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Journal ArticleDOI

Effect of chemical modifications of the pineapple leaf fiber surfaces on the interfacial and mechanical properties of laminated biocomposites

01 Mar 2008-Composite Interfaces (Taylor & Francis Group)-Vol. 15, pp 169-191
TL;DR: In this paper, the effects of surface treatment of pineapple leaf fibers on the performance of fiber-reinforced composites were analyzed using X-ray photo-electron spectroscopy (XPS) and Fourier transform infrared spectrograms (FTIR).
Abstract: Natural fiber reinforced renewable resource based laminated composites were prepared from biodegradable poly(lactic acid) (PLA) and untreated or surface-treated pineapple leaf fibers (PALF) by compression molding using the film stacking method. The objective of this study was to determine the effects of surface treatment of PALF on the performance of the fiber-reinforced composites. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) were used to aid in the analysis. The mechanical properties of the PLA laminated composites were improved significantly after chemical treatment. It was found that both silane- and alkali-treated fiber reinforced composites offered superior mechanical properties compared to untreated fiber reinforced composites. The effects of temperature on the viscoelastic properties of composites were studied by dynamic mechanical analysis (DMA). From the DMA results, incorporation of the PALF fibers resulted in a considerable increase of the storage m...
Citations
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Journal ArticleDOI
TL;DR: A comprehensive review of literature on bio-fiber reinforced composites is presented in this paper, where the overall characteristics of reinforcing fibers used in biocomposites, including source, type, structure, composition, as well as mechanical properties, are reviewed.

3,074 citations

Journal ArticleDOI
TL;DR: In this paper, a brief outline of work that covers in the area of biocomposites, major class of biodegradable polymers, natural fibres, as well as their manufacturing techniques and properties has been highlighted.
Abstract: The growing ecological and environmental consciousness has driven efforts for development of new innovative materials for various end-use applications. Polymers synthesized from natural resources, have gained considerable research interest in the recent years. This review paper is intended to provide a brief outline of work that covers in the area of biocomposites, major class of biodegradable polymers, natural fibres, as well as their manufacturing techniques and properties has been highlighted. Various surface modification methods were incorporated to improve the fibre–matrix adhesion resulting in the enhancement of mechanical properties of the biocomposites. Moreover, an economical impact and future direction of these materials has been critically reviewed. This review concludes that the biocomposites form one of the emerging areas in polymer science that gain attention for use in various applications ranging from automobile to the building industries.

894 citations

Journal ArticleDOI
TL;DR: In this paper, the authors present an up-do-date review on natural fiber and resin types and sources, modification and processing techniques, physical and mechanical behaviors, applications, life-cycle assessment, and other properties of green composites.
Abstract: There has been much effort to provide eco-friendly and biodegradable materials for the next generation of composite products owing to global environmental concerns and increased awareness of renewable green resources. An increase in the use of natural materials in composites has led to a reduction in greenhouse gas emissions and carbon footprint of composites. In addition to the benefits obtained from green materials, there are some challenges in working with them, such as poor compatibility between the reinforcing natural fiber and matrix and the relatively high moisture absorption of natural fibers. Green composites can be a suitable alternative for petroleum-based materials. However, before this can be accomplished, there are a number of issues that need to be addressed, including poor interfacial adhesion between the matrix and natural fibers, moisture absorption, poor fire resistance, low impact strength, and low durability. Several researchers have studied the properties of natural fiber composites. These investigations have resulted in the development of several procedures for modifying natural fibers and resins. To address the increasing demand to use eco-friendly materials in different applications, an up-do-date review on natural fiber and resin types and sources, modification and processing techniques, physical and mechanical behaviors, applications, life-cycle assessment, and other properties of green composites is required to provide a better understanding of the behavior of green composites. This paper presents such a review based on 322 studies published since 1978.

393 citations

Journal ArticleDOI
TL;DR: A detailed study of chemical, physical, and mechanical properties will bring out logical and reasonable utilization of Pineapple leave fibres for various applications as mentioned in this paper, which can be a new source of raw material to the industries and can be potential replacement of the expensive and non-renewable synthetic fibre.
Abstract: Natural fibre based composites are under intensive study due to their ecofriendly nature and peculiar properties. The advantage of natural fibres is their continuous supply, easy and safe handling, and biodegradable nature. Although natural fibres exhibit admirable physical and mechanical properties, it varies with the plant source, species, geography, and so forth. Pineapple leave fibre (PALF) is one of the abundantly available wastes materials of Malaysia and has not been studied yet as it is required. A detailed study of chemical, physical, and mechanical properties will bring out logical and reasonable utilization of PALF for various applications. From the socioeconomic prospective, PALF can be a new source of raw material to the industries and can be potential replacement of the expensive and nonrenewable synthetic fibre. However, few studies on PALF have been done describing the interfacial adhesion between fibres and reinforcement compatibility of fibre but a detailed study on PALF properties is not available. In this review, author covered the basic information of PALF and compared the chemical, physical, and mechanical properties with other natural fibres. Furthermore, it summarizes the recent work reported on physical, mechanical, and thermal properties of PALF reinforced polymer composites with its potential applications.

379 citations

Journal ArticleDOI
TL;DR: In this paper, the effects of alkali, silane and combined alkali and silane treatments on the mechanical (tensile), morphological, and structural properties of Pine Apple Leave Fibres (PALF) and Kenaf fibres (KF) were investigated with the aim to improve their compatibility with polymer matrices.

250 citations

References
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Journal ArticleDOI
TL;DR: In this article, a survey about physical and chemical treatment methods which improve the fiber matrix adhesion, their results and effects on the physical properties of composites is presented, and the influence of such treatments by taking into account fibre content on the creep, quasi-static, cyclic dynamic and impact behaviour of natural fibre reinforced plastics are discussed in detail.

4,160 citations

Journal ArticleDOI
TL;DR: The structural aspects and properties of several biofibers and biodegradable polymers, recent developments of different biofiber and biocomposites are discussed in this paper.
Abstract: Recently the critical discussion about the preservation of natural resources and recycling has led to the renewed interest concerning biomaterials with the focus on renewable raw materials. Because of increasing environmental consciousness and demands of legislative authorities, use and removal of traditional composite structures, usually made of glass, carbon or aramid fibers being reinforced with epoxy, unsaturated polyester, or phenolics, are considered critically. Recent advances in natural fiber development, genetic engineering and composite science offer significant opportunities for improved materials from renewable resources with enhanced support for global sustainability. The important feature of composite materials is that they can be designed and tailored to meet different requirements. Since natural fibers are cheap and biodegradable, the biodegradable composites from biofibers and biodegradable polymers will render a contribution in the 21st century due to serious environmental problem. Biodegradable polymers have offered scientists a possible solution to waste-disposal problems associated with traditional petroleum-derived plastics. For scientists the real challenge lies in finding applications which would consume sufficiently large quantities of these materials to lead price reduction, allowing biodegradable polymers to compete economically in the market. Today's much better performance of traditional plastics are the outcome of continued RD however the existing biodegradable polymers came to public only few years back. Prices of biodegradable polymers can be reduced on mass scale production; and such mass scale production will be feasible through constant R&D efforts of scientists to improve the performance of biodegradable plastics. Manufacture of biodegradable composites from such biodegradable plastics will enhance the demand of such materials. The structural aspects and properties of several biofibers and biodegradable polymers, recent developments of different biodegradable polymers and biocomposites are discussed in this review article. Collaborative R&D efforts among material scientists and engineers as well as intensive co-operation and co-ordination among industries, research institutions and government are essential to find various commercial applications of biocomposites even beyond to our imagination.

2,612 citations

Book
01 Jan 1971
TL;DR: The Science of Large Molecules POLYMERIZATION Step-Reaction (Condensation) Polymerization Radical Chain (Addition) PolyMERization Ionic and Coordination Chain (addition) Copolymerization Polymerisation Conditions and Polymer Reactions CHARACTERIZATION Polymer Solutions Measurement of Molecular Weight and Size Analysis and Testing of Polymers STRUCTURE and PROPERTIES Morphology and Order in Crystalline Polymers Rheology and the Mechanical Properties of Polymer Structure and Physical Properties as mentioned in this paper.
Abstract: The Science of Large Molecules POLYMERIZATION Step-Reaction (Condensation) Polymerization Radical Chain (Addition) Polymerization Ionic and Coordination Chain (Addition) Polymerization Copolymerization Polymerization Conditions and Polymer Reactions CHARACTERIZATION Polymer Solutions Measurement of Molecular Weight and Size Analysis and Testing of Polymers STRUCTURE AND PROPERTIES Morphology and Order in Crystalline Polymers Rheology and the Mechanical Properties of Polymers Polymer Structure and Physical Properties PROPERTIES OF COMMERICAL POLYMERS Hydrocarbon Plastics and Elastomers Other Carbon-Chain Polymers Heterochain Thermoplastics Thermosetting Resins POLYMER PROCESSING Plastics Technology Fiber Technology Elastomer Technology Appendixes Author and Subject Indexes.

1,703 citations

Book
Edwin P. Plueddemann1
01 Aug 1982
TL;DR: In this article, a novel organosilane coupling agent is described and its use as an adhesion promoter in mineral-filled unsaturated polymer systems is described, where the coupling agent comprises the reaction product of an isocyanatoalkyl ester of acrylic or methacrylic acid with an aminoorganosilanes.
Abstract: A novel organosilane coupling agent is disclosed and its use as an adhesion promoter in mineral-filled unsaturated polymer systems is described. Additionally, use of the organosilane as a primer for various substrates is presented. The coupling agent comprises the reaction product of an isocyanatoalkyl ester of acrylic or methacrylic acid with an aminoorganosilane. The organosilane so formed links the acryloxyalkyl or methacryloxyalkyl functionality to an alkylene, or aminoalkylene, group on the silicon atom through a urea group. Use of the organosilane as a coupling agent in a mineral-filled unsaturated polymer results in superior resistance to moisture, particularly when the polymer is selected from the group of corrosion resistant unsaturated polyesters.

1,522 citations

Book
01 Jan 1995
TL;DR: The authors provided the basic building blocks of polymer science and engineering by coverage of fundamental polymer chemistry and materials topics given in Chapters 1 through 7 and provided information on the exciting new materialsnow available and the emerging areas of technological growth that could motivate a new generation of scientists and engineers.
Abstract: From the Book: PREFACE: At least dozens of good introductory textbooks on polymer science and engineering are now available. Why then has yet another book been written? The decision was based on my belief that none of the available texts fully addresses the needs of students in chemical engineering. It is not that chemical engineers are a rare breed, but rather that they have special training in areas of thermodynamics and transport phenomena that is seldom challenged by texts designed primarily for students of chemistry or materials science. This has been a frustration of mine and of many of my students for the past 15 years during which I have taught an introductory course, Polymer Technology, to some 350 chemical engineering seniors. In response to this perceived need, I had written nine review articles that appeared in the SPE publication Plastics Engineering from 1982 to 1984. These served as hard copy for my students to supplement their classroom notes but fell short of a complete solution. In writing this text, it was my objective to first provide the basic building blocks of polymer science and engineering by coverage of fundamental polymer chemistry and materials topics given in Chapters 1 through 7. As a supplement to the traditional coverage of polymer thermodynamics, extensive discussion of phase equilibria, equation-of- state theories, and UNIFAC has been included in Chapter 3. Coverage of rheology, including the use of constitutive equations and the modeling of simple flow geometries, and the fundamentals of polymer processing operations are given in Chapter 11. Finally, I wanted to provide information on the exciting new materialsnowavailable and the emerging areas of technological growth that could motivate a new generation of scientists and engineers. For this reason, engineering and specialty polymers are surveyed in Chapter 10 and important new applications for polymers in separations (membrane separations), electronics (conducting polymers), biotechnology (controlled drug release), and other specialized areas of engineering are given in Chapter 12. In all, this has been an ambitious undertaking and I hope that I have succeeded in at least some of these goals. Although the intended audience for this text is advanced undergraduates and graduate students in chemical engineering, the coverage of polymer science fundamentals (Chapters 1 through 7) should be suitable for a semester course in a materials science or chemistry curriculum. Chapters 8 through 10 intended as survey chapters of the principal categories of polymers commodity thermoplastics and fibers, network polymers (elastomers and thermosets), and engineering and specialty polymers may be included to supplement and reinforce the material presented in the chapters on fundamentals and should serve as a useful reference source for the practicing scientist or engineer in the plastics industry.

981 citations