Journal ArticleDOI
Design and synthesis of artificial enzymes
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This article is published in Tetrahedron.The article was published on 1984-01-01. It has received 73 citations till now.read more
Citations
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Supramolecular catalysis. Part 2: artificial enzyme mimics
TL;DR: Artificial catalysts and biomacromolecule hybrid catalysts which constitute good models towards the development of truly competitive artificial enzymes are presented.
Journal ArticleDOI
Molecular containers in complex chemical systems
TL;DR: Examples from the literature concerning three aspects of this field: complex host-guest behaviour, adaptive transformations of molecular containers and reactivity modulation within them are discussed.
Journal ArticleDOI
Cyclodextrine als Bausteine supramolekularer Strukturen und Funktionseinheiten
TL;DR: Cyclodextrine werden gerne als Bausteine eingesetzt, da sie sich gezielt sowohl kovalent, als auch nichtkovalent verknupfen lassen.
Journal ArticleDOI
Metal complexes of functionalized cyclodextrins as enzyme models and chiral receptors
TL;DR: In this paper, a review of the metal complexing properties of CDs and a report on some recent results of metal complexes formed by functionalized cyclodextrins is presented. But the main feature of CDs is an hydrophobic cavity which renders these molecules unusual.
References
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Journal ArticleDOI
Biological Applications of Ionophores
TL;DR: This paper describes the phytochemical properties of Ionophores, and some of the properties that matter most in the determination of good and bad Ionophore properties are listed.
Journal ArticleDOI
Role of a Buried Acid Group in the Mechanism of Action of Chymotrypsin
TL;DR: Polarization of the system due to the buried negative charge of the aspartic acid residue would make the serine oxygen strongly nucleophilic and would explain its reactivity towards amides and esters.
Journal ArticleDOI
"Picket fence porphyrins." Synthetic models for oxygen binding hemoproteins.
James P. Collman,Robert R. Gagne,Christopher A. Reed,Thomas R. Halbert,George Lang,Ward T. Robinson +5 more
Journal ArticleDOI
Structure of the complex formed by bovine trypsin and bovine pancreatic trypsin inhibitor: II. Crystallographic refinement at 1.9 Å resolution
Robert Huber,Dietmar Kukla,Wolfram Bode,Peter Schwager,Klaus Bartels,Johann Deisenhofer,Wolfgang Steigemann +6 more
TL;DR: An objective assessment of the upper limit of the error in the atomic coordinates of the final model is possible by comparing the inhibitor component in the model of the complex with the refined structure of the free inhibitor (Deisenhofer & Steigemann, 1974).
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Volker Schurig,H.-P. Nowotny +1 more