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Die ambidenten Ligandeigenschaften des Bis(trimethylphosphoranyliden)methans
Hubert Schmidbaur,Oswald Gasser +1 more
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This article is published in Angewandte Chemie.The article was published on 1976-08-01. It has received 55 citations till now.read more
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Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes
TL;DR: During the last five years, new types of stable cyclic carbenes, as well as related carbon-based ligands (which are not NHCs), and which feature even stronger σ-donor properties have been developed.
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A briefing on aurophilicity.
Hubert Schmidbaur,Annette Schier +1 more
TL;DR: There is now compelling experimental evidence for the existence of specific intra- and intermolecular bonding between seemingly closed-shell gold(I) centers (5d10) which manifests itself in all areas of gold chemistry.
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Stabile cyclische Carbene und verwandte Spezies jenseits der Diaminocarbene
TL;DR: In this article, the N-heterocyclischen carbenen (NHCs) are investigated in a Gebiet with cyclischen Diaminocarbenen, den so genannten N-HE-CARBEN (NHE-Carbenen) erzielt, die sich vor allem durch ihr starkes σ-Donorverhalten auszeichnen.
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Methods of preparation of C-substituted phosphorus ylides and their application in organic synthesis
TL;DR: Methods of preparation of phosphorus ylides substituted at the carbon atom of the P=C group with atoms of various elements and their application in organic synthesis are systematised and generalised as discussed by the authors.
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Hexaphenylcarbodiphosphorane, (c6h5)3pcp(c6h5)3
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Interaction of phosphorus ylides with transition metal carbonyl compounds. Triphenylphosphinemethylene and bis(triphenylphosphine)carbon. Comparative chemistry
Journal ArticleDOI
A new type of organogold compound
A. N. Nesmeyanov,É. G. Perevalova,K. I. Grandberg,D.A. Lemenovskii,T.V. Baukova,O.B. Afanassova +5 more
TL;DR: In this paper, the structure of organometallic organogold complexes of the type [R(AuPPh3)2]-BF−4 (I) containing a univalent gold atom and an Au fragment have been synthesized.