Enhanced Electromagnetic Interference Shielding in a Au–MWCNT Composite Nanostructure Dispersed PVDF Thin Films
20 Jun 2016-Journal of Physical Chemistry C (American Chemical Society)-Vol. 120, Iss: 25, pp 13771-13778
TL;DR: In this article, a flexible conducting polymer composite film, prepared via a simple solvent cast method, of PVDF incorporated with Au-MWCNT, was studied and the scanning electron microscopic analysis showed that the Au-loaded MWCNT uniformly dispersed in PVDF.
Abstract: Electromagnetic interference (EMI) shielding effectiveness and conductivities in a flexible conducting polymer composite film, prepared via a simple solvent cast method, of PVDF incorporated with Au–MWCNT are studied. The scanning electron microscopic analysis showed that the Au-loaded MWCNT uniformly dispersed in PVDF. The HRTEM images show that Au nanoparticles having a particle size of 20–30 nm have been deposited on the nodes of the MWCNT. The values of dielectric constant were found to be 12.11 and 13.89 at 1 MHz upon the incorporation of 1 and 3 wt % MWCNT in PVDF. The impedance and electromagnetic interference shielding effectiveness studies reveal that the polymer nanocomposites possess enhanced conductivity of 1.12 × 10–4 S/cm at 1 MHz, minimum return loss of 4.4 dB, and effective electromagnetic shielding of 26.7 dB at 12 GHz for 3 wt % Au NPs in 3 wt % MWCNT/PVDF thin film.
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TL;DR: Mechanism analysis reveals that the excellent EM wave absorption and shielding performances of the hybrid are contributed to the synergistic effect of conductive MXene and magnetic Ni chains, by which, the dielectric properties and electromagnetic loss can be easily controlled to obtain appropriate impedance matching conditions and good EM wave dissipation ability.
Abstract: Electromagnetic (EM) pollution affecting people's normal lives and health has attracted considerable attention in the current society. In this work, a promising EM wave absorption and shielding material, MXene/Ni hybrid, composed of one-dimensional Ni nanochains and two-dimensional Ti3C2Tx nanosheets (MXene), is successfully designed and developed. As expected, excellent EM wave absorption and shielding properties are obtained and controlled by only adjusting the MXene content in the hybrid. A minimum reflection loss of -49.9 dB is obtained only with a thickness of 1.75 mm at 11.9 GHz when the MXene content is 10 wt %. Upon further increasing the MXene content to 50 wt %, the optimal EM shielding effectiveness (SE) reaches 66.4 dB with an absorption effectiveness (SEA) of 59.9 dB. Mechanism analysis reveals that the excellent EM wave absorption and shielding performances of the hybrid are contributed to the synergistic effect of conductive MXene and magnetic Ni chains, by which, the dielectric properties and electromagnetic loss can be easily controlled to obtain appropriate impedance matching conditions and good EM wave dissipation ability. This work provides a simple but effective route to develop MXene-based EM wave absorption and shielding materials. A universal guideline for designing the absorbing and shielding materials for the future is also proposed.
292 citations
TL;DR: This study provides the groundwork for an effective way to design flexible, ultrathin conductive polymer composite film for application in miniaturized electronic devices.
Abstract: In this study, we fabricated conductive poly(vinylidene fluoride) (PVDF)/carbon composites simply by dispersing multiwalled carbon nanotubes (MWCNTs) and graphene nanoplatelets into a PVDF solution The electrical conductivity and the electromagnetic interference (EMI) shielding of the PVDF/carbon composites were increased by increasing the conductive carbon filler amounts Moreover, we also found that the EMI shielding properties of the PVDF/CNT/graphene composites were higher than those of PVDF/CNT and PVDF/graphene composites The mean EMI shielding values of PVDF/5 wt %-CNT, PVDF/10 wt %-graphene, and PVDF/CNT/graphene composite films with a thickness of 01 mm were 2241, 1870, and 2758 dB, respectively An analysis of the shielding mechanism showed that the main contribution to the EMI shielding came from the absorption mechanism, and that the EMI shielding could be tuned by controlling the films’ thickness The total shielding of the PVDF/CNT/graphene films increased from 2190 to 3646 dB as the
254 citations
TL;DR: One-dimensional ANFs were designed as the intermolecular cross-linker between d-Ti3C2Tx flakes and MXene and exhibited excellent mechanical properties and superior electrical conductivity and showed potential application prospects as an advanced composite in sensitive electronic products.
Abstract: MXenes, new two-dimensional compounds with hydrophilic surfaces and high metallic conductivity, have attracted significant interest in the electromagnetic interference shielding field in recent years. Nevertheless, poor mechanical properties and brittle nature are bottlenecks for their commercial application. Herein, one-dimensional ANFs were designed as the intermolecular cross-linker between d-Ti3C2Tx flakes and MXene (d-Ti3C2Tx)/aramid nanofiber (ANF) composite paper with a multi-layered structure was fabricated via the vacuum-assisted filtration approach. Further investigation revealed that the ANFs and MXene displayed good combination by hydrogen bonding, and MXene/ANF composite papers exhibited excellent mechanical properties and superior electrical conductivity. The MXene/ANF composite paper possessed a favorable shielding effectiveness (SE) which reached ∼28 dB in 8.2-12.4 GHz (X band) with an ultra-thin thickness ∼17 μm and showed potential application prospects as an advanced composite in sensitive electronic products.
168 citations
TL;DR: Soft conducting composites designed with doped multiwalled carbon nanotubes and a three-dimensional cross-linked graphene oxide (GO) framework doped with ferrite nanoparticles produce a very high electromagnetic shielding efficiency (SE) of -37 dB at 18 GHz, dominated by absorption-driven shielding.
Abstract: To minimize electromagnetic (EM) pollution, two key parameters, namely, intrinsic wave impedance matching and intense absorption of incoming EM radiation, must satisfy the utmost requirements. To target these requirements, soft conducting composites consisting of binary blends of polycarbonate (PC) and poly(vinylidene fluoride) (PVDF) were designed with doped multiwalled carbon nanotubes (MWCNTs) and a three-dimensional cross-linked graphene oxide (GO) framework doped with ferrite nanoparticles. The doping of α-MnO2 onto the MWCNTs ensured intrinsic wave impedance matching in addition to providing conducting pathways, and the ferrite-doped cross-linked GO facilitated the enhanced attenuation of the incoming EM radiation. This unique combination of magnetodielectric coupling led to a very high electromagnetic shielding efficiency (SE) of −37 dB at 18 GHz, dominated by absorption-driven shielding. The promising results from the composites further motivated us to rationally stack individual composites into a...
167 citations
TL;DR: In this paper, a flexible polyvinylidene fluoride (PVDF) with various heterogeneous alternating multilayer structure (HAMS) containing high-aligned graphene nanosheets and Ni nanochains was designed for electromagnetic interference (EMI) shielding and heat dissipation applications.
122 citations
References
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TL;DR: Carbon materials for electromagnetic interference (EMI) shielding are reviewed in this article, including composite materials, colloidal graphite and flexible graphite, and they include carbon filaments of submicron diameter.
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TL;DR: In this article, the electromagnetic interference (EMI) shielding mechanisms of multi-walled carbon nanotube (MWCNT)/polymer composites were analyzed experimentally and theoretically.
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TL;DR: The electromagnetic interference (EMI) shielding effectiveness measurements indicated that a novel carbon nanotube-polystyrene foam composite can be used as very effective, lightweight shielding materials.
Abstract: A novel carbon nanotube-polystyrene foam composite has been fabricated successfully. The electromagnetic interference (EMI) shielding effectiveness measurements indicated that such foam composites can be used as very effective, lightweight shielding materials. The correlation between the shielding effectiveness and electrical conductivity and the EMI shielding mechanism of such foam composites are also discussed.
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TL;DR: The results indicate that single-walled carbon nanotube-polymer composites can be used as effective lightweight EMI shielding materials and are found to correlate with the dc conductivity.
Abstract: Single-walled carbon nanotube (SWNT)−polymer composites have been fabricated to evaluate the electromagnetic interference (EMI) shielding effectiveness (SE) of SWNTs. Our results indicate that SWNTs can be used as effective lightweight EMI shielding materials. Composites with greater than 20 dB shielding efficiency were obtained easily. EMI SE was tested in the frequency range of 10 MHz to 1.5 GHz, and the highest EMI shielding efficiency (SE) was obtained for 15 wt % SWNT, reaching 49 dB at 10 MHz and exhibiting 15−20 dB in the 500 MHz to 1.5 GHz range. The EMI SE was found to correlate with the dc conductivity, and this frequency range is found to be dominated by reflection. The effects of SWNT wall defects and aspect ratio on the EMI SE were also studied.
1,148 citations