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Journal ArticleDOI

Development of a composite material between bacterial cellulose and E crassipes, for the treatment of water contaminated by chromium (VI)

TL;DR: In this paper, the removal of chromium (VI) by plant cellulose and bacterial cellulose was evaluated, and the capacity of these two biomasses was evaluated with different design variables such as characterizations of biomasses, adaption kinetics, adsorption capacity through Langmuir isotherms, pH influence, and desorption-adsorption capacities of each biomasses.
Abstract: In recent years, chromium water pollution has become a serious problem for aquatic environments as rivers and wetlands, and for human health. Many researchers are working on finding economic and efficient ways to solve this issue, with the objective of mitigating the damaging effluents of the industries, as in the case of the dumping of chromium. In this study, the removal of chromium (VI) by plant cellulose and bacterial cellulose was evaluated. An experiment was carried out with different initial concentrations of chromium, evaluating the ability to eliminate and adsorb this contaminant by means of biomass of E crassipes, bacterial cellulose, and the union of these two biomasses, determining which is the best biomass. Different design variables such as characterizations of biomasses, adsorption kinetics, adsorption capacities through Langmuir isotherms, pH influence, and desorption-adsorption capacities of each of these biomasses were evaluated. Concluding that the capacity of bacterial cellulose (BC) is 47 mg/g, the capacity between bacterial cellulose and E crassipes cellulose (EC + BC) is 28 mg/g and the cellulose of E crassipes (EC) is 10 mg/g. However, with the biomass of EC was given five processes of treatment more due to the power of elution that had the HCl about the Cr (VI) adhered in this biomass. But with the biomass of BC, the HCl had not the same result of elutions and alone had one treatment of Cr (VI).
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Journal ArticleDOI
TL;DR: It is evident from the literature survey presented herein that modified cellulose-based adsorbents exhibit good potential for the removal of various aquatic pollutants, however, still there is a need to find out the practical utility of these adsorbent on a commercial scale, leading to the improvement of pollution control.

747 citations

Journal ArticleDOI
TL;DR: A review of metal-organic frameworks (MOFs) for potential applications in heavy metal removal from water can be found in this paper, where the authors provide an overview of the current capabilities and important properties of MOFs used for this purpose.

672 citations

Journal ArticleDOI
TL;DR: The amino-functionalized magnetic nano-adsorbent shows a quite good capability for the rapid and efficient adsorption of metal cations and anions from aqueous solutions via the chelation or ion exchange mechanisms.

546 citations

Journal ArticleDOI
TL;DR: In this article, a novel nanoadsorbent for the removal of heavy metal ions is reported, which was first hydrolyzed to obtain cellulose nanocrystals (CNCs) and then chemically modified with succinic anhydride to obtain SCNCs.
Abstract: A novel nanoadsorbent for the removal of heavy metal ions is reported. Cotton was first hydrolyzed to obtain cellulose nanocrystals (CNCs). CNCs were then chemically modified with succinic anhydride to obtain SCNCs. The sodic nanoadsorbent (NaSCNCs) was further prepared by treatment of SCNCs with saturated NaHCO3 aqueous solution. Batch experiments were carried out with SCNCs and NaSCNCs for the removal of Pb2+ and Cd2+. The effects of contact time, pH, initial adsorption concentration, coexisting ions and the regeneration performance were investigated. Kinetic studies showed that the adsorption equilibrium time of Pb2+ and Cd2+ was reached within 150 min on SCNCs and 5 min on NaSCNCs. The adsorption capacities of Pb2+ and Cd2+ on SCNCs and NaSCNCs increased with increasing pH. The adsorption isotherm was well fitted by the Langmuir model. The maximum adsorption capacities of SCNCs and NaSCNCs for Pb2+ and Cd2+ were 367.6 mg/g, 259.7 mg/g and 465.1 mg/g, 344.8 mg/g, respectively. SCNCs and NaSCNCs showed high selectivity and interference resistance from coexisting ions for the adsorption of Pb2+. NaSCNCs could be efficiently regenerated with a mild saturated NaCl solution with no loss of capacity after two recycles. The adsorption mechanisms of SCNCs and NaSCNCs were discussed.

325 citations