Journal ArticleDOI
Darstellung und strukturelle und spektroskopische Charakterisierung der Triiodide [M(12-Krone-4)2]I3 mit M = Na und Rb / Preparation and Structural and Spectroscopic Characterization of Triiodides [M(12-Crown-4)2]I3 with M= Na and Rb
Zehra Edis,Samir Haj Bloukh +1 more
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TLDR
The lattice parameters are a = 8:505(2), b = 14:280(3), c = 10:695(2) A and α = 89:86(2)-°, β = 80:00° and γ = 85:90° for 1 and 2, respectively.Abstract:
Reddish-brown crystals of [Na(12-crown-4)₂]I₃ (1) and [Rb(12-crown-4)₂]I₃ (2) were formed through the reaction of NaI or RbI, I₂ and 12-crown-4 in ethanol. Both structures are triclinic, space group P1 with Z = 2. The lattice parameters are a = 8:505(2), b = 14:280(3), c = 10:695(2) A and α = 89:86(2)°, β = 80:00(2)° and γ = 85:90(2)°; and a = 10:694(2), b = 11:598(2), c = 12:718(2) A and α = 71:00(2)°, β = 86:97(2)° and γ = 67:710(10)° for 1 and 2, respectively. Both crystal structures contain one independent complex cation without crystallographic symmetry. The anionic parts of both structures consist of two crystallographically independent, isolated, triiodide anions I₃⁻ with crystallographic inversion symmetry. The cations are distorted sandwich-like complexes with two 12-crown-4 molecules surrounding the alkali metal atom in the center.read more
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Journal ArticleDOI
“Smart” Antimicrobial Nanocomplexes with Potential to Decrease Surgical Site Infections (SSI)
TL;DR: The new compounds TCA-Ag NP-PI and Cinn-AgNP-PI are broad spectrum microbicidal agents and therefore potential coating materials for sutures to prevent Surgical Site Infections (SSI).
Journal ArticleDOI
"Smart" Triiodide Compounds: Does Halogen Bonding Influence Antimicrobial Activities?
TL;DR: The halogen bonding in the triiodide ion reduces the antibacterial activities in comparison to the inhibitory actions of pure iodine but increases the long term stability of [Na(12-crown-4)2]I3.
Journal ArticleDOI
Facile Synthesis of Antimicrobial Aloe Vera-"Smart" Triiodide-PVP Biomaterials.
Zehra Edis,Samir Haj Bloukh +1 more
TL;DR: “Smart” biohybrids with triiodide inclusions have excellent antifungal and promising antimicrobial activities, with potential use against surgical site infections (SSI) and as disinfecting agents.
Journal ArticleDOI
Halogen bonding in crystal structure of bis(1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium triiodide, C16H32CsI3O8
Samir Haj Bloukh,Zehra Edis +1 more
TL;DR: In this article, triclinic trichlinic P1̄ (no. 2), a = 10.7930(5) Å, b = 11.5610(5)-Å, c = 12.4880(5), α = 73.050(10)°, β = 88.870(10)-°, γ = 66.060(10°, V = 1353.62(16)Å3, Z = 2, Rgt(F) = 0.0578, wRref(
Journal ArticleDOI
Crystal structure and antimicrobial properties of (1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium(I) pentaiodide, C16H32CsI5O8
Samir Haj Bloukh,Zehra Edis +1 more
TL;DR: In this paper, a monoclinic I2/a (no. 15), a = 16.386(2) Å, b = 11.7050(10)Å, c = 19.005(3)À, β = 108.008(14)°, V = 3466.6(8) À3, Z = 4, Rgt(F) = 0.0437, wRref(F2)= 0.1085, T = 293(2)/a, K.
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