scispace - formally typeset
Search or ask a question
Journal ArticleDOI

Effects of Expandable Graphite and Modified Ammonium Polyphosphate on the Flame-Retardant and Mechanical Properties of Wood Flour-Polypropylene Composites:

01 Sep 2013-Polymers & Polymer Composites (SAGE PublicationsSage UK: London, England)-Vol. 21, Iss: 7, pp 449-456
TL;DR: In this paper, the effect of expandable graphite (EG) and ammonium polyphosphate modified with 3-(methylacryloxyl) propyltrimethoxy silane (M-APP) on the flame retardancy and mechanical performance was investigated.
Abstract: In this work, the effect of both the expandable graphite (EG) and ammonium polyphosphate modified with 3-(methylacryloxyl) propyltrimethoxy silane (M-APP) on the flame retardancy and mechanical pro...
Citations
More filters
Journal ArticleDOI
01 Aug 2018-PLOS ONE
TL;DR: It is shown that the most commonly used plastics produce two greenhouse gases, methane and ethylene, when exposed to ambient solar radiation, and plastics represent a heretofore unrecognized source of climate-relevant trace gases that are expected to increase as more plastic is produced and accumulated in the environment.
Abstract: Mass production of plastics started nearly 70 years ago and the production rate is expected to double over the next two decades. While serving many applications because of their durability, stability and low cost, plastics have deleterious effects on the environment. Plastic is known to release a variety of chemicals during degradation, which has a negative impact on biota. Here, we show that the most commonly used plastics produce two greenhouse gases, methane and ethylene, when exposed to ambient solar radiation. Polyethylene, which is the most produced and discarded synthetic polymer globally, is the most prolific emitter of both gases. We demonstrate that the production of trace gases from virgin low-density polyethylene increase with time, with rates at the end of a 212-day incubation of 5.8 nmol g-1 d-1 of methane, 14.5 nmol g-1 d-1 of ethylene, 3.9 nmol g-1 d-1 of ethane and 9.7 nmol g-1 d-1 of propylene. Environmentally aged plastics incubated in water for at least 152 days also produced hydrocarbon gases. In addition, low-density polyethylene emits these gases when incubated in air at rates ~2 times and ~76 times higher than when incubated in water for methane and ethylene, respectively. Our results show that plastics represent a heretofore unrecognized source of climate-relevant trace gases that are expected to increase as more plastic is produced and accumulated in the environment.

296 citations

Journal ArticleDOI
TL;DR: In this paper, a review on the processing, properties, functionalization, and potential applications of electrospun biopolymers is presented, including proteins, polysaccharides, and cellulose derivatives, pullulan, dextran, cyclodextrins.

222 citations

Journal ArticleDOI
TL;DR: Prepared chitosan was characterized by Fourier transforms infrared spectroscopy, X-ray powder diffraction, Scanning electron microscope and Thermogravimetric analysis and TGA results demonstrated the lower thermal stability of chitOSan.

196 citations

Journal ArticleDOI
TL;DR: In this article, the authors partially replace Pb2+ with Ca2+ in the CsPbI3 precursor, producing multiple benefits, such as more uniform films with larger grains and better contact at the interface between the perovskite and the hole transport layer.
Abstract: Cesium metal halides are potential light-harvesting materials for use in the top cells of multi-junction devices due to their suitable bandgaps and good thermal stabilities. In particular, CsPbI3 has a bandgap of 1.7 eV, which is suitable for perovskite/Si tandem cells. However, the desirable black phase for CsPbI3 is not stable because Cs is too small to support the PbI6 octahedra. Also, there is room for improvement in terms of cell performance. Herein, we partially replace Pb2+ with Ca2+ in the CsPbI3 precursor, producing multiple benefits. Firstly, more uniform films with larger grains are produced from CsPbI3 with Ca2+, due to the reduction in the size of the colloids in the precursor solution with Ca2+. This morphology improvement provides better contact at the interface between the perovskite and the hole transport layer. In addition, it is found that the surface of the film is modified by the formation of a Ca rich oxide layer, providing a surface passivation effect. Finally, incorporation of Ca increases the band gap, leading to an increase in output voltage. The best CsPbI3 solar cell using 5% Ca2+ substitution in the precursor achieves a stabilised efficiency of 13.3%, and maintains 85% of its initial efficiency for over 2 months with encapsulation.

186 citations

Journal ArticleDOI
TL;DR: In this review, the most recent developments of PHB-based toughening materials are discussed with respect to their approaches and strategies, which includes: drawing and thermal treatment, blending with materials from natural sources and synthetic polymers, as well as forming reinforced composites with natural fibers and inorganic fillers.

179 citations

References
More filters
Journal ArticleDOI
TL;DR: From a technical point of view, these bio-based composites will enhance mechanical strength and acoustic performance, reduce material weight and fuel consumption, lower production cost, improve passenger safety and shatterproof performance under extreme temperature changes, and improve biodegradability for the auto interior parts.

844 citations

Journal ArticleDOI
TL;DR: In this paper, a review of recent approaches for making intumescent systems is described and commented on, and synergistic aspects using zeolites and organoclays are also considered and discussed new strategies are examined on the basis of the intumescence.
Abstract: Summary: This paper reviews recent approaches for making intumescent systems The mechanisms of action involving intumescence are described and commented on Synergistic aspects using zeolites and organoclays are also considered and discussed New strategies are examined on the basis of the mechanism of intumescence The approach of using char forming polymers as additives (blend technology) is also fully discussed This consists of substituting classical polyols (char forming agents) with char forming polymers (polyamides and thermoplastic polyurethane) It will be shown that the advantages of this concept are to obtain flame-retarded (FR) polymer blends with improved mechanical properties in comparison with polymers loaded with classical formulations, and the avoidance of problems due to the water solubility of the polyols and their migration The “nanocomposite approach” enhances the performance of intumescent systems by using a nanostructured char forming polymer It will be shown that this combination of intumescence via the blending approach and nanocomposites enhances both flame retardancy and mechanical properties, and allows many specifications to be produced (for example, the design of EVA-based materials for flame retarded low voltage cables and wire) This appears to be one of the most promising ways for designing new efficient intumescent materials Intumescent residue after LOI test of an intumescent poly(propylene)

635 citations

Journal ArticleDOI
TL;DR: In this paper, the manifold effects of expanded graphite (EG) on PLA molecular, thermo-mechanical and fire-retardant properties were evaluated using different techniques of addition.

257 citations

Journal ArticleDOI
TL;DR: In this article, the flammability of polypropylene (PP) composites containing intumescent flame retardant additives, i.e., melamine phosphate (MP) and pentaerythritol (PER), dipentaerythrin (DPER) or tripentaerythsrin (TPER), was characterized by limiting oxygen index (LOI), UL 94 and the cone calorimeter, and the thermal degradation of the composites was studied using thermogravimetric analysis (TG) and real-time Fourier transform infrared (RTFTIR).

243 citations

Journal ArticleDOI
TL;DR: In this article, the authors used oxygen index and cone calorimeter tests to characterize the fire performance of wood flour-polyethylene composites, and compared the results with unfilled polyethylene and solid wood.

220 citations