Enhanced nonlinear optical responses of materials: Composite effects
TL;DR: In this paper, the authors review recent theoretical progress in understanding physical processes of composite effects on enhanced third-order nonlinear optical responses of various kinds of the recently proposed non-linear optical materials, namely, colloidal nanocrystals with inhomogeneous metallodielectric particles or a graded-index host, metallic films with inhmogeneous microstructures adjusted by ion doping or temperature gradient, composites with compositional gradation or graded particles.
About: This article is published in Physics Reports.The article was published on 2006-08-01 and is currently open access. It has received 188 citations till now. The article focuses on the topics: Ferrofluid.
Citations
More filters
TL;DR: In this paper, the authors exploit a class of shaped graded materials in which thermal energy is apparently controlled to transfer from a region of lower temperature to a higher temperature, which is indicative of an apparent negative thermal conductivity.
Abstract: Based on a first-principles approach, we exploit a class of shaped graded materials in which thermal energy is apparently controlled to transfer from a region of lower temperature to a region of higher temperature. This phenomenon, which is in contrast to our common intuition, is indicative of an apparent negative thermal conductivity (ANTC). Further analysis shows that the ANTC is related to a symmetric oscillation of paired thermal conductivities with specific gradation profiles, which are shown to satisfy a sum rule. Such shaped graded materials can serve as good candidates for thermal rectification.
432 citations
TL;DR: This work proposes a strategy for radiative camouflage of external objects on a given background using a structured thermal surface, independent of the background material for many practical situations, to meet the demands of anti-detection and thermal radiation manipulation in complex unknown environments.
Abstract: Thermal camouflage has been successful in the conductive regime, where thermal metamaterials embedded in a conductive system can manipulate heat conduction inside the bulk. Most reported approaches are background-dependent and not applicable to radiative heat emitted from the surface of the system. A coating with engineered emissivity is one option for radiative camouflage, but only when the background has uniform temperature. Here, we propose a strategy for radiative camouflage of external objects on a given background using a structured thermal surface. The device is non-invasive and restores arbitrary background temperature distributions on its top. For many practical candidates of the background material with similar emissivity as the device, the object can thereby be radiatively concealed without a priori knowledge of the host conductivity and temperature. We expect this strategy to meet the demands of anti-detection and thermal radiation manipulation in complex unknown environments and to inspire developments in phononic and photonic thermotronics.
193 citations
TL;DR: These findings liberate the excellent luminescence and nonlinear optical properties of perovskite QDs from the solution system to the solid single-crystal system, which provide a new avenue for the exploitation of high-performance multiphoton excited hybrid single microcrystal for future optoelectronic and micro-nano photonic integration applications.
Abstract: The development of the photostable higher-order multiphoton-excited (MPE) upconversion single microcrystalline material is fundamentally and technologically important, but very challenging. Here, up to five-photon excited luminescence in a host-guest metal-organic framework (MOF) and perovskite quantum dot (QD) hybrid single crystal ZJU-28⊃MAPbBr3 is shown via an in situ growth approach. Such a MOF strategy not only results in a high QD loading concentration, but also significantly diminishes the aggregation-caused quenching (ACQ) effect, provides effective surface passivation, and greatly reduces the contact of the QDs with the external bad atmosphere due to the confinement effect and protection of the framework. These advantages make the resulting ZJU-28⊃MAPbBr3 single crystals possess high PLQY of ≈51.1%, a high multiphoton action cross-sections that can rival the current highest record (measured in toluene solution), and excellent photostability. These findings liberate the excellent luminescence and nonlinear optical properties of perovskite QDs from the solution system to the solid single-crystal system, which provide a new avenue for the exploitation of high-performance multiphoton excited hybrid single microcrystal for future optoelectronic and micro-nano photonic integration applications.
105 citations
TL;DR: In this article, a subwavelength periodic layered medium whose slabs are filled by arbitrary linear metamaterials and standard nonlinear Kerr media is considered and it is shown that the homogenized medium behaves as a Kerr medium whose parameters can assume values not available in standard materials.
Abstract: We consider a subwavelength periodic layered medium whose slabs are filled by arbitrary linear metamaterials and standard nonlinear Kerr media and show that the homogenized medium behaves as a Kerr medium whose parameters can assume values not available in standard materials. Exploiting such a parameter availability, we focus on the situation where the linear relative dielectric permittivity is very small, thus allowing the observation of the extreme nonlinear regime where the nonlinear polarization is comparable with or even greater than the linear part of the overall dielectric response. The behavior of the electromagnetic field in the extreme nonlinear regime is very peculiar and characterized by interesting features such as the transverse power flow reversing. In order to probe this regime, we consider a class of fields (transverse magnetic nonlinear guided waves) admitting full analytical description and show that these waves are allowed to propagate even in media with $\ensuremath{\epsilon}l0$ and $\ensuremath{\mu}g0$ since the nonlinear polarization produces a positive overall effective permittivity. The considered nonlinear waves exhibit, in addition to the mentioned features, a number of interesting properties like hyperfocusing induced by the phase difference between the field components.
104 citations
TL;DR: It is numerically demonstrated that optical negative refraction in ferrofluids containing isotropic Fe3O4 nanoparticles, each having an isotropics Ag shell, in the presence of an external dc magnetic field H, arises from H-induced chains or columns.
Abstract: We numerically demonstrate optical negative refraction in ferrofluids containing isotropic ${\mathrm{Fe}}_{3}{\mathrm{O}}_{4}$ nanoparticles, each having an isotropic Ag shell, in the presence of an external dc magnetic field $H$. The all-angle broadband optical negative refraction with magnetocontrollability arises from $H$-induced chains or columns. They result in hyperbolic equifrequency contour for transverse magnetic waves propagating in the system. The finite element simulations verify the analyses using the effective medium approximation. Experimental demonstration and potential applications are suggested and discussed.
94 citations
References
More filters
Book•
01 Jan 1983
TL;DR: In this paper, a Potpourri of Particles is used to describe surface modes in small Particles and the Angular Dependence of Scattering is shown to be a function of the size of the particles.
Abstract: BASIC THEORY. Electromagnetic Theory. Absorption and Scattering by an Arbitrary Particle. Absorption and Scattering by a Sphere. Particles Small Compared with the Wavelength. Rayleigh--Gans Theory. Geometrical Optics. A Potpourri of Particles. OPTICAL PROPERTIES OF BULK MATTER. Classical Theories of Optical Constants. Measured Optical Properties. OPTICAL PROPERTIES OF PARTICLES. Extinction. Surface Modes in Small Particles. Angular Dependence of Scattering. A Miscellany of Applications. Appendices. References. Index.
16,859 citations
Book•
01 Jan 1960
TL;DR: In this article, the propagation of electromagnetic waves and X-ray diffraction of X rays in crystals are discussed. But they do not consider the effects of superconductivity on superconducting conductors.
Abstract: Electrostatics of conductors Static magnetic field Superconductivity The propagation of electromagnetic waves Spatial dispersion Diffraction of X rays in crystals.
12,543 citations
Book•
01 May 1984
TL;DR: In this article, the authors present a general description of wave propagation in nonlinear media, including high-resolution nonlinear optical spectroscopy, and four-wave mixing and mixing.
Abstract: Introduction. Nonlinear Optical Susceptibilities. General Description of Wave Propagation in Nonlinear Media. Electrooptical and Magnetooptical Effects. Optical Rectification and Optical Field-Induced Magnetization. Sum-Frequency Generation. Harmonic Generation. Difference Frequency Generation. Parametric Amplification and Oscillation. Stimulated Raman Scattering. Stimulated Light Scattering. Two-Photon Absorption. High-Resolution Nonlinear Optical Spectroscopy. Four-Wave Mixing. Four-Wave Mixing Spectroscopy. Optical-Field-Induced Birefringence. Self-Focusing. Multiphoton Spectroscopy. Detection of Rare Atoms and Molecules. Laser Manipulation of Particles. Transient Coherent Optical Effects. Strong Interaction of Light with Atoms. Infrared Multiphoton Excitation and Dissociation of Molecules. Laser Isotope Separation. Surface Nonlinear Optics. Nonlinear Optics in Optical Waveguides. Optical Breakdown. Nonlinear Optical Effects in Plasmas. Index.
5,311 citations
TL;DR: In this article, the authors established and applied variational theorems for the derivation of bounds for the effective magnetic permeability of macroscopically homogeneous and isotropic multiphase materials.
Abstract: Variational theorems are established and applied to the derivation of bounds for the effective magnetic permeability of macroscopically homogeneous and isotropic multiphase materials. For reasons of mathematical analogy the results are also valid for the dielectric constant, electric conductivity, heat conductivity, and diffusivity of such materials. For the case of two‐phase materials, the bounds derived are the most restrictive ones that can be given in terms of the phase permeabilities and volume fractions. Comparison of present theoretical results with existing experimental data shows good agreement.
2,887 citations