Journal ArticleDOI
Coordination reactions in non aqueous solutions - The role of the donor strength
Viktor Gutmann,Erhard Wychera +1 more
Reads0
Chats0
About:
This article is published in Inorganic and Nuclear Chemistry Letters.The article was published on 1966-09-01. It has received 333 citations till now. The article focuses on the topics: Aqueous solution.read more
Citations
More filters
Journal ArticleDOI
The acceptor number — A quantitative empirical parameter for the electrophilic properties of solvents
TL;DR: In this article, the acceptor number of 34 solvents has been derived from 31P-n.m.r. measurements of triethylphosphine oxide dissolved in the respective solvent.
Journal ArticleDOI
Empirical parameters for donor and acceptor properties of solvents
TL;DR: In this article, a clear distinction is made between nucleophilic and electrophilic solvent functions towards the solute and rules are presented which are extremely useful in choosing the most suitable solvent for a particular purpose.
Journal ArticleDOI
Toward a Generalized Treatment of the Solvent Effect Based on Four Empirical Scales: Dipolarity (SdP, a New Scale), Polarizability (SP), Acidity (SA), and Basicity (SB) of the Medium
TL;DR: The proposed methodology departs from the traditional single-parameter procedures for estimating nonspecific solvent effects by splitting them into a polarizability term and a dipolarity term, and is applied to understanding for the indole chromophore the feasible inversion of the electronic nature for the first electronic excited state due to solvent effects.
Journal ArticleDOI
Empirical Parameters of Solvent Polarity as Linear Free‐Energy Relationships
TL;DR: In this article, a summary of the 24 most important empirical parameters of solvent polarity and the table of ET(30) values for 151 solvents are presented, in addition to examples of the application of these values, attempts to improve the LFE correlations of singular empirical parameters with the aid of multiparametric equations are described.
References
Related Papers (5)
The acceptor number — A quantitative empirical parameter for the electrophilic properties of solvents
The solvatochromic comparison method. I. The .beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities
Mortimer J. Kamlet,R. W. Taft +1 more