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Journal ArticleDOI

Crystal and molecular structure of bis(o-phenylenethiourea)selenium(II)chloride dihydrate, C14H12N4S2Cl2Se·2H2O

01 Jun 1989-Journal of Chemical Crystallography (Kluwer Academic Publishers-Plenum Publishers)-Vol. 19, Iss: 3, pp 465-473
TL;DR: The synthesis and crystal structure of bis(o-phenylenethiourea)selenium(II)-chloride dihydrate, Se(C7H6N2S)2Cl2·2H2O are reported in this article.
Abstract: The synthesis and crystal structure ofbis(o-phenylenethiourea)selenium(II)-chloride dihydrate, Se(C7H6N2S)2Cl2·2H2O are reported. The compound crystallizes in the monoclinic space group, P21/n, with four molecules per unit cell, the dimensions of which area=10.243(3),b=13.341(4),c=14.273(4) A,β=93.00(3)°,U=1947.76 A3. The structure was solved by direct methods and refined by full-matrix least-squares toR=0.039 andR w =0.040 for 3314 unique reflections. Selenium displays two strong coordinations arising from the two sulfurs, Se-S(1)=2.191(1), Se-S(2)=2.206(1) A, and S(1)-Se-S(2)=101.0(1)°, and four secondary interactions involving three chlorines and one sulfur. The complex occurs as a dimer with two sets of very weakly interacting bridging pairs S(2), S(2)a; and Cl(2), Cl(2)a, where “a” denotes the inversion related atom. Lattice stabilization is ensured by the extensive network of hydrogen bonds involving chlorines, water oxygens, and nitrogens of phenylenethiourea ligands.
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TL;DR: Etude des trans-te(etu) 2 Br 2, trans-Te(etuan) 2 I 2 (etu=ethylenethiouree), [Te[etu] 4 ]Cl 2 [Te(esu 4 ],Cl 2 (esu=methyleneselenouree) and trans-tmtu 2 (SCN) 2 (tmtnu=tetramethylthiourees).
Abstract: Etude des trans-Te(etu) 2 Br 2 , trans-Te(etu) 2 I 2 (etu=ethylenethiouree), [Te(etu) 4 ]Cl 2 [Te(esu 4 ]Cl 2 (esu=ethyleneselenouree), trans-Te(tmtu) 2 (SCN) 2 (tmtu=tetramethylthiouree) et trans-Te(tmsu) 2 (SeCN) 6 (tmsu=tetramethylselenouree)

9 citations