Electron transition in dodekahedral crystal field-III 8-coordinated complexes of pentavalent rhenium
About: This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1969-11-01. It has received 4 citations till now. The article focuses on the topics: Rhenium & Crystal.
Citations
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TL;DR: The octahedral geometry of K3[ReO2(CN)4], ReO2en2]Cl.2H2O and [ReO 2py4]Cl 2H 2O with a trans OReO(CN)-O group is confirmed in this article.
4 citations
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TL;DR: In this paper, the dichroic properties of K3[ReO2(CN)4] have been analyzed and discussed on the basis of molecular geometry and the oriented molecular model.
References
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01 Jan 1964
TL;DR: Theoretical analysis of molecular vibrational and rotational spectra has been studied in this paper, with a focus on the Vibrational Origin of Group Frequencies (VIB).
Abstract: Vibrational and Rotational Spectra. IR Experimental Considerations. Molecular Symmetry. The Vibrational Origin of Group Frequencies. Methyl and Methylene Groups. Triple Bonds and Cumulated Double Bonds. Olefin Groups. Aromatic and Heteroaromatic Rings. Carbonyl Compounds. Ethers, Alcohols, and Phenols. Amines, C=N, and N=O Compounds. Compounds Conking Boron, Silicon, Phosphorus, Sulfur, or Halogen. Major Spectra-Structure Correlations by Spectral Regions. The Theoretical Analysis of Molecular Vibrations.
5,173 citations
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TL;DR: From the measurement of absorption spectra of crystals of biguanide complexes of copper chloride, -bromide and -fluoride, it has been concluded that the five fold degenerate d -orbitals of copper ion are split into four levels by the electrostatic field of the four ligand donor atoms in the plane of the molecule as discussed by the authors.
23 citations
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TL;DR: In this paper, the dodekahedral Dq values for three 8-coordinated molybdenum cyanides containing one, two or three d-electrons were observed in the visible region.
9 citations