Drops can bounce from perfectly hydrophilic surfaces
TL;DR: In this article, the authors show that drops can also rebound from a superhydrophilic solid surface such as an atomically smooth mica sheet, but the coefficient of restitution CR associated with this process is significantly lower than that associated with rebound from super-hydrophobic surfaces.
Abstract: Drops are well known to rebound from superhydrophobic surfaces and from liquid surfaces. Here, we show that drops can also rebound from a superhydrophilic solid surface such as an atomically smooth mica sheet. However, the coefficient of restitution CR associated with this process is significantly lower than that associated with rebound from superhydrophobic surfaces. A direct imaging method allows us to characterize the dynamics of the deformation of the drop in entering the vicinity of the surface. We find that drop bouncing occurs without the drop ever touching the solid and there is a nanometer-scale film of air that separates the liquid and solid, suggesting that shear in the air film is the dominant source of dissipation during rebound. Furthermore, we see that any discrete nanometer-height defects on an otherwise hydrophilic surface, such as treated glass, completely inhibits the bouncing of the drop, causing the liquid to wet the surface. Our study adds a new facet to the dynamics of droplet impact by emphasizing that the thin film of air can play a role not just in the context of splashing but also bouncing, while highlighting the role of rare surface defects in inhibiting this response.
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TL;DR: In this article, the authors focus on recent experimental and theoretical studies, which aim at unraveling the underlying physics, characterized by the delicate interplay of liquid inertia, viscosity, and surface tension, but also the surrounding gas.
Abstract: A drop hitting a solid surface can deposit, bounce, or splash. Splashing arises from the breakup of a fine liquid sheet that is ejected radially along the substrate. Bouncing and deposition depend crucially on the wetting properties of the substrate. In this review, we focus on recent experimental and theoretical studies, which aim at unraveling the underlying physics, characterized by the delicate interplay of not only liquid inertia, viscosity, and surface tension, but also the surrounding gas. The gas cushions the initial contact; it is entrapped in a central microbubble on the substrate; and it promotes the so-called corona splash, by lifting the lamella away from the solid. Particular attention is paid to the influence of surface roughness, natural or engineered to enhance repellency, relevant in many applications.
994 citations
Cites background from "Drops can bounce from perfectly hyd..."
...Thirdly, Kolinski et al. (2012) (see also Kolinski et al. (2014); de Ruiter et al. (2015a)) showed clearly the formation of isolated wetting contacts and that increasing the impact velocity causes larger number of contacts along the ring bounding the central disc....
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...Some signature is also observed due to an evanescent wave, when the air-layer becomes a few tens of nano-meters, allowing measurements of the bottom profile of the drop (Kolinski et al. (2014))....
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TL;DR: It is shown that a drop impinging on Echevaria leaves exhibits asymmetric bouncing dynamics with distinct spreading and retraction along two perpendicular directions, which results from an asymmetric momentum and mass distribution that allows for preferential fluid pumping around the drop rim.
Abstract: The impact of liquid drops on solid surfaces is ubiquitous in nature, and of practical importance in many industrial processes. A drop hitting a flat surface retains a circular symmetry throughout the impact process. Here we show that a drop impinging on Echevaria leaves exhibits asymmetric bouncing dynamics with distinct spreading and retraction along two perpendicular directions. This is a direct consequence of the cylindrical leaves that have a convex/concave architecture of size comparable to the drop. Systematic experimental investigations on mimetic surfaces and lattice Boltzmann simulations reveal that this novel phenomenon results from an asymmetric momentum and mass distribution that allows for preferential fluid pumping around the drop rim. The asymmetry of the bouncing leads to ∼40% reduction in contact time.
332 citations
TL;DR: It is demonstrated that the manifestation of such a superhydrophobic-like bouncing necessitates an intricate interplay between the Weber number, the thickness and viscosity of liquid film, and the restitution coefficient independent of underlying liquid film.
Abstract: Droplet impacting on solid or liquid interfaces is a ubiquitous phenomenon in nature. Although complete rebound of droplets is widely observed on superhydrophobic surfaces, the bouncing of droplets on liquid is usually vulnerable due to easy collapse of entrapped air pocket underneath the impinging droplet. Here, we report a superhydrophobic-like bouncing regime on thin liquid film, characterized by the contact time, the spreading dynamics, and the restitution coefficient independent of underlying liquid film. Through experimental exploration and theoretical analysis, we demonstrate that the manifestation of such a superhydrophobic-like bouncing necessitates an intricate interplay between the Weber number, the thickness and viscosity of liquid film. Such insights allow us to tune the droplet behaviours in a well-controlled fashion. We anticipate that the combination of superhydrophobic-like bouncing with inherent advantages of emerging slippery liquid interfaces will find a wide range of applications.
222 citations
TL;DR: The development of bio-inspired interfacial materials with enhanced drop mobility that mimic the innate functionalities of nature will have a significant impact on the energy, environment and global healthcare.
Abstract: The development of bioinspired interfacial materials with enhanced drop mobility that mimic the innate functionalities of nature will have a significant impact on the energy, environment and global healthcare. Despite extensive progress, state of the art interfacial materials have not reached the level of maturity sufficient for industrial applications in terms of scalability, stability, and reliability. These are complicated by their operating environments and lack of facile approaches to control the local structural texture and chemical composition at multiple length scales. The recent advances in the fundamental understanding are reviewed, as well as practical applications of bioinspired interfacial materials, with an emphasis on the drop bouncing and coalescence-induced jumping behaviors. Perspectives on how to catalyze new discoveries and to foster technological adoption to move this exciting area forward are also suggested.
184 citations
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TL;DR: The recent advances in the fundamental understanding are reviewed, as well as practical applications of bioinspired interfacial materials, with an emphasis on the drop bouncing and coalescence-induced jumping behaviors.
Abstract: The development of bio-inspired interfacial materials with enhanced drop mobility that mimic the innate functionalities of nature will have significant impact on the energy, environment and global healthcare. In spite of extensive progress, the state of the art of interfacial materials have not reached the level of maturity sufficient for industrial applications in terms of scalability, stability and reliability, which are complicated by their operating environments and lack of facile approaches to exquisitely control the local structural texture and chemical composition at multiple length scales. In this review, we focus on the recent advances in the fundamental understanding as well as practical applications of bio-inspired interfacial materials, with an emphasis on the drop impact induced bouncing and coalescence induced jumping behaviors. We also suggest our own perspectives on how to catalyze new discoveries and to foster technological adoption to move this exciting area forward.
133 citations
References
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TL;DR: In this article, a review deals with drop impacts on thin liquid layers and dry surfaces, referred to as splashing, and their propagation is discussed in detail, as well as some additional kindred, albeit nonsplashing, phenomena like drop spreading and deposition, receding (recoil), jetting, fingering, and rebound.
Abstract: The review deals with drop impacts on thin liquid layers and dry surfaces. The impacts resulting in crown formation are referred to as splashing. Crowns and their propagation are discussed in detail, as well as some additional kindred, albeit nonsplashing, phenomena like drop spreading and deposition, receding (recoil), jetting, fingering, and rebound. The review begins with an explanation of various practical motivations feeding the interest in the fascinating phenomena of drop impact, and the above-mentioned topics are then considered in their experimental, theoretical, and computational aspects.
2,077 citations
TL;DR: In this article, the authors showed that fractal surfaces can be super water repellent (superwettable) when the surfaces are composed of hydrophobic (hydrophilic) materials.
Abstract: Wettability of fractal surfaces has been studied both theoretically and experimentally. The contact angle of a liquid droplet placed on a fractal surface is expressed as a function of the fractal dimension, the range of fractal behavior, and the contacting ratio of the surface. The result shows that fractal surfaces can be super water repellent (superwettable) when the surfaces are composed of hydrophobic (hydrophilic) materials. We also demonstrate a super-water-repellent fractal surface made of alkylketene dimer; a water droplet on this surface has a contact angle as large as 174°.
1,500 citations
TL;DR: This work measures how long the drop remains in contact with the solid during the shock to help quantify the efficiency of water-repellent surfaces (super-hydrophobic solids) and to improve water-cooling of hot solids, which is limited by the rebounding of drops as well as by temperature effects.
Abstract: When a liquid drop lands on a solid surface without wetting it, it bounces with remarkable elasticity. Here we measure how long the drop remains in contact with the solid during the shock, a problem that was considered by Hertz for a bouncing ball. Our findings could help to quantify the efficiency of water-repellent surfaces (super-hydrophobic solids) and to improve water-cooling of hot solids, which is limited by the rebounding of drops as well as by temperature effects.
888 citations
TL;DR: It is demonstrated that it is possible to reduce the contact time below this theoretical limit by using superhydrophobic surfaces with a morphology that redistributes the liquid mass and thereby alters the drop hydrodynamics.
Abstract: Surfaces designed so that drops do not adhere to them but instead bounce off have received substantial attention because of their ability to stay dry, self-clean and resist icing. A drop striking a non-wetting surface of this type will spread out to a maximum diameter and then recoil to such an extent that it completely rebounds and leaves the solid material. The amount of time that the drop is in contact with the solid--the 'contact time'--depends on the inertia and capillarity of the drop, internal dissipation and surface-liquid interactions. And because contact time controls the extent to which mass, momentum and energy are exchanged between drop and surface, it is often advantageous to minimize it. The conventional approach has been to minimize surface-liquid interactions that can lead to contact line pinning; but even in the absence of any surface interactions, drop hydrodynamics imposes a minimum contact time that was conventionally assumed to be attained with axisymmetrically spreading and recoiling drops. Here we demonstrate that it is possible to reduce the contact time below this theoretical limit by using superhydrophobic surfaces with a morphology that redistributes the liquid mass and thereby alters the drop hydrodynamics. We show theoretically and experimentally that this approach allows us to reduce the overall contact time between a bouncing drop and a surface below what was previously thought possible.
821 citations
TL;DR: In this article, the fractal dimension of the solid AKD surface was determined to be D ≈ 2.3 applying the box-counting method to the SEM images of the AKD cross section.
Abstract: Super water-repellent surfaces showing a contact angle of 174° for water droplets have been made of alkylketene dimer (AKD). Water droplets roll around without attachment on the super water-repellent surfaces when tilted slightly. The AKD is a kind of wax and forms spontaneously a fractal structure in its surfaces by solidification from the melt. The fractal surfaces of AKD repel a water droplet completely and show a contact angle larger than 170° without any fluorination treatments. Theoretical prediction of the wettability of the fractal surfaces has been given in the previous paper.3 The relationship between the contact angle of the flat surface θ and that of the fractal surface θf is expressed by the equation cos θf = (L/l)D-2 cos θ where (L/l)D-2 is the surface area magnification factor. The fractal dimension of the solid AKD surface was determined to be D ≈ 2.3 applying the box-counting method to the SEM images of the AKD cross section. L and l, which are the largest and the smallest size limits of ...
786 citations