Damping pathways of mid-infrared plasmons in graphene nanostructures
TL;DR: In this paper, the authors clarified damping pathways for mid-infrared graphene plasmons, including graphene intrinsic optical phonons and edge scattering, and demonstrated the guiding of a 50-nm-wide structure with an electromagnetic mode area of 10−3 μm2 and a propagation length of 200 nm.
Abstract: Researchers clarify damping pathways for mid-infrared graphene plasmons, including graphene intrinsic optical phonons and edge scattering. They also demonstrate the guiding of mid-infrared graphene plasmons in 50-nm-wide structures with an electromagnetic mode area of 10−3 μm2 and a propagation length of 200 nm.
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TL;DR: Black phosphorus (BP), the most stable allotrope of phosphorus with strong intrinsic in-plane anisotropy, is reintroduced to the layered-material family and shows great potential for thin-film electronics, infrared optoelectronics and novel devices in which anisotropic properties are desirable.
Abstract: The applications of graphene and transition metal dichalcogenides in electronics are limited by their zero-bandgap and low mobility, respectively. Here, the authors demonstrate the potential of an emerging layered material—black phosphorous—for thin film electronics and infrared optoelectronics.
2,983 citations
University of Cambridge1, Istituto Italiano di Tecnologia2, Lancaster University3, University of Manchester4, Catalan Institution for Research and Advanced Studies5, Technical University of Denmark6, Nokia7, Queen Mary University of London8, University of Trento9, fondazione bruno kessler10, Technische Universität München11, Polytechnic University of Milan12, Centre national de la recherche scientifique13, University of Trieste14, University of Ioannina15, University of Geneva16, Trinity College, Dublin17, Texas Instruments18, University of Paris19, Spanish National Research Council20, Leiden University21, Delft University of Technology22, University of Patras23, École Normale Supérieure24, Radboud University Nijmegen25, Nest Labs26, Airbus UK27, Seoul National University28, Yonsei University29, University of Oxford30, Chalmers University of Technology31, University of Groningen32, STMicroelectronics33, Chemnitz University of Technology34, Max Planck Society35, Aalto University36
TL;DR: An overview of the key aspects of graphene and related materials, ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries are provided.
Abstract: We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.
2,560 citations
TL;DR: In this article, the optical properties and applications of various two-dimensional materials including transition metal dichalcogenides are reviewed with an emphasis on nanophotonic applications, and two different approaches for enhancing their interactions with light: through their integration with external photonic structures, and through intrinsic polaritonic resonances.
Abstract: The optical properties of graphene and emerging two-dimensional materials including transition metal dichalcogenides are reviewed with an emphasis on nanophotonic applications. Two-dimensional materials exhibit diverse electronic properties, ranging from insulating hexagonal boron nitride and semiconducting transition metal dichalcogenides such as molybdenum disulphide, to semimetallic graphene. In this Review, we first discuss the optical properties and applications of various two-dimensional materials, and then cover two different approaches for enhancing their interactions with light: through their integration with external photonic structures, and through intrinsic polaritonic resonances. Finally, we present a narrow-bandgap layered material — black phosphorus — that serendipitously bridges the energy gap between the zero-bandgap graphene and the relatively large-bandgap transition metal dichalcogenides. The plethora of two-dimensional materials and their heterostructures, together with the array of available approaches for enhancing the light–matter interaction, offers the promise of scientific discoveries and nanophotonics technologies across a wide range of the electromagnetic spectrum.
2,414 citations
IBM1
TL;DR: The basic properties of graphene plasmons are reviewed: their energy dispersion, localization and propagation, plasmon-phonon hybridization, lifetimes and damping pathways, and emerging and potential applications.
Abstract: In recent years, we have seen a rapid progress in the field of graphene plasmonics, motivated by graphene's unique electrical and optical properties, tunabilty, long-lived collective excitation and their extreme light confinement. Here, we review the basic properties of graphene plasmons; their energy dispersion, localization and propagation, plasmon-phonon hybridization, lifetimes and damping pathways. The application space of graphene plasmonics lies in the technologically significant, but relatively unexploited terahertz to mid-infrared regime. We discuss emerging and potential applications, such as modulators, notch filters, polarizers, mid-infrared photodetectors, mid-infrared vibrational spectroscopy, among many others.
1,056 citations
University of Minnesota1, Federal University of Ceará2, United States Naval Research Laboratory3, Massachusetts Institute of Technology4, IBM5, Stanford University6, University of Manchester7, IMDEA8, Spanish National Research Council9, Catalan Institution for Research and Advanced Studies10, ICFO – The Institute of Photonic Sciences11
TL;DR: The emerging field of 2D material polaritonics and their hybrids provide enticing avenues for manipulating light-matter interactions across the visible, infrared to terahertz spectral ranges, with new optical control beyond what can be achieved using traditional bulk materials.
Abstract: In recent years, enhanced light-matter interactions through a plethora of dipole-type polaritonic excitations have been observed in two-dimensional (2D) layered materials. In graphene, electrically tunable and highly confined plasmon-polaritons were predicted and observed, opening up opportunities for optoelectronics, bio-sensing and other mid-infrared applications. In hexagonal boron nitride, low-loss infrared-active phonon-polaritons exhibit hyperbolic behaviour for some frequencies, allowing for ray-like propagation exhibiting high quality factors and hyperlensing effects. In transition metal dichalcogenides, reduced screening in the 2D limit leads to optically prominent excitons with large binding energy, with these polaritonic modes having been recently observed with scanning near-field optical microscopy. Here, we review recent progress in state-of-the-art experiments, and survey the vast library of polaritonic modes in 2D materials, their optical spectral properties, figures of merit and application space. Taken together, the emerging field of 2D material polaritonics and their hybrids provide enticing avenues for manipulating light-matter interactions across the visible, infrared to terahertz spectral ranges, with new optical control beyond what can be achieved using traditional bulk materials.
976 citations
References
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TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
Abstract: Graphene is the two-dimensional building block for carbon allotropes of every other dimensionality We show that its electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers The D peak second order changes in shape, width, and position for an increasing number of layers, reflecting the change in the electron bands via a double resonant Raman process The G peak slightly down-shifts This allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area
13,474 citations
TL;DR: It is shown that graphene grows in a self-limiting way on copper films as large-area sheets (one square centimeter) from methane through a chemical vapor deposition process, and graphene film transfer processes to arbitrary substrates showed electron mobilities as high as 4050 square centimeters per volt per second at room temperature.
Abstract: Graphene has been attracting great interest because of its distinctive band structure and physical properties. Today, graphene is limited to small sizes because it is produced mostly by exfoliating graphite. We grew large-area graphene films of the order of centimeters on copper substrates by chemical vapor deposition using methane. The films are predominantly single-layer graphene, with a small percentage (less than 5%) of the area having few layers, and are continuous across copper surface steps and grain boundaries. The low solubility of carbon in copper appears to help make this growth process self-limiting. We also developed graphene film transfer processes to arbitrary substrates, and dual-gated field-effect transistors fabricated on silicon/silicon dioxide substrates showed electron mobilities as high as 4050 square centimeters per volt per second at room temperature.
10,663 citations
TL;DR: In this paper, a theoretical analysis of the shape of the 2s2p^{1}P resonance of He observed in the inelastic scattering of electrons is presented. But the analysis is restricted to the case of one discrete level with two or more continua and of a set of discrete levels with one continuum.
Abstract: The interference of a discrete autoionized state with a continuum gives rise to characteristically asymmetric peaks in excitation spectra. The earlier qualitative interpretation of this phenomenon is extended and revised. A theoretical formula is fitted to the shape of the $2s2p^{1}P$ resonance of He observed in the inelastic scattering of electrons. The fitting determines the parameters of the $2s2p^{1}P$ resonance as follows: $E=60.1$ ev, $\ensuremath{\Gamma}\ensuremath{\sim}0.04$ ev, $f\ensuremath{\sim}2 \mathrm{to} 4\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}3}$. The theory is extended to the interaction of one discrete level with two or more continua and of a set of discrete levels with one continuum. The theory can also give the position and intensity shifts produced in a Rydberg series of discrete levels by interaction with a level of another configuration. The connection with the nuclear theory of resonance scattering is indicated.
8,210 citations
Book•
15 May 2007
TL;DR: In this paper, the authors discuss the role of surface plasmon polaritons at metal/insulator interfaces and their application in the propagation of surfaceplasmon waveguides.
Abstract: Fundamentals of Plasmonics.- Electromagnetics of Metals.- Surface Plasmon Polaritons at Metal / Insulator Interfaces.- Excitation of Surface Plasmon Polaritons at Planar Interfaces.- Imaging Surface Plasmon Polariton Propagation.- Localized Surface Plasmons.- Electromagnetic Surface Modes at Low Frequencies.- Applications.- Plasmon Waveguides.- Transmission of Radiation Through Apertures and Films.- Enhancement of Emissive Processes and Nonlinearities.- Spectroscopy and Sensing.- Metamaterials and Imaging with Surface Plasmon Polaritons.- Concluding Remarks.
7,238 citations
Book•
05 Oct 2014
TL;DR: In this paper, the authors present a survey of optical spectra of Elemental Metal Clusters and Chain Aggregates and discuss experimental results and experimental methods for metal clustering experiments.
Abstract: 1. Introduction.- 2. Theoretical Considerations.- 3. Experimental Methods.- 4. Experimental Results and Discussion.- A.1 Tables: Optical Spectroscopy Experiments with Metal Clusters.- A.2 Survey of Optical Spectra of Elemental Metal Clusters and Chain-Aggregates.- A.3 Mie Computer Program.- References.
6,405 citations