O and CO2 contents of the melt at fluid saturation are not affected. The CO2 solubility in experiments using both sets of starting materials is well matched to calculated solubilities using published models. Models consistently overestimate H2O solubilities for the Stromboli-like composition, leading to calculated vapour compositions that are more CO2-rich and calculated degassing trajectories that are more strongly curved than observed in experiments. The difference is less acute for the Masaya-like composition, emphasizing the important compositional dependence of solubility and melt^ vapour partitioning. Our novel experimental method can be readily extended to other bulk compositions.

148 citations

Journal ArticleDOI
TL;DR: In this article, the authors used the MultiGAS technique to provide the best documented record of gas plume discharges from Stromboli volcano to date, and showed that Strombolian's gases are dominated by H2O (48−98−mol); mean, 80%), and by CO2 (2−50−mol%; mean, 17%) and SO2 (0.2−14−mol; mean, 3%).

144 citations


Cites background or methods or result from "Conditions of Magma Storage, Degass..."

  • ...In the attempt to provide a comprehensivemodel of degassing, we integrate here our volcanic gas observations with recent determinations of volatile contents in melt inclusions (Métrich et al., 2010); and we compare the natural (volcanic gas and MI) data with results from the Moretti and Papale (2004) equilibrium saturation model, which we use to numerically reproduce the degassing trends of Stromboli's magmas upon their ascent and decompression....

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  • ...Our focus is on the routine Strombolian activity, making our study complementary to recent work (Métrich et al., 2010; Allard, 2010) on the genetic mechanisms of the Stromboli's large scale explosions....

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  • ...In spite of this existing knowledge, the structure of the deep and shallow plumbing system is still a matter of debate (Métrich et al., 2010; Pichavant et al., 2009), and information of volcanic gas compositions is still fragmentary, particularly for H2O....

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  • ...%) content is consistent with melt inclusion evidences (Métrich et al., 2010); the run at 20% CO2 content should only be viewed as an endmember composition calculation (and not an authentic representation of the natural case)....

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  • ...7a) indicate entrapment pressures of ∼50–100 MPa pressure (Métrich et al., 2010), confirming that a change from closed- to open-system degassing regime (with the consequent water depletion being the trigger for transition from LP to HP magma) occurs in the 2–4 km bsv depth range....

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Journal ArticleDOI
TL;DR: The olivine macrocrysts found in oceanites, picrites and magnesian basalts erupted at hotspot volcanoes are generally interpreted either as phenocrysts crystallized from the magma or as xenocrysts extracted from a deforming cumulate as mentioned in this paper.
Abstract: The olivine macrocrysts found in oceanites, picrites and magnesian basalts erupted at hotspot volcanoes are generally interpreted either as phenocrysts crystallized from the magma or as xenocrysts extracted from a deforming cumulate. To constrain the origin of these crystals we studied their texture and composition at Piton de la Fournaise volcano, La Reunion. We show that macrocrysts are organized and subdivided into parallel units; this suggests a crystallization by dendritic growth and ripening rather than by a complex combination of paired nucleation, crystal aggregation or synneusis. Dendritic growth is also evidenced by the occurrence of hollow faces, P-rich zones, melt and Cr-spinel inclusions formed from the accumulation of slow diffusing impurities (P, Cr, Al) in the liquid at the contact with rapid-growing olivine. We suggest that early dendritic crystallization may even cause branch misorientations and lattice mismatches, yielding subgrain boundaries, dislocation lamellae and to a certain extent undulose extinction, which have all been formerly interpreted in terms of plastic intracrystalline deformation. We interpret olivine macrocrysts as phenocrysts crystallized under a strong degree of undercooling (-ΔT > 60°C), and derived from a harrisitic mush formed on the cold walls of the magma reservoir. Given the growth shapes indicated by P zoning patterns and external faces, the olivine macrocrysts (which consist of groups of several subcrystals) have grown in suspension within the liquid and were neither aggregated into a dense cumulate nor corroded, shocked or deformed before or during their transport to the surface. The major consequence of our study is that most olivine macrocrysts are not xenocrysts, and very few of them, if any, have experienced intracrystalline deformation. The importance of deforming (creeping) cumulate bodies, thought to accommodate the spreading of basaltic volcanoes in La Reunion and Hawaii, may hence have been overestimated.

136 citations

Book ChapterDOI
01 Jan 2015
TL;DR: Hawaiian and Strombolian eruptions are characteristic of silica-poor, low viscosity magmas and represent the most frequent manifestations of explosive volcanism on Earth as mentioned in this paper.
Abstract: Hawaiian and Strombolian eruption styles are characteristic of silica-poor, low viscosity magmas and represent the most frequent manifestations of explosive volcanism on Earth. In these eruption styles, the violent release of relatively large volumes of magma decoupled from the melt ejects coarse, still molten pyroclasts. Strombolian eruptions involve the complex bursting of gas pockets at the volcanic vent, while Hawaiian eruptions are best described as the fountaining of sustained jets of gas and fluidal pyroclasts. Transitions between these two styles and their variations are linked to the amount and chemical composition of the magmatic gases that drive the eruptions and to the way gas pockets segregate from the magma and migrate along the volcanic conduit, also a function of magma physical properties and conduit geometry. Each style is also characterized by a specific infrasonic signature, which can be used to measure the gas pockets and deduce their origin and evolution.

134 citations

References
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Journal ArticleDOI
TL;DR: In this article, a regular solution-type thermodynamic model for twelve-component silicate liquids in the system SiO2-TiO 2-Al 2O3-Fe2O 3-Cr2O3 -FeO-MgO-CaO-Na2O-K 2O-P2O5-H2O is calibrated.
Abstract: A revised regular solution-type thermodynamic model for twelve-component silicate liquids in the system SiO2-TiO2-Al2O3-Fe2O3-Cr2O3-FeO-MgO-CaO-Na2O-K2O-P2O5-H2O is calibrated. The model is referenced to previously published standard state thermodynamic properties and is derived from a set of internally consistent thermodynamic models for solid solutions of the igneous rock forming minerals, including: (Mg,Fe2+,Ca)-olivines, (Na,Mg,Fe2+,Ca)M2 (Mg,Fe2+, Ti, Fe3+, Al)M1 (Fe3+, Al,Si)2TETO6-pyroxenes, (Na,Ca,K)-feldspars, (Mg,Fe2+) (Fe3+, Al, Cr)2O4-(Mg,Fe2+)2 TiO4 spinels and (Fe2+, Mg, Mn2+)TiO3-Fe2O3 rhombohedral oxides. The calibration utilizes over 2,500 experimentally determined compositions of silicate liquids coexisting at known temperatures, pressures and oxygen fugacities with apatite ±feldspar ±leucite ±olivine ±pyroxene ±quartz ±rhombohedral oxides ±spinel ±whitlockite ±water. The model is applicable to natural magmatic compositions (both hydrous and anhydrous), ranging from potash ankaratrites to rhyolites, over the temperature (T) range 900°–1700°C and pressures (P) up to 4 GPa. The model is implemented as a software package (MELTS) which may be used to simulate igneous processes such as (1) equilibrium or fractional crystallization, (2) isothermal, isenthalpic or isochoric assimilation, and (3) degassing of volatiles. Phase equilibria are predicted using the MELTS package by specifying bulk composition of the system and either (1) T and P, (2) enthalpy (H) and P, (3) entropy (S) and P, or (4) T and volume (V). Phase relations in systems open to oxygen are determined by directly specifying the fo2 or the T-P-fo2 (or equivalently H-P-fo2, S-P-fo2, T-V-fo2) evolution path. Calculations are performed by constrained minimization of the appropriate thermodynamic potential. Compositions and proportions of solids and liquids in the equilibrium assemblage are computed.

2,614 citations


"Conditions of Magma Storage, Degass..." refers methods in this paper

  • ...…from https://academic.oup.com/petrology/article-abstract/51/3/603/1531471/Conditions-of-Magma-Storage-Degassing-and-Ascent by guest on 16 September 2017 the magma crystallization paths using the Adiabat thermodynamic model (Ghiorso & Sack, 1995; Asimow & Ghiorso, 1998; Smith & Asimow, 2005)....

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Journal ArticleDOI
TL;DR: In this paper, the ascent and emplacement of basaltic magma on the earth and moon is modeled by the application of geological and physical observations and constraints, provided that allowance is made for the coalescence of gas bubbles.
Abstract: The ascent and emplacement of basaltic magma on the earth and moon is modeled by the application of geological and physical observations and constraints. Relatively simple mathematical models of the motion of gas/liquid mixtures are shown to be adequate in the treatment of basaltic eruptions, provided that allowance is made for the coalescence of gas bubbles and that realistic geological and petrochemical constraints are applied to the numerical values of variables. Because gas exsolution from magmas on the earth and moon commonly occur at depths of less than 2 km, it is generally convenient to consider separately the rise of bubble-free magmatic liquid at depth in a planetary crust and the more complex motions occurring near the surface with gas exsolution.

690 citations


"Conditions of Magma Storage, Degass..." refers background in this paper

  • ...…degassing or outgassing have been associated with low-intensity strombolian activity because of differential transfer of coalescing gas bubbles (e.g.Wilson & Head,1981) or bubble accumulation, foam collapse and gas pocket (slug) migration upwards in the conduits (e.g. Jaupart & Vergniolle, 1988)....

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Journal ArticleDOI
TL;DR: In this article, the MELTS software package is modified to support the calculation of heterogeneous phase equilibria in the subsolidus by adding and removing phases from the assemblage without adjusting the system bulk composition.
Abstract: Algorithmic modifications to the MELTS software package are presented in order that calculations of heterogeneous phase equilibria can be performed in the subsolidus. Methods are presented for: (1) selecting an "initial guess assemblage" that satisfies the bulk composition constraints; (2) detecting saturation of new phases (including liquid) in an assemblage; (3) adding and removing phases from the assemblage without adjusting the system bulk composition; and (4) constraining the assemblage to a fixed f_(O2). These methods have O2 been added to MELTS, allowing it to calculate heterogeneous phase equilibria with or without liquid, closed or open to O, and with fixed intensive variables (P,T), (P,S), (P,H), or (V,T). Applications include fractional melting calculations, metamorphic phase equilibria, and geophysical models of subsolidus regions of the Earth.

689 citations


"Conditions of Magma Storage, Degass..." refers methods in this paper

  • ...For the shoshonitic melt hosted in Fo69·5 (ST182-11; Table 1) the measured K Fe D Ol Liq value (0·302) matches well that predicted (0·294) by the model of Toplis (2005), for an fO2 buffered at FMQ and a temperature of 11208C....

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  • ...…from https://academic.oup.com/petrology/article-abstract/51/3/603/1531471/Conditions-of-Magma-Storage-Degassing-and-Ascent by guest on 16 September 2017 the magma crystallization paths using the Adiabat thermodynamic model (Ghiorso & Sack, 1995; Asimow & Ghiorso, 1998; Smith & Asimow, 2005)....

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Journal ArticleDOI
TL;DR: Papale et al. as mentioned in this paper applied thermodynamic equilibrium between gaseous and liquid volatile components to model the volatile saturation surface in H 2 O−CO 2 -silicate melt systems.

491 citations


"Conditions of Magma Storage, Degass..." refers methods or result in this paper

  • ...Thus the saturation pressures calculated using the solubility model of Papale et al. (2006) must be considered with caution, all the more so because the computed CO2 solubility is highly sensitive to the redox state....

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  • ...The pressures calculated using the Papale et al. (2006) model confirm the presence of a magma ponding zone extending vertically from 7 to 10 km, in accordance with previous findings (Bertagnini et al., 2003) and available experimental petrology (Di Carlo et al., 2006)....

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  • ...The minimum melt saturation pressure (PCO2þPH2O) and gas phase composition (XCO2, XH2O) were derived from the dissolved amounts of H2O and CO2 measured in melt inclusions, using the H2O^CO2 solubility model of Papale (1999), updated by Papale et al. (2006)....

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  • ...We have computed the pressure-related evolution of H2O and CO2 in a basaltic melt under closed-system ascent and decompression (CSAD) conditions, using Papale’s updated model (Papale et al., 2006)....

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Journal ArticleDOI
TL;DR: The program adiabat_1ph is a simple text‐menu driver for subroutine versions of the algorithms MELTS, pMELts, and pHMELTS that may be used to calculate equilibrium assemblages along a thermodynamic path set by the user and can simultaneously calculate trace element distributions.
Abstract: The program adiabat_1ph is a simple text-menu driver for subroutine versions of the algorithms MELTS, pMELTS, and pHMELTS [Asimow et al., 2004; Ghiorso et al., 2002; Ghiorso and Sack, 1995]. It may be used to calculate equilibrium assemblages along a thermodynamic path set by the user and can simultaneously calculate trace element distributions. The MELTS family of algorithms is suitable for multicomponent systems, which may be anhydrous, water-undersaturated, or water-saturated, with the options of buffering oxygen fugacity and/or water activity. A wide variety of calculations can be performed either subsolidus or with liquid(s) present; melting and crystallization may be batch, fractional, or continuous. The software is suitable for Linux, MacOS X, and Windows, and many aspects of program execution are controlled by environment variables. Perl scripts are also provided that may be used to invoke adiabat_1ph with some command line options and to produce output that may be easily imported into spreadsheet programs, such as Microsoft Excel. Benefits include a batch mode, which allows almost complete automation of the calculation process when suitable input files are written. This technical brief describes version 1.04, which is provided as ancillary material. Binaries, scripts, documentation, and example files for this and future releases may be downloaded at http://www.gps.caltech.edu/~asimow/adiabat. On a networked computer, adiabat_1ph automatically checks whether a newer version is available.

442 citations


"Conditions of Magma Storage, Degass..." refers methods in this paper

  • ...…from https://academic.oup.com/petrology/article-abstract/51/3/603/1531471/Conditions-of-Magma-Storage-Degassing-and-Ascent by guest on 16 September 2017 the magma crystallization paths using the Adiabat thermodynamic model (Ghiorso & Sack, 1995; Asimow & Ghiorso, 1998; Smith & Asimow, 2005)....

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