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Engineering Carbon Materials from the Hydrothermal Carbonization Process of Biomass

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TLDR
It will be demonstrated that the HTC process can rationally design a rich family of carbonaceous and hybrid functional carbon materials with important applications in a sustainable fashion.
Abstract
Energy shortage, environmental crisis, and developing customer demands have driven people to find facile, low-cost, environmentally friendly, and nontoxic routes to produce novel functional materials that can be commercialized in the near future. Amongst various techniques, the hydrothermal carbonization (HTC) process of biomass (either of isolated carbohydrates or crude plants) is a promising candidate for the synthesis of novel carbon-based materials with a wide variety of potential applications. In this Review, we will discuss various synthetic routes towards such novel carbon-based materials or composites via the HTC process of biomass. Furthermore, factors that influence the carbonization process will be analyzed and the special chemical/physical properties of the final products will be discussed. Despite the lack of a clear mechanism, these novel carbonaceous materials have already shown promising applications in many fields such as carbon fixation, water purification, fuel cell catalysis, energy storage, CO(2) sequestration, bioimaging, drug delivery, and gas sensors. Some of the most promising examples will also be discussed here, demonstrating that the HTC process can rationally design a rich family of carbonaceous and hybrid functional carbon materials with important applications in a sustainable fashion.

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Journal ArticleDOI

Carbon quantum dots: synthesis, properties and applications

TL;DR: Carbon quantum dots (CQDs, C-dots or CDs) have found wide use in more and more fields during the last few years as discussed by the authors, focusing on their synthetic methods, size control, modification strategies, photoelectric properties, luminescent mechanism, and applications in biomedicine, optronics, catalysis and sensor issues.
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Synthesis of Nitrogen-Doped Porous Carbon Nanofibers as an Efficient Electrode Material for Supercapacitors

TL;DR: This work presents a high-capacity supercapacitor material based on the nitrogen-doped porous carbon nan ofibers synthesized by carbonization of macroscopic-scale carbonaceous nanofibers coated with polypyrrole (CNFs@polypyr role) at an appropriate temperature.
Journal ArticleDOI

Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications

TL;DR: In this paper, a state-of-the-art update on the most recent developments concerning the advanced heteroatom doping of carbon that goes beyond nitrogen is given, with respect to their boron-, sulphur-and phosphorus-doping.
References
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Journal ArticleDOI

Helical microtubules of graphitic carbon

Sumio Iijima
- 01 Nov 1991 - 
TL;DR: Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.
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C 60 : Buckminsterfullerene

TL;DR: In this article, the authors proposed a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal.
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Colloidal carbon spheres and their core/shell structures with noble-metal nanoparticles.

TL;DR: Only amorphous silica and some colloidal polymer spheres can be routinely prepared with satisfactorily narrow size distributions, and surface modification almost unavoidable before use as supports or templates.
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Monodispersed Colloidal Spheres: Old Materials with New Applications

TL;DR: An overview of current research activities that center on monodispersed colloidal spheres whose diameter falls anywhere in the range of 10 nm to 1 μm can be found in this paper.
Journal ArticleDOI

Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies

TL;DR: Several biomass hydrothermal conversion processes are in development or demonstration as mentioned in this paper, which are generally lower temperature (200-400 °C) reactions which produce liquid products, often called bio-oil or bio-crude.
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