Journal ArticleDOI
Efficient catalytic asymmetric alkylations. 1. Enantioselective synthesis of (+)-indacrinone via chiral phase-transfer catalysis
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This article is published in Journal of the American Chemical Society.The article was published on 1984-01-01. It has received 376 citations till now. The article focuses on the topics: Indacrinone & Enantioselective synthesis.read more
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Small-molecule H-bond donors in asymmetric catalysis.
Journal ArticleDOI
The advent and development of organocatalysis
TL;DR: My opinion on why the field of organocatalysis has blossomed so dramatically over the past decade is presented.
Journal ArticleDOI
Asymmetric catalysis by chiral hydrogen-bond donors.
Mark S. Taylor,Eric N. Jacobsen +1 more
TL;DR: This review documents the structural and mechanistic features that contribute to high enantioselectivity in hydrogen-bond-mediated catalytic processes in small-molecule, synthetic catalyst systems.
Journal ArticleDOI
Enantioselective Michael Reaction of Malonates to Nitroolefins Catalyzed by Bifunctional Organocatalysts
TL;DR: Michael reaction of malonates to nitrooleolefins with chiral bifunctional organocatalysts, bearing both a thiourea and tertiary amino group, afforded Michael adducts with high yields and enantioselectivities.
Journal ArticleDOI
Privileged Chiral Catalysts
Tehshik P. Yoon,Eric N. Jacobsen +1 more
TL;DR: Drawing inspiration from natural catalysts, chemists have developed a variety of synthetic small-molecule catalysts that can achieve levels of selectivity approaching, and in some cases matching, those observed in enzymatic reactions.
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