Effect of different carbon nano-fillers on rheological properties and lap shear strength of epoxy adhesive joints
TL;DR: In this paper, the rheological properties, thermal stability and the lap shear strength of epoxy adhesive joints reinforced with different carbon nano-fillers such as multi-walled carbon nanotubes (CNT), graphene nanoplatelets (GNP), and single-wall carbon nanohorns (CNH) have been studied.
Abstract: In this work, the rheological properties, thermal stability and the lap shear strength of epoxy adhesive joints reinforced with different carbon nano-fillers such as multi-walled carbon nanotubes (CNT), graphene nanoplatelets (GNP) and single-walled carbon nanohorns (CNH) have been studied. The nano-fillers were dispersed homogeneously using Brabender® Plasti-Corder®. The epoxy pre-polymer with and without the nano-fillers exhibited shear thinning behavior. The nano-filler epoxy mixtures exhibited a viscoplastic behavior which was analyzed using Casson’s model. Thermo-gravimetric analysis indicated an increase in the thermal stability of the epoxy with the addition of carbon nano-fillers. Carbon nano-fillers resulted in increased lap shear strength having high Weibull modulus. The joint strength increased by 53%, 49% and 46% with the addition of 1 wt.% CNT, 0.5 wt.% GNP and 0.5 wt.% CNH, respectively. The strength of the joints having high filler content (>1 wt.%) was limited by mixed mode type of failure.
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TL;DR: In this article, state-of-the-art of technical enhancements on epoxy-based coating systems, performed over the past few years, are summarized and analyzed in this work, considering the difference of failure modes, comparisons between the technical methods in terms of the effect in improvement, supporting mechanism, occasions of use, etc.
Abstract: Epoxy is widely adopted in the coating industry because of its excellent performance, which can be applied to the surfaces of metal and non-metal structures for protection and/or decoration purposes. The strength of adhesion and cohesion is an essential prerequisite for coating, which will directly affect the performance and its applications. In the light of the mechanisms of adhesion and cohesion, state-of-the-art of technical enhancements on epoxy-based coating systems, performed over the past few years, are summarized and analyzed in this work. Considering the difference of failure modes, comparisons between the technical methods in terms of the effect in improvement, supporting mechanism, occasions of use, etc. Were compiled. It should be pointed out that research referring to the methods for improving the adhesive and cohesive strength of the applied coating mainly focused on the substrates, fillers and resins, whereas the work related to micro-scale mechanism of adhesion and cohesion, hybridizing nanoscale fillers, and compounded methods have already become a popular path for related research till the moment.
106 citations
TL;DR: In this article, the recent progress to improve the target properties of epoxy adhesives such as mechanical properties, fracture toughness and thermal stability in the present of nanoparticles are discussed.
99 citations
TL;DR: In this article, the influence of the type and content of graphene nanoplatelets (GNP) on the thermo-mechanical and adhesive properties of epoxy-graphene nanocomposites was investigated.
90 citations
TL;DR: In this paper, composites with different carbonaceous nanofillers, prepared by solution casting, were studied their chemical, mechanical, electrical and electro-mechanical properties evaluated.
77 citations
TL;DR: In this paper, the research advances on epoxy-based nanocomposites as adhesive materials are reported and the effect of different nano-fillers on the mechanical properties and the joint strength of epoxy are reported.
71 citations
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TL;DR: In this paper, a review of the current understanding of carbon nanotubes and CNT/polymer nanocomposites with two particular topics: (i) the principles and techniques for CNT dispersion and functionalization and (ii) the effects of CNT-based functionalization on the properties of polymers.
Abstract: Carbon nanotubes (CNTs) hold the promise of delivering exceptional mechanical properties and multi-functional characteristics. Ever-increasing interest in applying CNTs in many different fields has led to continued efforts to develop dispersion and functionalization techniques. To employ CNTs as effective reinforcement in polymer nanocomposites, proper dispersion and appropriate interfacial adhesion between the CNTs and polymer matrix have to be guaranteed. This paper reviews the current understanding of CNTs and CNT/polymer nanocomposites with two particular topics: (i) the principles and techniques for CNT dispersion and functionalization and (ii) the effects of CNT dispersion and functionalization on the properties of CNT/polymer nanocomposites. The fabrication techniques and potential applications of CNT/polymer nanocomposites are also highlighted.
2,849 citations
TL;DR: In this article, the effects of particle size, particle/matrix interface adhesion and particle loading on the stiffness, strength and toughness of such particulate polymer composites are reviewed.
Abstract: There have been a number of review papers on layered silicate and carbon nanotube reinforced polymer nanocomposites, in which the fillers have high aspect ratios. Particulate–polymer nanocomposites containing fillers with small aspect ratios are also an important class of polymer composites. However, they have been apparently overlooked. Thus, in this paper, detailed discussions on the effects of particle size, particle/matrix interface adhesion and particle loading on the stiffness, strength and toughness of such particulate–polymer composites are reviewed. To develop high performance particulate composites, it is necessary to have some basic understanding of the stiffening, strengthening and toughening mechanisms of these composites. A critical evaluation of published experimental results in comparison with theoretical models is given.
2,767 citations
TL;DR: Graphene platelets significantly out-perform carbon nanotube additives in terms of mechanical properties enhancement, and may be related to their high specific surface area, enhanced nanofiller-matrix adhesion/interlocking arising from their wrinkled (rough) surface, as well as the two-dimensional geometry of graphene platelets.
Abstract: In this study, the mechanical properties of epoxy nanocomposites with graphene platelets, single-walled carbon nanotubes, and multi-walled carbon nanotube additives were compared at a nanofiller weight fraction of 0.1 ± 0.002%. The mechanical properties measured were the Young’s modulus, ultimate tensile strength, fracture toughness, fracture energy, and the material’s resistance to fatigue crack propagation. The results indicate that graphene platelets significantly out-perform carbon nanotube additives. The Young’s modulus of the graphene nanocomposite was ∼31% greater than the pristine epoxy as compared to ∼3% increase for single-walled carbon nanotubes. The tensile strength of the baseline epoxy was enhanced by ∼40% with graphene platelets compared to ∼14% improvement for multi-walled carbon nanotubes. The mode I fracture toughness of the nanocomposite with graphene platelets showed ∼53% increase over the epoxy compared to ∼20% improvement for multi-walled carbon nanotubes. The fatigue resistance resu...
2,367 citations
TL;DR: In this paper, the mechanical behavior of multi-walled carbon nanotube/epoxy composites was studied in both tension and compression, and it was found that the compression modulus is higher than the tensile modulus, indicating that load transfer to the nanotubes in the composite is much higher in compression.
Abstract: The mechanical behavior of multiwalled carbon nanotube/epoxy composites was studied in both tension and compression. It was found that the compression modulus is higher than the tensile modulus, indicating that load transfer to the nanotubes in the composite is much higher in compression. In addition, it was found that the Raman peak position, indicating the strain in the carbon bonds under loading, shifts significantly under compression but not in tension. It is proposed that during load transfer to multiwalled nanotubes, only the outer layers are stressed in tension whereas all the layers respond in compression.
1,617 citations
TL;DR: In this paper, a review summarises the research work carried out in the field of carbon nanotube (CNT) metal matrix composites (MMCs), focusing on the critical issues of CNT-reinforced MMCs that include processing techniques, nanotubes dispersion, interface, strengthening mechanisms and mechanical properties.
Abstract: This review summarises the research work carried out in the field of carbon nanotube (CNT) metal matrix composites (MMCs). Much research has been undertaken in utilising CNTs as reinforcement for composite material. However, CNT-reinforced MMCs have received the least attention. These composites are being projected for use in structural applications for their high specific strength as well as functional materials for their exciting thermal and electrical characteristics. The present review focuses on the critical issues of CNT-reinforced MMCs that include processing techniques, nanotube dispersion, interface, strengthening mechanisms and mechanical properties. Processing techniques used for synthesis of the composites have been critically reviewed with an objective to achieve homogeneous distribution of carbon nanotubes in the matrix. The mechanical property improvements achieved by addition of CNTs in various metal matrix systems are summarised. The factors determining strengthening achieved by CNT reinforcement are elucidated as are the structural and chemical stability of CNTs in different metal matrixes and the importance of the CNT/metal interface has been reviewed. The importance of CNT dispersion and its quantification is highlighted. Carbon nanotube reinforced MMCs as functional materials are summarised. Future work that needs attention is addressed.
1,265 citations