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Journal ArticleDOI

‘Electronic Noses’ and Their Application to Food

TL;DR: A substantial increase in research into the application of electronic noses in the evaluation of volatile compounds in food, cosmetic, and other items of everyday life is observed as discussed by the authors, which involve various types of electronic chemical gas sensors with partial specificity, as well as suitable statistical methods enabling the recognition of complex odours.
Abstract: ‘Electronic nose’ systems involve various types of electronic chemical gas sensors with partial specificity, as well as suitable statistical methods enabling the recognition of complex odours. As commercial instruments have become available, a substantial increase in research into the application of electronic noses in the evaluation of volatile compounds in food, cosmetic and other items of everyday life is observed. At present, the commercial gas sensor technologies comprise metal oxide semiconductors, metal oxide semiconductor field effect transistors, organic conducting polymers, and piezoelectric crystal sensors. Further sensors based on fibreoptic, electrochemical and bi-metal principles are still in the developmental stage. Statistical analysis techniques range from simple graphical evaluation to multivariate analysis such as artificial neural network and radial basis function. The introduction of electronic noses into the area of food is envisaged for quality control, process monitoring, freshness evaluation, shelf-life investigation and authenticity assessment. Considerable work has already been carried out on meat, grains, coffee, mushrooms, cheese, sugar, fish, beer and other beverages, as well as on the odour quality evaluation of food packaging material.
Citations
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Journal ArticleDOI
TL;DR: In this paper, the authors extensively review the development of semiconductor metal oxide gas sensors for environmentally hazardous gases including NO2, NO, N2O, H2S, CO, NH3, CH4, SO2 and CO2.
Abstract: This article extensively reviews the recent development of semiconductor metal oxide gas sensors for environmentally hazardous gases including NO2, NO, N2O, H2S, CO, NH3, CH4, SO2 and CO2. The gas sensing properties of differently-prepared metal oxides and loaded metal oxides towards nine environmentally hazardous gases have been individually compared and digested. Promising materials for sensitive and selective detection of each hazardous gas have been identified. For instance, unloaded WO3 nanostructures are the most promising candidates for NO2 sensing while metal catalyst loaded WO3 and gold-loaded SnO2 sensors are among the most effective for NO and N2O sensing, respectively. Moreover, related gas-sensing mechanisms are comprehensively discussed.

999 citations

Journal ArticleDOI
TL;DR: An overview of different physicochemical instrumental techniques for direct and indirect identification of bacteria such as: infrared and fluorescence spectroscopy, flow cytometry, chromatography and chemiluminescence techniques as a basis for biosensor construction is presented.

926 citations


Cites background from "‘Electronic Noses’ and Their Applic..."

  • ...Electronic nose systems comprise sophisticated hardware, with sensors, electronics, pumps, flow controllers, software, data pre-processing, statistical analysis (Schaller et al., 1998)....

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  • ...The ideal sensors to be integrated in an electronic nose should fulfil the following criteria (Schaller et al., 1998): high sensitivity (down to 10−12 g/ml), they must respond to different compounds present in the headspace of the sample; high stability and reproducibility; short recovery time;…...

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  • ...The electronic nose ‘Electronic nose’ systems have advanced rapidly during the past 10 years, the majority of applications being within the food and drink industry (Gardner and Bartlett, 1992; DiNatale et al., 1997; Kress-Rogers, 1997; Haugen and Kvaal, 1998; Schaller et al., 1998)....

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Journal ArticleDOI
29 Jun 2009-Sensors
TL;DR: This paper is a review of the major electronic-nose technologies developed since this specialized field was born and became prominent in the mid 1980s, and a summarization of some of the more important and useful applications that have been of greatest benefit to man.
Abstract: Electronic-nose devices have received considerable attention in the field of sensor technology during the past twenty years, largely due to the discovery of numerous applications derived from research in diverse fields of applied sciences. Recent applications of electronic nose technologies have come through advances in sensor design, material improvements, software innovations and progress in microcircuitry design and systems integration. The invention of many new e-nose sensor types and arrays, based on different detection principles and mechanisms, is closely correlated with the expansion of new applications. Electronic noses have provided a plethora of benefits to a variety of commercial industries, including the agricultural, biomedical, cosmetics, environmental, food, manufacturing, military, pharmaceutical, regulatory, and various scientific research fields. Advances have improved product attributes, uniformity, and consistency as a result of increases in quality control capabilities afforded by electronic-nose monitoring of all phases of industrial manufacturing processes. This paper is a review of the major electronic-nose technologies, developed since this specialized field was born and became prominent in the mid 1980s, and a summarization of some of the more important and useful applications that have been of greatest benefit to man.

887 citations


Cites background or methods from "‘Electronic Noses’ and Their Applic..."

  • ...Conductive polymer gas sensors consist of a substrate, usually silicon, a pair of gold-plated electrodes and a conducting organic polymer coating as the sensing element [72]....

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  • ...[72] provided a very good review of electronic-nose systems that have been used for various applications with different types of foods....

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  • ...They were first used commercially in the 1960s as household gas alarms in Japan [72]....

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  • ...Commercially available analysis techniques fall into three main categories as follows [72]: 1....

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  • ...They used a polypyrrole sensor array system for the detection of Serpula lacrymans, a wood destroying dry rot fungus responsible for millions of dollars of damage annually to buildings containing lumber or timbers in Northern and Central Europe, Australia, and Japan....

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Journal ArticleDOI
TL;DR: In this article, the authors reviewed the range of sensors used in electronic nose (e•nose) systems to date and outlined the operating principles and fabrication methods of each sensor type as well as the applications in which the different sensors have been used.
Abstract: This paper reviews the range of sensors used in electronic nose (e‐nose) systems to date. It outlines the operating principles and fabrication methods of each sensor type as well as the applications in which the different sensors have been utilised. It also outlines the advantages and disadvantages of each sensor for application in a cost‐effective low‐power handheld e‐nose system.

744 citations


Cites background or methods from "‘Electronic Noses’ and Their Applic..."

  • ...Coatings can be between 10 nm and 1mm and are applied using spincoating, airbrushing, inkjet printing or dip coating, (Schaller et al., 1998)....

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  • ...Gas sensing MOSFETs are produced by microfabrication, therefore reproducibility is quite good and the sensor can be incorporated into CMOS technology resulting in small, low cost sensors (Dickinson et al., 1998; Gu et al., 1998; Nagle et al., 1998; Pearce et al., 2003; Schaller et al., 1998; )....

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  • ...The grain size of the oxide also affects the sensitivity and selectivity to particular gases as the grain boundaries act as scattering centres for the electrons (Schaller et al., 1998)....

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  • ...The factors that affect the sensitivity of FET-based devices are operating temperature, composition and structure of the catalytic metal (Lundstrom et al., 1995; Schaller et al., 1998)....

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  • ...However, SAW devices suffer from poor signal to noise performance because of the high frequencies at which they operate, (Schaller et al., 1998) and the circuitry required to operate them is complex and expensive (Pearce et al., 2003)....

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Journal ArticleDOI
TL;DR: Some of the most common chemical and vapor-deposition methods for the synthesis of semiconductor metal oxide based detectors for chemical gas sensors are presented and a direct comparison of structural and chemical properties with sensing performance is given.
Abstract: Since the development of the first chemoresistive metal oxide based gas sensors, transducers with innovative properties have been prepared by a variety of wet- and dry-deposition methods. Among these, direct assembly of nanostructured films from the gas phase promises simple fabrication and control and with the appropriate synthesis and deposition methods nm to μm thick films, can be prepared. Dense structures are achieved by tuning chemical or vapor deposition methods whereas particulate films are obtained by deposition of airborne, mono- or polydisperse, aggregated or agglomerated nanoparticles. Innovative materials in non-equilibrium or sub-stoichiometric states are captured by rapid cooling during their synthesis. This Review presents some of the most common chemical and vapor-deposition methods for the synthesis of semiconductor metal oxide based detectors for chemical gas sensors. In addition, the synthesis of highly porous films by novel aerosol methods is discussed. A direct comparison of structural and chemical properties with sensing performance is given.

464 citations

References
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Journal ArticleDOI
23 Sep 1982-Nature
TL;DR: An electronic nose constructed using semiconductor transducers and incorporating design features suggested by the proposal can reproducibly discriminate between a wide variety of odours, and its properties show that discrimination in an olfactory system could be achieved without the use of highly specific receptors.
Abstract: Olfaction exhibits both high sensitivity for odours and high discrimination between them. We suggest that to make fine discriminations between complex odorant mixtures containing varying ratios of odorants without the necessity for highly specialized peripheral receptors, the olfactory systems makes use of feature detection using broadly tuned receptor cells organized in a convergent neurone pathway. As a test of this hypothesis we have constructed an electronic nose using semiconductor transducers and incorporating design features suggested by our proposal. We report here that this device can reproducibly discriminate between a wide variety of odours, and its properties show that discrimination in an olfactory system could be achieved without the use of highly specific receptors.

1,309 citations

Journal ArticleDOI
TL;DR: The human nose is still the primary instrument used to assess the smell or flavour of various industrial products today, despite considerable and sustained attempts to develop new electronic instrumentation capable of mimicking its remarkable ability as discussed by the authors.
Abstract: The human nose is still the primaryinstrument' used to assess the smell or flavour of various industrial products today, despite considerable and sustained attempts to develop new electronic instrumentation capable of mimicking its remarkable ability In this paper we review the research effort that has been carried out over the past 25 years or so to create an electronic nose Indoing so, we first provide a definition for the term electronic nose, and then discuss some of the technologies that have been explored in what is essentially an intelligent chemical array sensor systemwe summarize the applications of electronic noses to date and suggest where future applications may lie

1,079 citations

Journal ArticleDOI

734 citations

Journal ArticleDOI
TL;DR: In this paper, an MOS transistor with 10−nm silicon dioxide as gate insulator and 10 −nm palladium as gate electrode was fabricated and the threshold voltage of this transistor was found to be a function of the partial pressure of hydrogen in the ambient atmosphere.
Abstract: An MOS transistor in silicon with 10−nm silicon dioxide as gate insulator and 10−nm palladium as gate electrode was fabricated. The threshold voltage of this transistor was found to be a function of the partial pressure of hydrogen in the ambient atmosphere. At a device temperature of 150 °C it was possible to detect 40 ppm hydrogen gas in air with response times less than 2 min.

707 citations