Corrosion characteristics of cobalt-silicon nitride electro composites in various corrosive environments
TL;DR: In this paper, the corrosion characteristics of electro codeposited cobalt-silicon nitride composites in neutral sodium chloride and sulphuric acid solutions are presented, and the electro composites showed greatly improved corrosion resistance over pure cobalt in nondeaerated 3.5% sodium chloride solution, but they induced significantly less galvanic corrosion on steel in the same medium.
Abstract: The corrosion characteristics of electro codeposited cobalt-silicon nitride composites in neutral sodium chloride and sulphuric acid solutions are presented. The electro composites showed greatly improved corrosion resistance over pure cobalt in nondeaerated 3.5% sodium chloride solution, but they induced significantly less galvanic corrosion on steel in the same medium. Galvanic current and dissolution current measurements showed a linear variation with the cathode-to-anode area ratio, while the galvanic potential showed a logarithmic variation with the same. Composites of cobalt-silicon nitride also showed improved passivation properties in 1 N sulphuric acid.
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TL;DR: In this article, the effect of deposition conditions on the evolution of surface microstructure, crystallographic microtexture, microhardness, and sliding wear behavior of pure nickel and nickel composite coatings are presented.
Abstract: In this work, pure nickel and nickel composite coatings (Ni–Al 2 O 3 , Ni–SiC, and Ni–ZrO 2 ) were deposited from Watts bath using direct current (DC), pulsed current (PC), and pulsed reverse current (PRC) electrodeposition conditions. Detailed investigations on the effect of deposition conditions on the evolution of surface microstructure, crystallographic micro-texture, microhardness, and sliding wear behavior of pure nickel and nickel composite coatings are presented. For all the coatings, the PC and PRC deposition conditions resulted in more random/weak crystallographic texture compared to DC deposition. The composite coatings deposited using PC and PRC deposition also exhibited significant improvement in microhardness and wear resistance due to enhanced reinforcement of nanoparticles in the coatings. Also, the effect of nanoparticle content of the electrolyte bath on the surface microstructure, tribological properties, and level of reinforcement in the Ni–Al 2 O 3 composite coating is investigated. The reinforcement of nanoparticles in the Ni–Al 2 O 3 composite coatings increased linearly with the amount of nanoparticle loading in the electrolyte bath. The microhardness and wear resistance of the Ni–Al 2 O 3 composite coatings also improved with increasing Al 2 O 3 content in the coatings.
144 citations
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TL;DR: In this article, ternary Ni-W-P alloy films were prepared using alkaline citrate-based bath and evaluated in 3.5% sodium chloride solution in non-deaerated and deaerated conditions by potentiodynamic polarization and electrochemical impedance (EIS).
Abstract: The autocatalytic (electroless) deposition of Ni–P based alloys is a well-known commercial process that has found numerous applications because of their excellent anticorrosive, wear, magnetic, solderable properties, etc. It is a barrier coating, protecting the substrate by sealing it off from the corrosive environments, rather than by sacrificial action. The corrosion resistance varies with the phosphorus content of the deposit: relatively high for a high-phosphorus electroless nickel deposit but low for a low-phosphorus electroless nickel deposit. In the present investigation ternary Ni–W–P alloy films were prepared using alkaline citrate-based bath. Quaternary Ni–W–Cu–P films were deposited by the addition of 3 mM copper ions in ternary Ni–W–P bath. X-ray diffraction (XRD) studies indicated that all the deposits were nanocrystalline, i.e. 1.2, 2.1 and 6.0 nm, respectively, for binary, ternary and quaternary alloys. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated and deaerated conditions by potentiodynamic polarization and electrochemical impedance (EIS) methods. Lower corrosion current density values were obtained for the coatings tested in deaerated condition. EIS studies showed that higher charge transfer resistance values were obtained for binary Ni–P coatings compared to ternary or quaternary coatings. For all the coatings a gradual increase in the anodic current density had been observed beyond 740 mV. In deaerated condition all the reported coatings exhibited a narrow passive region and all the values of Ep, Etp and ipass were very close showing no major changes in the electrochemical behavior. In the non-deaerated conditions no passivation behavior had been observed for all these coatings.
120 citations
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TL;DR: In this paper, as-deposited and annealed/pre-oxidised NiCoCrAlYSiB coatings were studied by salt spray testing in a neutral mist of 5-wt% NaCl at 35-°C for 200h.
Abstract: NiCoCrAlYSiB coatings were deposited by arc ion plating (AIP) and annealed/pre-oxidised under various conditions. The corrosion behaviour of as-deposited and annealed/pre-oxidised coatings was studied by salt spray testing in a neutral mist of 5 wt% NaCl at 35 °C for 200 h. The results showed that the as-deposited NiCoCrAlYSiB coating behaved poorly while the annealed and pre-oxidised ones performed much better in salt spray tests. The dense microstructure in annealed coatings and formation of α-Al 2 O 3 scales on the surface during pre-oxidation improved the corrosion resistance in salt spray test. The corrosion process was investigated from the aspects of corrosion products, and its electrochemical mechanism was proposed as well.
22 citations
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TL;DR: The galvanic corrosion behavior of carbon steel-stainless steel couples with various cathode/anode area ratios was investigated in S 2−-containing solutions, which were in equilibrium with air, by electrochemical measurements, immersion test, and surface characterization.
Abstract: The galvanic corrosion behavior of carbon steel-stainless steel couples with various cathode/anode area ratios was investigated in S
2−-containing solutions, which were in equilibrium with air, by electrochemical measurements, immersion test, and surface characterization. It is found that the galvanic corrosion effect on carbon steel anode increases with the cathode/anode area ratios, and decreases with the increasing concentration of S2− in the solution. A layer of sulfide film is formed on carbon steel surface, which protects it from corrosion. When the cathode/anode area ratio is 1:1, the potentiodynamic polarization curve measurement and the weight-loss determination give the identical measurement of the galvanic corrosion effect. With the increase of the cathode/anode area ratio, the electrochemical method may not be accurate to determine the galvanic effect. The anodic dissolution current density of carbon steel cannot be approximated simply with the galvanic current density.
9 citations
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TL;DR: In this paper, the influence of Cs + concentration on the cathodic polarization curves was determined in galvanostatic and potentiodynamic measurements, and the structure of the composite coatings was studied by microscopic observations.
Abstract: Electrodeposition of SiC particles with cobalt matrix in the presence of cesium ions was studied. The influence of Cs + concentration (0–37.6 mM) on the cathodic polarization curves was determined in galvanostatic and potentiodynamic measurements. It was found that the presence of Cs + in the solution enhanced adsorption of Co 2+ ions on SiC, but preferential cesium adsorption occurred simultaneously. The last phenomena resulted in cesium incorporation in the composite coating. Surface charge of SiC powder and amounts of functional groups on SiC surface were determined. The particles incorporation into deposits was only little dependent on cesium concentration in the bath. Structure of the composite coatings was studied by microscopic observations. Microhardness of the deposits was also determined.
6 citations
References
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TL;DR: In this paper, the effect of graphite and silicon carbide reinforcements on the pitting behavior of a graphite/aluminum (Gr/Al) and SiC/Al matrix composites was examined.
Abstract: This paper examines the effect of graphite and silicon carbide reinforcements on the pitting behavior of graphite/aluminum (Gr/Al) and silicon carbide/aluminum (SiC/Al) metal matrix composites. Electrochemical corrosion tests were performed on both Gr/Al and SiC/Al composite specimens. Identical tests were completed on powder metallurgy processed aluminum and wrought aluminum of the same composition. The electrochemical behavio of the SiC/Al composites was essentially identical to that of the powder processed and wrought aluminum alloys; however, the pitting attack on the SiC/Al composites was distributed more uniformly across the surface, and the pits penetrated to significantly less depths. The presence of graphite in the Gr/Al composites did not cause an electropositive shift in corrosion potential as anticipated, but caused a substantial decrease in resistance to passive film breakdown. This effect is the predominant reason for the poor performance of Gr/Al composites in marine environments.
136 citations
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TL;DR: In this paper, the effect of phase on the corrosion behavior of metal matrix composites has been studied in, both in the presence and absence of dissolved oxygen, and the results show that pitting susceptibility is about the same for the composites and their corresponding alloys, except for Al 2024.
Abstract: The effect of the phase on the corrosion behavior of metal matrix composites has been studied in , both in the presence and absence of dissolved oxygen. Anodic polarization behavior has been determined, and pitting potentials have been measured for three composite systems: 2024, 6061, and 5456. General corrosion behavior and the effects of anodizing on the corrosion resistance of the composites have been studied by a‐c impedance techniques. The results show that pitting susceptibility is about the same for the composites and their corresponding alloys, except for Al 2024. In this system, the composite is less resistant to pit initiation than the corresponding wrought aluminum alloy. General corrosion is more significantly affected by the presence of oxygen than by the phase. In the absence of oxygen, corrosion resistance is improved for both the alloys and composites. In addition, the corrosion resistance of the composites can be improved by anodizing.
122 citations
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TL;DR: Pit morphology of Al 5456, Al 6061, SiCw/Al 5456 (UNS A95456), Al 60 61 (UNs A96061) and SiCws/Al 6061 is studied in this article, in order to compare pitting processes of Si cw/al matrix composites with that of corresponding unreinforced alloys.
Abstract: Pit morphology of Al 5456 (UNS A95456), Al 6061 (UNS A96061), SiCw/Al 5456, and SiCw/Al 6061 is studied in order to compare pitting processes of SiCw/Al metal matrix composites with that of corresponding unreinforced alloys. Work on anodized samples of Al 6061 and SiCw/Al 6061 is also included. Pits on the composites are significantly more numerous, shallow, and widespread than on the monolithic materials. Studies of pit structure suggest there are two stages in pit development. The first involves the initial dissolution of metal atoms and opening of the pit, and the second involves pit enlargement or growth. For both materials, pits initiate at secondary particles within the metal matrix. In the case of Al 5456 and SiCw/Al 5456, it is shown that these particles are intermetallic phases composed of alloying elements Mg, Cr, Mn, and Al, as well as, Fe, which is an impurity of the metal. Under equivalent conditions of preparation and processing, a greater number of intermetallic phases form in the ...
114 citations
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TL;DR: Galvanic interaction between the Al alloys 1100, 2024, 2219, 6061, 7075, and Ag, Cu, Ni, Sn, Cd, Zn, the stainless steels 301, 304L, 347, A286, PH13-8Mo, Steel 4130, Inconel 718, Haynes 188 and Ti-6AI-4V has been studied in air saturated 3.5% NaCl by weight loss measurements and continuous monitoring of the galvanic current in 24 hour tests as discussed by the authors.
Abstract: Galvanic interaction between the Al alloys 1100, 2024, 2219, 6061, 7075, and Ag, Cu, Ni, Sn, Cd, Zn, the stainless steels 301, 304L, 347, A286, PH13-8Mo, Steel 4130, Inconel 718, Haynes 188 and Ti-6AI-4V has been studied in air saturated 3.5% NaCl by weight loss measurements and continuous monitoring of the galvanic current in 24 hour tests. Results show that the potential difference of uncoupled dissimilar metals, while in most cases accurately predicting the direction of current flow, is a poor indicator of the extent (rate) of galvanic corrosion of coupled dissimilar materials. The values of the average galvanic current density agree well with the increase of dissolution rates due to galvanic coupling. In general, galvanic corrosion of Al alloys coupled to dissimilar metals decreases in the order Ag > Cu > steel 4130 ≫ stainless steels ≈ Ni > Inconel 718 ≫ Ti-6AI-4V ≈ Haynes 188 >Sn > Cd. Coupling to zinc does not result in cathodic protection for all Al alloys studied, but can lead to increas...
51 citations