Journal ArticleDOI
Efficient CuCl-Catalyzed Selective and Direct Oxidation of β- and γ-Substituted Aliphatic Primary Alcohols to Carboxylic Acids
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TLDR
In this article, a new procedure for the selective and direct oxidation of aliphatic primary alcohols having substitution at β-and γ-positions to corresponding carboxylic acids was developed using a catalytic amount of ligand and additive-free CuCl with anhydrous tBuOOH in acetonitrile solvent under very mild reaction conditions.About:
This article is published in Synthetic Communications.The article was published on 2010-08-25. It has received 4 citations till now. The article focuses on the topics: Alcohol oxidation & Catalysis.read more
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Journal ArticleDOI
Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation with peroxides.
Marina S. Dronova,Marina S. Dronova,Alexey N. Bilyachenko,Alexey I. Yalymov,Yuriy N. Kozlov,Lidia S. Shul’pina,Alexander A. Korlyukov,Dmitry E. Arkhipov,Mikhail M. Levitsky,Elena S. Shubina,Georgiy B. Shul'pin +10 more
TL;DR: It has been found that the reaction of benzene with H2O2 in acetonitrile solution at 50 °C catalyzed by 1 requires addition of trifluoroacetic acid (TFA) in low concentration and gives phenol with a turnover number (TON) of 250 after 3 h.
Journal ArticleDOI
MOF‐Stabilized Perfluorinated Palladium Cages Catalyze the Additive‐Free Aerobic Oxidation of Aliphatic Alcohols to Acids
TL;DR: In this paper , the synthesis of fluorinated pyridine-Pd2+ coordinate cages within the channels of an anionic tridimensional metal-organic framework (MOF) was shown.
Reference EntryDOI
Formation of Nitriles, Carboxylic Acids, and Derivatives by Oxidation, Substitution, and Addition
Richard C. Larock,Tuanli Yao +1 more
TL;DR: Aldehydes and Derivatives, Hemiacetals, and Lactols as mentioned in this paper, and Carboxylic Acids, were used for the purpose of substitution and addition.
Journal ArticleDOI
Efficient CuCl-Catalyzed Selective and Direct Oxidation of β- and γ-Substituted Aliphatic Primary Alcohols to Carboxylic Acids.
TL;DR: In this paper, the first report of a ligand and additive-free copper-catalyzed direct and selective oxidation of unactivated substituted aliphatic primary alcohols to carboxylic acids is presented.
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Tetrapropylammonium Perruthenate, Pr4N+RuO4-, TPAP: A Catalytic Oxidant for Organic Synthesis
TL;DR: In this paper, a review of the oxidations of a wide range of molecules with tetrapropylammonium perruthenate including examples of both double oxidations and selective oxidations is presented.
Journal ArticleDOI
Useful procedures for the oxidation of alcohols involving pyridinium dichromate in aprotic media
E. J. Corey,Greg Schmidt +1 more
Journal ArticleDOI
13. Researches on acetylenic compounds. Part I. The preparation of acetylenic ketones by oxidation of acetylenic carbinols and glycols
BookDOI
Catalytic oxidations with hydrogen peroxide as oxidant
TL;DR: The use of Polyoxometalates in Reactions with Hydrogen Peroxide has been investigated in this paper, where the use of polyoxometals in reaction with hydrogen peroxide is discussed.
Journal ArticleDOI
Selective oxidation of aldehydes to carboxylic acids with sodium chlorite-hydrogen peroxide
TL;DR: In this article, the authors propose a method for the Oxydation de cinnamaldehydes, benzaldehyde, furfural, pyridine carbaldehyde-4, thiophene carbaldehyde, 2 pyrrolecarbaldehyde-2, alcenals, dans l'acetonitrile et dans different solvants alcooliques.