Direct functionalization of white phosphorus by organolithium reagents to organophosphorus compounds
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This article is published in Phosphorus Sulfur and Silicon and The Related Elements.The article was published on 2021-11-30 and is currently open access. It has received 10 citations till now. The article focuses on the topics: White Phosphorus.read more
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Recent Breakthroughs in P4 Chemistry: Towards Practical, Direct Transformations into P1 Compounds
TL;DR: In this article , a series of independent reports has begun to change this state of affairs, showing how relatively simple and practical synthetic methods can be used to access academically or industrially relevant P1 compounds from P4 directly, in a one pot or even in a catalytic fashion.
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Decarboxylative Selective Phosphorylation of Aliphatic Acids: A Transition-Metal- and Photocatalyst-Free Avenue to Dialkyl and Trialkyl Phosphine Oxides from White Phosphorus.
Fushan Chen,Mengpei Bai,Yumeng Zhang,Weijie Liu,Xinlei Huangfu,Yang Liu,Guo-Min Tang,Yufen Zhao +7 more
TL;DR: In this article , a photo-induced phosphorylation reaction for the direct functionalization of white phosphorus (P 4 ) without chlorination is presented, which relies on the successive generation of carbon-centered radicals from N -hydroxyphthalimide (NHPI) esters and controllable alkylation of the P 4 molecule under transition-metal and photocatalyst-free conditions.
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Activation of CS2 with the 2H-Phosphindole Complex to Construct P,S-Polycycles.
TL;DR: In this article , the activation of CS2 by the 2H-phosphindole complex with a low-coordinate phosphadiene moiety is reported, which reveals the unique reactivity of organophosphorus species and their potential applications in small molecule activation.
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Recent Breakthroughs in P <sub>4</sub> Chemistry: Towards Practical, Direct Transformations into P <sub>1</sub> Compounds
TL;DR: For several decades, academic researchers have been intensively studying the chemistry of white phosphorus (P4) in the hope of developing direct methods for its transformation into useful P-containing products as discussed by the authors .
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Direct Synthesis of Dialkylphosphites from White Phosphorus
TL;DR: In this paper , a KBr-mediated synthesis of DAPIs involving P4, alcohols and water is presented, with the use of silica gel as the catalyst, oxone as the safe oxidant, and industrially important (EtO)2P(O)H, (i-PrO) 2P(E)H and (MeO)
References
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New Chiral Phosphorus Ligands for Enantioselective Hydrogenation
Wenjun Tang,Xumu Zhang +1 more
TL;DR: The increasing demand to produce enantiomerically pure pharmaceuticals, agrochemicals, flavors, and other fine chemicals has advanced the field of asymmetric catalytic technologies, and asymmetric hydrogenation utilizing molecular hydrogen to reduce prochiral olefins, ketones, and imines has become one of the most efficient methods for constructing chiral compounds.
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P4 Activation by Main Group Elements and Compounds
TL;DR: An overview about the activation of white phosphorus, P4 with main group elements and compounds is given.
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Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus
TL;DR: The MIT Faculty has made this article openly available and the public is invited to share how this access benefits you.
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P4 Activation by Late-Transition Metal Complexes†‡
TL;DR: The coordination chemistry of white phosphorus is nowadays a mature discipline, which during the last four decades has reached a deep understanding of the mechanisms governing the metal-mediated activation of this unique and highly reactive molecule.