Lawrence Berkeley National Laboratory
Recent Work
Title
CORE-ELECTRON BINDING ENERGIES FOR COMPOUNDS OF BORON, CARBON AND
CHROMIUM
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https://escholarship.org/uc/item/2hc6r2zd
Authors
Henrickson, D.N.
Hollander, J.M.
Jolly, W.L.
Publication Date
1969-09-01
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University of California
Submitted
to
Inorganic
Chemistry
UCRL-19083
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print
d·Z
CORE-ELECTRON
BINDING
ENERGIES
FOR
COMPOUNDS
OF
BORON,
CARBON
AND
CHROMIUM
D.
N.
Henrickson,
J.
M.
Hollander,
and
W.
L.
Jolly
September
1969
AEC
Contract
No.
W
-7405
-eng
-48
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'
l'
UCRL-19083
Core-Electron
Binding
Energies
for
Compounds
of
Boron, Carbon and Chromium
D.
N.
Hendrickson,
J.
M.
Hollander,
and
W.
L.
Jolly
Contribution
from
the
Department
of
Chemistry
of
the
University
of
California
and
the
Inorganic
Materials
Research
and
Nuclear
Chemistry
Divisions
of
the
Lawrence
Radiation
Laboratory,
Berkeley,
California
94720
ABSTRACT
Boron
1~
and chromium
3E
binding
energies
have
been
measured
for
25
boron
compounds and
17
chromium compounds. The
data
correlate
linearly
with
calculated
atomic
charges.
A
linear
correlation
is
also
demonstrated
for
CNDO~calculated
atomic
charges
and
carbon
1~
binding
energies
determined
by
other
workers.
•
•
UCRL-19083
INrRODUCTION
~
Core-electron
binding
energies
for
several
elements
in
a wide
variety
1
of
compounds have
been
determined
by
X-ray-photoelectron
spectroscopy
(XPS)
•
(1)
A
review
of
many
aspects·of
XPS
can
be.found
inK.
Siegbahn,
c.
Nordling,
A. Fahlman, R. Nordberg,
K.
Hamrin,
J.
Hedman,
G.
Johansson,
T. Bergmark,
S.-E.
Karlsson,
J,
Lindgren
and
B·
Lindberg,
"ESCA
Atomic
Molecular
and
Solid
State
Structure
Studied
by
Means
of
Electron
Spectroscopy,"
Almgvist
and
Wiksells
AB,
Stockholm
(1967).
lhes~.
energies
have
been
correlated
with
atomic·
charges
calculated·
from
molecular
orbital
eigenfunctions.
2
-
4
·
Although
it
has
been
pointed:>
out
that,
from
(2)
For
nitrogen
compoUnds
see:
J.
M.
Hollander,
D.
N.
Hendrickson,
and
w.
L.
Jolly,
:I.·
Chem.
Phys.,
49,
3315
(1968);
D.
N.
Hendrickson,
J.
M.
Hollander,
and
w.
L.
Jolly,
submitted
to
Inorg.
Chem.
(3)
For
carbon
compounds
see:
R.
Nordberg,
U.
Gelius,
P.
F.
Heden,
J,
Hedman,
c.
Nordling,
K.
Siegbahn,
and
B.
J.
Lindberg,
su~mitted
to
Arkiv.
f8r
Kemi.
(4)
For
phosphorus compound's
see:
M.
Pelavi'n,
D.
N
..
Hend:.i:'ickson,
J~
M •
Hollander,
and
w.
L.
Jolly,
submitted
to
~·
Phys.
Chem.
(5)
W.
L.
Jolly
and
D.
N~
Hendrickson,
to
be
published~