Journal ArticleDOI
Deactivation of RuCl2(PPh3)3 during disproportionation of D-glucose in amide solvents
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TLDR
In this article, the aldehydo-glucose was shown to be the main source of carbon monoxide in dimethylacetamide (DMA) and cis-RuCl2(CO)2(PPh3)2.About:
This article is published in Journal of Molecular Catalysis.The article was published on 1983-12-01. It has received 8 citations till now. The article focuses on the topics: Dimethylformamide & Disproportionation.read more
Citations
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Journal ArticleDOI
RuCl2(PPh3)3-catalyzed transfer hydrogenation of d-glucose
TL;DR: In this paper, a mixed solvent system such as dimethylacetamide-water and dioxane-water is used for the transfer hydrogenation of glucose to a mixture of mixed solvent systems.
Journal ArticleDOI
Homogeneous catalytic hydrogenation of aldehydes and aldoses in organic solvents and water
Snježana Kolarić,Vitomir Šunjić +1 more
TL;DR: In this paper, water-soluble homogeneous catalysts used for hydrogenation of aldehydes and aldoses are reviewed. Butler et al. focus on the mechanistic aspects of their activity and modes of their deactivation.
Patent
Decarbonylation and dehydrogenation of carbohydrates
TL;DR: In this paper, aldose or ketose sugars, including those whose carbonyl group is masked by hemiacetal or hemi-ketal formation, are decarbonylated by heating the feed carbohydrate together with a transition metal complex in a suitable solvent.
References
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Journal ArticleDOI
New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
T.A. Stephenson,G. Wilkinson +1 more
TL;DR: In this article, the interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCL2(SbPh3]3], RuCl3(Pph3)2CH3OH, [RuC2(CPh3As, Ph3Sb, pyridine etc., with a carbonyl-containing solution] and the corresponding brom
Journal ArticleDOI
Formation of Rh(I)-Carbonyl Complex by the Reaction with Some Non-alcoholic, Oxygen-containing Solvents
A. Rusina,A. A. Vlček +1 more
TL;DR: In this article, it was shown from an examination of the polarographic behaviour of some Rh(III)-arsine and phosphine complexes in dimethylformamide (DMF) as solvent that these complexes undergo reaction with the solvent.
Journal ArticleDOI
Homogeneous catalytic hydrogenation of sugars
Walter M. Kruse,Leon W. Wright +1 more
Journal ArticleDOI
Transfert catalytigue d'hydrogene VIII—gas des sucres reducteurs
TL;DR: In this paper, a reaction of transfert catalytique d'hydrogene etudiee avec le di- O -isopropylidene-2,3,4;5-D-mannofuranose comme donneur and RuH 2 (PPh 3 ) 4 comme catalyseur is described.
Related Papers (5)
Reactions of a dichlorocarbene-ruthenium complex, RuCl2(CCl2)(CO)(PPh3)2
Warren R. Roper,A.H. Wright +1 more