Effect of the fluid-wall interaction on freezing of confined fluids: Toward the development of a global phase diagram
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Cites background from "Effect of the fluid-wall interactio..."
...[30], an elevation in freezing temperature for fluids confined in slit-shaped pores was found to occur when the dimensionless parameter, a*=2p 1⁄4 rw1fws2 fw (Equation (2)), was greater than 1....
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...[30], which is based on a principle of corresponding states, was developed for pore widths ....
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8 citations
Cites background from "Effect of the fluid-wall interactio..."
...Tracking structural transitions is important for a wide variety of applications, including elucidating thermodynamic transitions [57, 348, 349, 350, 351] and assembly pathways [29, 352, 353, 268]....
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..., the spatial ordering within a single plane in a confined fluid [350,351] or the crystalline arrangement of cylindrical domain [298, 314]) and “q"” is used when we wish to describe the 3d ordering (e....
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7 citations
7 citations
Cites background from "Effect of the fluid-wall interactio..."
...The crystallization of organic compounds, minerals, polymers, and metals in porous glass and other confined systems has been studied for a long time, see, for example, the recent review of Gelb et al.[20] As recalled in the introduction, the effect of a decrease of the melting temperatures Tm, with the confined size is well known; in addition only a few cases of increase have been reported....
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...This effect has been explained by simulation works.([20]) Recently, Wautelet([26]) has proposed a phenomenological model, based on the surface phonon interaction theory, to estimate the variation of Tm with 1=‘c....
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...It must be noted that similar increases or decreases of the melting temperature Tm are observed in organic, mineral, and metallic materials, which are crystallized in confined geometry.([20]) By various spectroscopy methods, the relaxation map of the GFM can be obtained in a large domain of frequency, 10(6) < n < 10 (2)....
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...The crystallization of organic compounds, minerals, polymers, and metals in porous glass and other confined systems has been studied for a long time, see, for example, the recent review of Gelb et al.([20]) As recalled in the introduction, the effect of a decrease of the melting temperatures Tm, with the confined size is well known; in addition only a few cases of increase have been reported....
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References
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