Journal ArticleDOI
Equilibrium Acidities in Dimethyl Sulfoxide Solution
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This article is published in ChemInform.The article was published on 1989-04-04. It has received 149 citations till now. The article focuses on the topics: Dimethyl sulfoxide.read more
Citations
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Stronger Brønsted Acids: Recent Progress.
Journal ArticleDOI
Thermodynamic Hydricity of Transition Metal Hydrides
Eric S. Wiedner,Matthew B. Chambers,Catherine L. Pitman,R. Morris Bullock,Alexander J. M. Miller,Aaron M. Appel +5 more
TL;DR: Methods for using hydricity values to predict chemical reactivity are discussed, including organic transformations, the reduction of CO2, and the production and oxidation of hydrogen.
Journal ArticleDOI
The Essential Role of Bond Energetics in C-H Activation/Functionalization.
TL;DR: The present review provides examples that applied the concept and values of C-H bond energy in rationalizing the observations associated with reactivity and/or selectivity in C- H activation/functionalization.
Journal ArticleDOI
N-heterocyclic carbene gold(I) and copper(I) complexes in C-H bond activation.
TL;DR: Recent discoveries involving the versatile NHC-gold(I) and N HC-copper(i) hydroxide complexes, led to new organometallic chemistry and catalysis involving C-H bond activation (metalation) and subsequent C-h bond functionalization, are discussed.
Journal ArticleDOI
Isomerization of allylbenzenes.
Mohammad Hassam,Abu Taher,Gareth E. Arnott,Ivan R. Green,Willem A. L. van Otterlo,Willem A. L. van Otterlo +5 more
TL;DR: The proposed Base-Mediated Reaction Mechanism answers the question of both the retention and the inversion of stereochemistry for the simple exchange reaction giving back I and leads to two “conformations” of the chiral alkene I that will lead to either the E or the Z allylic anions as shown.
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Journal ArticleDOI
Equilibrium Acidities in Dimethyl Sulfoxide Solution
TL;DR: The first acidity scale to be established in a pure solvent other than water was the result of the pioneering work of Conant, Wheland, and McEwen in ether or ben~ene.
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Structural and Solvent Effects Evaluated from Acidities Measured in Dimethyl Sulfoxide and in the Gas Phase
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