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Design and development of an organic-inorganic system for the chemical modification of molecular nitrogen under mild conditions
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This article is published in Accounts of Chemical Research.The article was published on 1970-11-01. It has received 89 citations till now. The article focuses on the topics: Chemical modification.read more
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Domino Reactions in Organic Synthesis
TL;DR: It is shown that domino reactions initiated by oxidation or reduction or reduction, as well as other mechanisms, can be inhibited by various materials, such as Na6(CO3)(SO4), Na2SO4, Na2CO3, and so on.
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The continuing story of dinitrogen activation
TL;DR: A review of the recent literature concerning coordination chemistry and the reactivity patterns of metal-dinitrogen complexes is presented in this article, where the emphasis is on synthesis and reactivity pattern of recently discovered dinitrogen compounds.
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Biomimetic polyene cyclizations.
TL;DR: Certain polyenic substances having trans olefinic bonds in a 1-5 relationship can be induced to undergo stereospecific, non-enzymic, cationic cyclization to give polycyclic products with all-trans (“natural”) configuration to mimic in principle the biogenetic conversion of squalene intopolycyclic triterpenoids.
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Group 4 Transition Metal Sandwich Complexes: Still Fresh after Almost 60 Years†
TL;DR: A review of metal sandwich compounds can be found in this article, with a focus on recent developments in the field, including dinitrogen coordination by various substituted titanocene derivatives as well as our group's interest in bis(indenyl)zirconium and -hafnium compounds.
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Lithium-mediated electrochemical reduction of high pressure N2 to NH3
TL;DR: In this article, LiClO 4 + ethanol was used to form NH 3 in tetrahydrofuran under an atmospheric pressure of 50 atm of N 2, and NH 3 was even formed (3.7% current efficiency) when air was used as a source.
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Bioorganic chemistry: sterols and acrylic terpene terminal expoxides
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Nitrogen Fixation by Transition Metal Complexes
M. E. Vol'pin,Vladimir B. Shur +1 more
TL;DR: In this article, it has been shown that small amounts of ammonia can form on prolonged cathodic reduction of nitrogen (or reduction by stannous chloride) in the presence of aqueous solutions of molybdate and tungstate ions.
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