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Journal ArticleDOI

Design of Diketopyrrolopyrrole (DPP)-Based Small Molecules for Organic-Solar-Cell Applications.

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TLDR
The development of DPP-based photovoltaic small molecule performance is discussed in relation to structural modifications, such as the variations of donor-acceptor building blocks, alkyl substitutions, and the type of conjugated bridges, as well as end-capped groups.
Abstract
After the first report in 2008, diketopyrrolopyrrole (DPP)-based small-molecule photovoltaic materials have been intensively explored. The power conversion efficiencies (PCEs) for the DPP-based small-molecule donors have been improved up to 8%. Furthermore, through judicious structure modification, DPP-based small molecules can also be converted into electron-acceptor materials, and, recently, some exciting progress has been achieved. The development of DPP-based photovoltaic small molecules is summarized here, and the photovoltaic performance is discussed in relation to structural modifications, such as the variations of donor-acceptor building blocks, alkyl substitutions, and the type of conjugated bridges, as well as end-capped groups. It is expected that the discussion will provide a guideline in the exploration of novel and promising DPP-containing photovoltaic small molecules.

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Supramolecular Luminescent Sensors

TL;DR: Specific focus is placed on the development of new macrocycle hosts since 2010, coupled with considerations of the underlying principles of supramolecular chemistry as well as analytes of interest and common luminophores.
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Small-Molecule Acceptor Based on the Heptacyclic Benzodi(cyclopentadithiophene) Unit for Highly Efficient Nonfullerene Organic Solar Cells

TL;DR: The results demonstrate that the BDT unit could also be applied for designing NF-acceptors, and the fused-ring benzodi(cyclopentadithiophene) unit is a prospective block for designing new NF- acceptors with excellent performance.
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Benzotriazole-Based Acceptor and Donors, Coupled with Chlorination, Achieve a High VOC of 1.24 V and an Efficiency of 10.5% in Fullerene-Free Organic Solar Cells

TL;DR: In this paper, a simple "Same-A-Strategies" (SAS) strategy for constructing p-type and n-type photovoltaic materials with the same electron-accepting (A) unit of benzotriazole was adopted to initially control the energ...
Journal ArticleDOI

Fine-Tuning the Energy Levels of a Nonfullerene Small-Molecule Acceptor to Achieve a High Short-Circuit Current and a Power Conversion Efficiency over 12% in Organic Solar Cells.

TL;DR: An unusually slow but ultimately efficient charge generation mediated by interfacial charge-pair states is observed, followed by effective charge extraction of the PBDB-T:NCBDT devices, among the best for solution-processed organic solar cells.
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Organic Dye Based Nanoparticles for Cancer Phototheranostics.

TL;DR: The recent progress of organic dye-based NPs for cancer phototheranostic applications is summarized, which extends the anticancer arsenal and holds promise for clinical uses in the near future.
References
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Journal ArticleDOI

Conjugated polymer-based organic solar cells

TL;DR: This review gives a general introduction to the materials, production techniques, working principles, critical parameters, and stability of the organic solar cells, and discusses the alternative approaches such as polymer/polymer solar cells and organic/inorganic hybrid solar cells.
Journal ArticleDOI

Photoinduced electron transfer from a conducting polymer to buckminsterfullerene.

TL;DR: Because the photoluminescence in the conducting polymer is quenched by interaction with C60, the data imply that charge transfer from the excited state occurs on a picosecond time scale.
Journal ArticleDOI

Synthesis of Conjugated Polymers for Organic Solar Cell Applications

TL;DR: Fluorene-Based Copolymers ContainingPhosphorescent Complexes and Carbazole-Based Conjugated Polymers R5.1.3.
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Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells.

TL;DR: The uncovered aggregation and design rules yield three high-efficiency (>10%) donor polymers and will allow further synthetic advances and matching of both the polymer and fullerene materials, potentially leading to significantly improved performance and increased design flexibility.
Journal ArticleDOI

2.5% efficient organic plastic solar cells

TL;DR: In this article, the power conversion efficiency of organic photovoltaic devices based on a conjugated polymer/methanofullerene blend is dramatically affected by molecular morphology.
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