Journal ArticleDOI
Efficient palladium catalysts for the copolymerization of carbon monoxide with olefins to produce perfectly alternating polyketones
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In this paper, a homogeneous palladium catalyst system was developed for the production of perfectly alternating copolymers of carbon monoxide with ethylene, where C 3 units randomly replace ethylene units along the chain.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1991-10-01. It has received 464 citations till now. The article focuses on the topics: Palladium & Propene.read more
Citations
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Journal ArticleDOI
Palladium-Catalyzed Alternating Copolymerization of Alkenes and Carbon Monoxide.
Eite Drent,Peter H. M. Budzelaar +1 more
Journal ArticleDOI
Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
TL;DR: The history of “ligand effects” in catalysis, a range of reactions for which a notable effect has been observed, and some of the established examples of bite angle effects involve diphosphine ligands.
Journal ArticleDOI
Theoretical studies on reactions of transition-metal complexes.
Shuqiang Niu,Michael B. Hall +1 more
Journal ArticleDOI
Progress in hydroformylation and carbonylation
TL;DR: The last 15 years of hydroformylation and carbonylation chemistry are reviewed in this article, including technical and commercial aspects, and the authors present a review of the most relevant papers.
Journal ArticleDOI
Multinuclear olefin polymerization catalysts
References
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Book
Principles and applications of organotransition metal chemistry
TL;DR: A perspective survey of organotransition metal complexes according to ligand substitution processes can be found in this paper, with a focus on transition metal complexes with metal carbon-bonded ligands.
Journal ArticleDOI
Crystal and molecular structures of dichloro[bis(diphenylphosphino)methane]palladium(II), dichloro[bis(diphenylphosphino)ethane]palladium(II), and dichloro[1,3-bis(diphenylphosphino)propane]palladium(II)
W. L. Steffen,Gus J. Palenik +1 more
Journal ArticleDOI
Novel palladium(II)-catalyzed copolymerization of carbon monoxide with olefins
Ayusman Sen,Ta Wang Lai +1 more
TL;DR: In this article, the catalytic capacity of the (Pd(CH/sub 3/CN)/sub 4/)(BF/ sub 4/)/sub 2/n-triphenylphosphine n = (1-3) was demonstrated for copolymerization of CO with ethylene and other alkenes under very mild conditions.
Journal ArticleDOI
Palladium(II)-catalyzed copolymerization of carbon monoxide with ethylene: direct evidence for a single mode of chain growth
Ta Wang Lai,Ayusman Sen +1 more
TL;DR: Une serie de complexes cationiques de palladium (II) catalyse la copolymerisation de CO and C 2 H 4 dans des conditions inhabituellement douces (25°C and pression totale de 300 psi) as discussed by the authors.
Journal ArticleDOI
Insertion of olefins into palladium(II)-acyl bonds. Mechanistic and structural studies
TL;DR: The reaction of norbornylene with (Pd(PPh{sub 3}){sub 2}(CH{sub 7}H{sub 10}COR))(BF{sub 4}) (3) produces (PpPh{ sub 3}):
Related Papers (5)
Palladium-Catalyzed Alternating Copolymerization of Alkenes and Carbon Monoxide.
Eite Drent,Peter H. M. Budzelaar +1 more
Mechanistic aspects of metal-catalyzed alternating copolymerization of olefins with carbon monoxide
Novel palladium(II)-catalyzed copolymerization of carbon monoxide with olefins
Ayusman Sen,Ta Wang Lai +1 more