Electrical Energy Storage for the Grid: A Battery of Choices
18 Nov 2011-Science (American Association for the Advancement of Science)-Vol. 334, Iss: 6058, pp 928-935
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Abstract: The increasing interest in energy storage for the grid can be attributed to multiple factors, including the capital costs of managing peak demands, the investments needed for grid reliability, and the integration of renewable energy sources. Although existing energy storage is dominated by pumped hydroelectric, there is the recognition that battery systems can offer a number of high-value opportunities, provided that lower costs can be obtained. The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
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TL;DR: In this paper, the first electrochemical and rheological characterization of MXene-based suspension electrodes, using multilayer Ti3C2Tx as the active material and carbon black (CB) as the conductive additive in symmetric and asymmetric EFC devices, was reported.
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TL;DR: In this article , during galvanostatic cycling structural changes of the environment of sodium/sodium ions are investigated by applying 23Na in-situ solid-state NMR.
Abstract: Polymer-derived silicon carbonitride ceramic (SiCN) is used as an electrode material to prepare cylindrical sodium/sodium ion cells for solid-state NMR investigations. During galvanostatic cycling structural changes of the environment of sodium/sodium ions are investigated by applying 23Na in-situ solid-state NMR. Changes of the signals assigned to sodium metal, intercalated sodium cation and sodium cation originating from the electrolyte are monitored as well as the occurrence of an additional signal in the region of metallic sodium. The intensity of this additional signal changes periodically with the cycling process indicating the reversibility of structures formed and deformed during the galvanostatic cycling. To identify interactions of sodium/sodium ions with the SiCN electrode materials, the cycled SiCN material is studied by 23Na ex-situ MAS NMR at high spinning rates of 20 and 50 kHz to obtain appropriate spectral resolution.
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TL;DR: In this article , the electronic structure of homogeneous carbon nitride monolayers (CxN3, x=10,19) was explored to understand its suitability as electrode material for rechargeable Li-ion batteries.
Abstract: In present day Li-ion batteries (LIBs) is the most successful and widely used rechargeable batteries. The continuous effort is going on in finding suitable electrode material for LIBs for improved performance in terms of life-time, storage capacity etc. Computational chemistry plays an important role in identifying suitable electrode materials through electronic structure calculation. By employing state of the art density functional theory we herein explored the electronic structure of homogeneous holey carbon nitride monolayers (CxN3, x=10,19) to understand its suitability as electrode material for rechargeable LIB. The monolayers have shown high negative adsorption energy for Li adsorption and more interestingly the band structure of monolayers reveal Dirac semimetallic character thus would exhibit high electronic conductivity. Meanwhile, monolithiation introduces metallicity in these monolayers. The calculated average open circuit voltages of the monolayers lie in the range of 0.45 to 0.09 V, which are typically observed in high performance anode materials. Moreover, these monolayers achieve ultrahigh theoretical specific capacity upto 2092.01 mAh/g and low diffusion barrier from 0.004 to 0.44 eV. Based on our computational study we suggest that, the CxN3 monolayers could be a promising anode material in search of low-cost and high performance LIBs.
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TL;DR: In this article, a mathematical model of the discharge process of an alkaline zinc-cobalt battery for design optimization is established based on the single-domain method, which couples the species transport in the porous electrodes with the electrochemical reactions.
Abstract: Zinc-cobalt batteries with cobalt oxide (Co3O4) as the positive electrode material are promising energy storage devices, due to their safety, remarkable energy densities, and good cycle stability. To understand the discharge characteristics of an alkaline zinc-cobalt battery for design optimization, a mathematical model of the discharge process is established based on the single-domain method, which couples the species transport in the porous electrodes with the electrochemical reactions. After model validation, the effects of different design parameters on the discharge performance of zinc-cobalt batteries are investigated, and the design strategies for the battery are proposed. It is found that a thin cathode with a large porosity can lead to a high specific capacity, and a low loading with a large electroactive area is beneficial for a high discharge voltage. The separator thickness has little effect on the discharge performance of the battery. Using the electrolyte with a high concentration is favorable for the improvement of the output voltage. The results obtained from this work can provide useful guidance for improving the discharge performance of aqueous zinc-cobalt batteries.
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TL;DR: In this paper, the authors consider the problem of dynamic programming when supremum terms appear in the objective function and show that the supremum is a special case of the class of forward separable objective functions.
Abstract: In this paper, we consider the problem of dynamic programming when supremum terms appear in the objective function. Such terms can represent overhead costs associated with the underlying state variables. Specifically, this form of optimization problem can be used to represent optimal scheduling of batteries such as the Tesla Powerwall for electrical consumers subject to demand charges - a charge based on the maximum rate of electricity consumption. These demand charges reflect the cost to the utility of building and maintaining generating capacity. Unfortunately, we show that dynamic programming problems with supremum terms do not satisfy the principle of optimality. However, we also show that the supremum is a special case of the class of forward separable objective functions. To solve the dynamic programming problem, we propose a general class of optimization problems with forward separable objectives. We then show that for any problem in this class, there exists an augmented-state dynamic programming problem which satisfies the principle of optimality and the solutions to which yield solutions to the original forward separable problem. We further generalize this approach to stochastic dynamic programming problems and apply the results to the problem of optimal battery scheduling with demand charges using a databased stochastic model for electricity usage and solar generation by the consumer.
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TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Abstract: Electrochemical capacitors, also called supercapacitors, store energy using either ion adsorption (electrochemical double layer capacitors) or fast surface redox reactions (pseudo-capacitors). They can complement or replace batteries in electrical energy storage and harvesting applications, when high power delivery or uptake is needed. A notable improvement in performance has been achieved through recent advances in understanding charge storage mechanisms and the development of advanced nanostructured materials. The discovery that ion desolvation occurs in pores smaller than the solvated ions has led to higher capacitance for electrochemical double layer capacitors using carbon electrodes with subnanometre pores, and opened the door to designing high-energy density devices using a variety of electrolytes. Combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries. The use of carbon nanotubes has further advanced micro-electrochemical capacitors, enabling flexible and adaptable devices to be made. Mathematical modelling and simulation will be the key to success in designing tomorrow's high-energy and high-power devices.
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Abstract: The challenges for further development of Li rechargeable batteries for electric vehicles are reviewed. Most important is safety, which requires development of a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital (LUMO) and highest occupied molecular orbital (HOMO) or a constituent (or additive) that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery. A high Li-ion conductivity (σ Li > 10 ―4 S/cm) in the electrolyte and across the electrode/ electrolyte interface is needed for a power battery. Important also is an increase in the density of the stored energy, which is the product of the voltage and capacity of reversible Li insertion/extraction into/from the electrodes. It will be difficult to design a better anode than carbon, but carbon requires formation of an SEI layer, which involves an irreversible capacity loss. The design of a cathode composed of environmentally benign, low-cost materials that has its electrochemical potential μ C well-matched to the HOMO of the electrolyte and allows access to two Li atoms per transition-metal cation would increase the energy density, but it is a daunting challenge. Two redox couples can be accessed where the cation redox couples are "pinned" at the top of the O 2p bands, but to take advantage of this possibility, it must be realized in a framework structure that can accept more than one Li atom per transition-metal cation. Moreover, such a situation represents an intrinsic voltage limit of the cathode, and matching this limit to the HOMO of the electrolyte requires the ability to tune the intrinsic voltage limit. Finally, the chemical compatibility in the battery must allow a long service life.
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