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Efficient charge injection from a high work function metal in high mobility n-type polymer field-effect transistors

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TLDR
In this article, the authors demonstrate efficient electron injection from a high work function metal in staggered transistors based on the high mobility poly{[N,N′-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis (dicarboximide)-2,6-diyl]-alt-5,5′-(2,2′-bithiophene)}.
Abstract
We demonstrate efficient electron injection from a high work function metal in staggered transistors based on the high mobility poly{[N,N′-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5′-(2,2′-bithiophene)}. Channel length scaling shows that the linear mobility for electrons remains higher than 0.1 cm2/V s when reducing the channel length to a few micrometers. Field-enhanced injection favors downscaling at a fixed lateral voltage and reduces the contact resistance to 11 kΩ cm at high gate voltages for channels of only a few micrometers. The contacts are asymmetric, with the source contribution dominating the overall resistance, consistent with an injection limited regime rather than bulk-limited as generally found in staggered transistors.

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Citations
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Journal ArticleDOI

High‐Performance Ambipolar Diketopyrrolopyrrole‐Thieno[3,2‐b]thiophene Copolymer Field‐Effect Transistors with Balanced Hole and Electron Mobilities

TL;DR: High-performance ambipolar OFETs with balanced hole and electron field-effect mobilities both exceeding 1 cm(2) V (-1) s(-1) are achieved based on a single-solution-processed conjugated polymer, DPPT-TT, upon careful optimization of the device architecture, charge injection, and polymer processing.
Journal ArticleDOI

Toward printed integrated circuits based on unipolar or ambipolar polymer semiconductors.

TL;DR: Recently unprecedented values of μ ∼ 10 cm(2) /Vs have been achieved with solution-processed polymer based OFETs, a value competing with mobilities reported in organic single-crystals and exceeding the performances enabled by amorphous silicon.
Journal ArticleDOI

Charge injection in solution-processed organic field-effect transistors: physics, models and characterization methods.

TL;DR: A comprehensive overview on the subject of current injection in organic thin film transistors is offered: physical principles concerning energy level (mis)alignment at interfaces, models describing charge injection, technologies for interface tuning, and techniques for characterizing devices.
Journal ArticleDOI

Aggregation in a high-mobility n-type low-bandgap copolymer with implications on semicrystalline morphology.

TL;DR: It is concluded that film formation is mainly governed by the chain collapse, leading in general to a high aggregate content of ~45% and inhibits the formation of amorphous and disordered P(NDI2OD-T2) films.
References
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Journal ArticleDOI

A high-mobility electron-transporting polymer for printed transistors

TL;DR: A highly soluble and printable n-channel polymer exhibiting unprecedented OTFT characteristics under ambient conditions in combination with Au contacts and various polymeric dielectrics is reported and all-printed polymeric complementary inverters have been demonstrated.
Journal ArticleDOI

Energy‐Level Alignment at Organic/Metal and Organic/Organic Interfaces

TL;DR: A review of recent work on modeling of organic/metal and organic/organic interfaces can be found in this article, where the strength of the interaction at the interface has been used as the main factor.
Journal ArticleDOI

Introduction to Organic Thin Film Transistors and Design of n-Channel Organic Semiconductors

TL;DR: The development of air-stable n-channel organic semiconductors with improved performance in organic thin film transistors (OTFTs) is a major challenge for materials chemists as discussed by the authors.
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