Journal ArticleDOI
Effect of structure on the rate of pyramidal inversion of acyclic phosphines
Raymond D. Baechler,Kurt Mislow +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1970-05-01. It has received 170 citations till now. The article focuses on the topics: Inversion (discrete mathematics).read more
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Structurally Constrained Boron-, Nitrogen-, Silicon-, and Phosphorus-Centered Polycyclic π-Conjugated Systems.
TL;DR: This review will specifically focus on historical developments of structurally constrained polycyclic ρ-electron systems particularly of those with boron, nitrogen, silicon, or phosphorus atoms annulated directly into the center of π-conjugated systems.
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P-chiral bis(trialkylphosphine) ligands and their use in highly enantioselective hydrogenation reactions
Tsuneo Imamoto,Junko Watanabe,Yoshiyuki Wada,Hideki Masuda,Hironari Yamada,Hideyuki Tsuruta,Satoru Matsukawa,Kentaro Yamaguchi +7 more
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Applications and stereoselective syntheses of P-chirogenic phosphorus compounds
TL;DR: The best stereoselective or asymmetric syntheses, the most efficient P*-building blocks and functionalisation of P-chirogenic compounds, in the light of chiral phosphorus compound applications are reported.
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Catalytic enantioselective synthesis of P-stereogenic compounds
TL;DR: The dynamic kinetic resolution of racemic P-templates relying on a P-C bond-forming event has been the object of extensive investigations, which have culminated with the arylation and alkylation (benzylation) of equilibrating diastereomeric palladium, platinum or ruthenium phosphido complexes.