Q2. What is the use of cNDIs to sense polyphenols?
The intercalation of dialkoxyanthracene 101 has been used to sense polyphenols such as epigallocatechin gallate 102 within synthetic pores with internal NDI tweezers.
Q3. What is the effect of cNDIs on the photonic energy transfer?
Rainbow cNDIs have been coupled with zinc chlorins to harvest light at the periphery of zinc chlorin rod antennas and transfer the photonic energy to the chlorophyll centers.
Q4. What is the example of a cNDI-OT polymer?
The successful fabrication of organic solar cells with cNDIEDOT polymers 80 is the first example where the ability of - stacked cNDIs to transport electrons is combined with light.
Q5. What is the redox gradient in the e-channel?
The red cNDIs placed on top of the yellow cNDIs create a redox gradient in the e-channel that directs the electrons toward the gold surface.
Q6. What is the symmetry-breaking photoinduced charge separation with blue cNDIs 17?
As with chlorophyll, the symmetry-breaking photoinduced charge separation with blue cNDIs 17 is 290 attractive for optoelectronics applications because it occurs with minimal losses in photonic energy.
Q7. What is the quadrupole moment of cNDIs 83-86?
Electrostatic potential surfaces (blue positive, red negative) and computed axial quadrupole moments QZZ of cNDIs 83-86, adapted from refs.
Q8. How can the authors determine the LUMO of cNDIs?
The introduction of the two alkoxy donors in the core of yellow cNDIs 13 raises the LUMO to -3.82 eV, and the first oxidation accounting for the HOMO level of -6.16 eV can be 185 determined directly by CV (Figures 2b and 1).
Q9. What is the effect of anion interactions on organocatalysis?
Considering that 500 anionic reactive intermediates such as enolates should be similarly recognized on asymmetric -acidic surfaces, the impact of anion- interactions on organocatalysis is expected to be significant.7anionNNOOOOCNNCNNOOOONNOOOOCNNCNNOOOO105103 106104-acidity decrowdinganion binding anion transport505Fig. 10 Structure of NDIs and cNDIs 103-106 used to demonstrate the functional relevance of anion- interactions with regard to anion binding and transport across lipid bilayer membranes.
Q10. What is the way to determine the transport activity of a cNDI?
With nanomolar effective concentrations, the transport activity of the ideal cNDI 106 is significant, as is the found selectivity toward size and nature of the transported anion.
Q11. What is the effect of the addition of dodecyl tails on the LU?
Addition of head-to-head dodecyl tails to the bithiophene donor increased bandgap and lowered the HOMO level of polymer 77, whereas the LUMO was not affected (Table 1, entry 50).
Q12. What is the effect of the thiophene donor on the bandgap?
605The replacement of the central thiophene in cNDI-OT polymers 81 with a fluorene in the fluorescent cNDI-OT polymers 82 has relatively little effect on the narrow bandgap ( max = 613 nm), indicating that strong electronic interactions 610 along the polymer chain are preserved (Table 1, entries 54- 55).36
Q13. What is the symmetry of the blue chromophores?
In monomeric POP-cNDI systems, the blue chromophores can undergo symmetry-breaking ultrafast and quantitative photoinduced charge separation with 685 a lifetime of 61 ps (Figure 3c).
Q14. What is the effect of the alcoholate on the cNDIs?
The transesterification that naturally occurs under these conditions is irrelevant because the obtained tetraester 36 is hydrolyzed anyway before the formation of yellow cNDIs 13 with the amines of choice.
Q15. What are the redox properties of cNDIs?
These 195 unique redox properties make cNDIs 17 similar to chlorophyll and very attractive for optoelectronic applications (see below).