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Journal ArticleDOI

Evidence for double diffusion in temperate meromictic lakes

TL;DR: In this article, the authors present CTD-measurements from two shallow meromictic mining lakes, which differ in size and depth, show completely different seasonal mixing patterns in their mixolimnia.
Abstract: . We present CTD-measurements from two shallow meromictic mining lakes. The lakes, which differ in size and depth, show completely different seasonal mixing patterns in their mixolimnia. However, the measurements document the occurrence of similar seasonal convective mixing in discrete layers within their monimolimnia. This mixing is induced by double diffusion and can be identified by the characteristic step-like structure of the temperature and electrical conductivity profiles. The steps develop in the upper part of the monimolimnion, when in autumn cooling mixolimnion temperatures have dropped below temperatures of the underlying monimolimnion. The density gradient across the chemocline due to solutes overcompensates the destabilizing temperature gradient, and moreover, keeps the vertical transport close to molecular level. In conclusion, preconditions for double diffusive effects are given on a seasonal basis. At in general high local stabilities N2 in the monimolimnia of 10−4–10−2s−2, the stability ratio Rρ was in the range of 1–20. This quantitatively indicates that double diffusion can become visible. Between 1 and 6 sequent steps, with sizes between 1 dm and 1 m, were visually identified in the CTD-profiles. In the lower monimolimnion of the deeper lake, the steps systematically emerge at a time delay of more than half a year, which matches with the progression of the mixolimnetic temperature changes into the monimolimnion. In none of the lakes, the chemocline interface is degraded by these processes. However, double diffusive convection is essential for the redistribution of solutes in the inner parts of the monimolimnion at longer time scales, which is crucial for the assessment of the ecologic development of such lakes.

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Citations
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Book ChapterDOI
01 Jan 2017
TL;DR: The chemical composition of meromictic lake waters varies widely. as discussed by the authors divided Chap. 3 into four sections and discussed biogeochemical aspects of monimolimnetic sediments from a palaeolimnologic perspective.
Abstract: The chemical composition of meromictic lake waters varies widely. Concentrations of total dissolved substances (TDS ) range from very low ( 300 g L−1), i.e. saturated with respect to particular salts. pH varies from acidic ( 10), and redox conditions range from well oxygenated and dominated by high concentrations of dissolved ferric iron (Eh about 600 mV in iron-rich acidic pit lakes) to strongly reduced (Eh < −100 mV). While the ranges of TDS and pH apply to both mixolimnion and monimolimnion, redox conditions are typically oxic for mixolimnion (except for hypolimnion in some meromictic lakes during thermal stratification) and permanently anoxic for monimolimnion. Concentrations of reduced chemical species, e.g. ferrous iron, hydrogen sulphide and ammonia, vary over a wide range in monimolimnia. Chemical differences between mixolimnion and monimolimnion are the reason for density differences that keep the stratification stable. Several processes occur in the water column of meromictic lakes that are known from sediments of holomictic lakes. Permanently anoxic conditions above the monimolimnetic sediments of meromictic lakes provide better conditions for the conservation of settling organic material and prevent disturbance by bioturbation . Based on these special conditions, we divide Chap. 3 into four sections. After a brief introduction, we present ten selected examples to illustrate the variety of chemical conditions in meromictic lakes in Sect. 3.2. We refer also to appropriate case studies presented in Chaps. 5–12. Section 3.3 is devoted to biogeochemical processes that have the potential for creating and sustaining meromixis and that occur in the water column of meromictic lakes but usually not in the water column of holomictic lakes. Special biogeochemical aspects of monimolimnetic sediments in meromictic lakes are presented in Sect. 3.4 from a palaeolimnologic point of view.

14 citations

Proceedings ArticleDOI
18 Sep 2011
TL;DR: In this paper, a brief overview of the processes relevant for the transport of substances from the waste into the main water body of pit lakes is given, together with examples and experiences from Germany and from international literature.
Abstract: Mine pits have been used as sites for disposal of wastes from mining, ore milling and refinery, oil sand processing, by-products of acid mine drainage (AMD) neutralisation, ashes of coal combustion in power plants or even industrial wastes. In several cases, pit lakes formed after disposal of the waste materials. In other cases, the disposal went on after formation of a pit lake or was even conducted in order to neutralise the pit lake. However, the deposition of waste in surface water is not allowed in many countries. The purpose of the paper is to contribute to the discussion how to handle such existing waste deposits. In order to reach that goal, the paper gives a brief overview over processes relevant for the transport of substances from the waste into the main water body of pit lakes. Examples and experiences from Germany and from international literature are presented. The presented examples and the literature show that there are advantages and disadvantages accompanying subaqueous disposal of waste. In general, the stability of the conditions inside the deposited waste and at its interface with its aqueous environment is a main prerequisite for successful long term storage of waste below a water cover. In this respect, meromixis is usually helpful. Risks such as long term change of conditions inside and around the waste deposits and the pit lakes, as groundwater contamination or as toxication of aquatic life have to be evaluated carefully and site specifically. However, there are no scientifically reasonable arguments for a general preclusion of the subaqueous disposal of waste in pit lakes.

13 citations


Cites background from "Evidence for double diffusion in te..."

  • ...Previously only reported in tropical lakes, this phenomenon has been observed in meromictic lakes of the temperate climate zone as well (Sánchez España et al., 2009; von Rohden et al., 2010)....

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Journal ArticleDOI
TL;DR: In this article, a geochemical model was incorporated into a stratification model for lakes to create the model package: DYCD-CORE, a numerical code that couples the thermal and hydrodynamic capabilities of DYRESM and the geochemical capabilities of the reactive transport model CORE2D V4.
Abstract: A geochemical model was incorporated into a stratification model for lakes to create the model package: DYCD-CORE, a numerical code that couples the thermal and hydrodynamic capabilities of DYRESM and the geochemical capabilities of the reactive transport model CORE2D V4 Based on the chemical composition of solutes calculated in each node for each time step, density was computed using specific partial molal volumes of all considered solutes and fed back into the stratification module of the program package The density calculated each time step leads to a strong coupling of hydrodynamics and hydrogeochemistry and reflects the complex interaction as it is present in all lakes To demonstrate the functionality of the numerical approach, an example of an iron-meromictic lake was chosen, where the reactivity of the dissolved iron kept the water body perennially stratified To critically validate the model results, temperatures were continously measured at high vertical and temporal resolution in a field investigation of Waldsee (near Dobern, Germany) Multiparameterprobe profiles and water samples confirmed the continous chemical stratification and served as initial and boundary conditions for the simulation period The model package DYCD-CORE could reproduce the permanent stratification as it were in the lake A demonstration run using the standard UNESCO equation for density, and hence assuming non-reactive solutes, failed entirely Hence, stratification models using salinity for density are not suited for simulating density created by lake-internal geochemical transformation of solutes However, density can be based directly on the simultaneous numerical simulation of lake geochemistry Predictive modeling of changing lake circulation in a variable climate or considering change of use will require a proper inclusion of the geochemistry as demonstrated in this paper

12 citations

Journal ArticleDOI
TL;DR: In this article, the physical limnology of pit lakes is studied and used to plan closure, manage water quality, and use pit lakes to address other water quality problems at mine sites.
Abstract: Understanding the physical limnology of pit lakes is essential to planning closure, managing water quality, and using pit lakes to address other water quality problems at mine sites. Pit lakes are ...

12 citations


Cites background from "Evidence for double diffusion in te..."

  • ...• Double-diffusion (Brenda: Hamblin et al. 1999; German mining lakes: von Rohden et al. 2010)....

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Journal ArticleDOI
TL;DR: In this article, the authors measured geothermal heat fluxes into the deepest waters of four caldera lakes and found that all lakes acquired more heat from the underground than the continental heat flux average.
Abstract: Geothermal heat fluxes into the deepest waters of four caldera lakes were measured. Temperature profiles within the stratification period between July and November 2007 allowed a quantification of the acquired heat. Due to their enormous depth, heat input from the lake bed was locally separated from heat fluxes at the surface. In conclusion, a direct measurement of geothermal heat input could be accomplished. Although enhanced geothermal activity could be suspected in all cases, two lakes showed a geothermal heat flux of 0.29 or 0.27 W/m2 (Lake Shikotsu and Lake Tazawa), as found in other regions not affected by volcanism, while both other lakes (Lake Kuttara and Lake Towada) showed a greatly enhanced heat input of 1 or 18.6 W/m2, respectively. In conclusion, within our investigated set, all lakes acquired more heat from the underground than the continental heat flux average. Hence, the heat flux into the lakes from the ground was not dominated by the temperature gradient implied by the inner heat of the earth. Other effects like the general temperature difference of deep lake water and the groundwater or local sources of heat in the underground deliver more important contributions. Obviously the flow of water in the underground can play a decisive role in the heat transport into the deep waters of lakes.

11 citations

References
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Book
23 Feb 1973
TL;DR: In this article, the authors introduce linear internal waves and herar flows in a stratified fluid and double-diffusive convection in stably stratified fluids, and show that the shear flows can produce turbulence.
Abstract: Preface 1. Introduction and preliminaries 2. Linear internal waves 3. Finite amplitude motions in stably stratified fluids 4. Instability and the production of turbulence 5. Turbulent shear flows in a stratified fluid 6. Buoyant convection from isolated sources 7. Convection from heated surfaces 8. Double-diffusive convection 9. Mixing across density interfaces 10. Internal mixing processes Bibliography and author index Recent publications Subject index.

2,722 citations


"Evidence for double diffusion in te..." refers background in this paper

  • ...The phenomenon of double diffusive convection has been discussed in detail in numerous observational, laboratory, and theoretical studies (e.g. Turner, 1973; Kelley, 2003; Schmitt, 1994)....

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  • ...Von Rohden et al. (2009) discuss this as a result of convective mixing in the mixolimnion. Convective mixing of the upper layer is strongest during summer when nocturnal cooling removes the heat of the preceding daytime through the surface. This drives a convection which reaches the (shallow) chemocline. Therefore the depth of the chemocline gradually increases during summer (chemocline erosion). In the cool season, mixing in the surface layer is weaker (wind speed 2 m above the lake surface∼0.5 m/s on average, virtually not exceeding 2 m/s), and the chemocline gradually moves upwards, presumably due to groundwater inflow. Figure 2b illustrates the situation in the larger Lake Moritzteich. The upper ∼11 m of the water column undergo the “usual” thermal cycle of temperate lakes with a warm epilimnion and a cooler hypolimnion in summer and a homothermal mixolimnion during the cool season. During the warm season starting in April, heat slowly enters the upper monimolimnion (similar to Lake Waldsee). This heating still continues while autumnal cooling already affects the mixolimnion. After the formation of local temperature maxima (e.g., on 19 November at ∼12 m), an inverse temperature profile establishes with gradients of 2–3 C/m between the mixed∼4C mixolimnion and the warmer monimolimnion. Heat diffuses out of the monimolimnion along these gradients. In general, the seasonal temperature signal at the top of the chemocline intrudes to a depth of about 16 m, i.e. at least 4 m into the monimolimnion. The monimolimnion temperatures follow the mixolimnion signal with a depth dependent delay. For example in the profile of 16 December 2008, the temperature has a local maximum at ∼ 14 m while the mixolimnion is cooler, close to 4 C. Towards the bottom, the temperature remains inversely stratified with much less variation, ending at a virtually constant value of ∼7.3C. This indicates a continuous heat flux from the sediments. With respect to electrical conductivity, we find a subdivision of the monimolimnion into two layers: The “upper” monimolimnion extends from the chemocline to ∼14 m depth. It is separated by a density step from the “lower” monimolimnion extending from∼15.8 m to the bottom. This structure as a whole has persisted for several years and has shown only little variation. While the seasonal mixing in the water bodies above the chemoclines is quite different between the lakes, their behaviour regarding the meromixis is similar. Seasonal temperature changes at the top of the chemocline proceed faster and deeper into the monimolimnion than variations of conductivity. This indicates that the effective diffusivities of heat and solutes are different. Hence, vertical transport must to a large extent be at a level close to the molecular diffusion, especially within the chemocline. The vertical density gradients are mainly caused by gradients of dissolved iron and the carbonate system. Ferrous iron (FeII ) which is transported out of the anoxic monimolimnia by diffusion is oxidized in the lower hypolimnion. As particulate ferric iron (Fe III ) it settles back into the monimolimnion, where it eventually redissolves. This chemical cycle results in the conservation of distinct chemoclines and implies an evanescent effective transport of the density regulating iron, sustaining the chemical and therefore the stable density stratification across the chemocline. These geochemical processes are discussed by means of lake Waldsee in Boehrer et al., (2009). The temporal variation of the overall electrical conductivity ( κ25) in the mixolimnion and monimolimnion of Lake Waldsee by about 10% (Fig....

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  • ...Von Rohden et al. (2009) discuss this as a result of convective mixing in the mixolimnion....

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Journal ArticleDOI
TL;DR: In this article, the authors proposed a model for the formation of meromixis in lakes, and the assumptions behind salinity, electrical conductance, potential density, and potential temperature are introduced.
Abstract: [1] Many lakes show vertical stratification of their water masses, at least for some extended time periods. Density differences in water bodies facilitate an evolution of chemical differences with many consequences for living organisms in lakes. Temperature and dissolved substances contribute to density differences in water. The atmosphere imposes a temperature signal on the lake surface. As a result, thermal stratification can be established during the warm season if a lake is sufficiently deep. On the contrary, during the cold period, surface cooling forces vertical circulation of water masses and removal of gradients of water properties. However, gradients of dissolved substances may be sustained for periods much longer than one annual cycle. Such lakes do not experience full overturns. Gradients may be a consequence of external inflows or groundwater seepage. In addition, photosynthesis at the lake surface and subsequent decomposition of organic material in the deeper layers of a lake can sustain a gradient of dissolved substances. Three more geochemical cycles, namely, calcite precipitation, iron cycle, and manganese cycle, are known for sustaining meromixis. A limited number of lakes do not experience a complete overturn because of pressure dependence of temperature of maximum density. Such lakes must be sufficiently deep and lie in the appropriate climate zone. Although these lakes are permanently stratified, deep waters are well ventilated, and chemical differences are small. Turbulent mixing and convective deep water renewal must be very effective. As a consequence, these lakes usually are not termed meromictic. Permanent stratification may also be created by episodic partial recharging of the deep water layer. This mechanism resembles the cycling of the ocean: horizontal gradients result from gradients at the surface, such as differential cooling or enhanced evaporation in adjacent shallow side bays. Dense water parcels can be formed which intrude the deep water layer. In the final section, stratification relevant physical properties, such as sound speed, hydrostatic pressure, electrical conductivity, and density, are discussed. The assumptions behind salinity, electrical conductance, potential density, and potential temperature are introduced. Finally, empirical and theoretical approaches for quantitative evaluation from easy to measure properties conclude this contribution.

532 citations


"Evidence for double diffusion in te..." refers background or methods in this paper

  • ...where α25 = 1/(25+ n/m), and n, m are the respective regression coefficients (Boehrer and Schultze, 2008)....

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  • ...From the linear regression to the data from 1.5◦C to 30◦C the electrical conductivity for the chosen reference temperature of 25◦C could be evaluated: κ25= C(T ) α25(T −25◦C)+1 , (1) where α25 = 1/(25+ n/m), and n, m are the respective regression coefficients (Boehrer and Schultze, 2008)....

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  • ...Meromixis is a well known phenomenon, also occurring in lakes located in regions in a temperate climate (Boehrer and Schultze, 2008)....

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Journal ArticleDOI
TL;DR: Turner et al. as mentioned in this paper showed how opposing stratifications of two component species could drive convection if their diffusivities differed, and they also identified the potential for the oscillatory instability when cold, fresh water overlies warm, salty water.
Abstract: The modern study of double-diffusive convection began with Melvin Stern's article on "The Salt Fountain and Thermohaline Convection" in 1960. In that paper, he showed how opposing stratifications of two component species could drive convection if their diffusivities differed. Stommel ct al (1956) had earlier noted that there was significant potential energy available in the decrease of salinity with depth found in much of the tropical and subtropical ocean. While they suggested that a flow (the salt fountain) would be driven in a thermally-conducting pipe, it was Stern who realized that the two orders of magnitude difference in heat and salt diffusivities allowed the ocean to form its own pipes. These later came to be known as "salt fingers." Stern also identified the potential for the oscillatory instability when cold, fresh water overlies warm, salty water in the 1960 paper, though only in a footnote. Turner & Stommel (1964) demonstrated the "diffusive-convection" process a few years later. From these beginnings in oceanography over three decades ago, double diffusion has come to be recognized as an important convection process in a wide variety of fluid media, including magmas, metals, and stellar interiors (Schmitt 1983, Turner 1985). However, it is interesting to note that about one hundred years before Stern's paper, W. S. Jevons (1857) reported on the observation of long, narrow convection cells formed when warm, salty water was introduced over cold, fresh water. He correctly attributed the phenomenon to a difference in the diffusivities for heat and

498 citations


"Evidence for double diffusion in te..." refers background in this paper

  • ...The phenomenon of double diffusive convection has been discussed in detail in numerous observational, laboratory, and theoretical studies (e.g. Turner, 1973; Kelley, 2003; Schmitt, 1994)....

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Journal ArticleDOI
TL;DR: In this paper, the authors calculate the following properties over the range of 0-0.6 salinity, 0/sup 0/-30/sub 0/C, and 0-180 bars: density, thermal expansibility, temperature of maximum density, maximum density and minimum specific volume, isothermal compressibility, specific heat at constant pressure, and sound speed.
Abstract: Dissolved salts affect the thermodynamic properties of lake waters. Equations are given to calculate the following properties over the range of 0-0.6 salinity, 0/sup 0/-30/sup 0/C, and 0-180 bars: density, thermal expansibility, temperature of maximum density, maximum density and minimum specific volume, isothermal compressibility, specific heat at constant pressure, specific heat at constant volume, sound speed, adiabatic compressibility, freezing point, adiabatic temperature gradient, and static stability.

290 citations


"Evidence for double diffusion in te..." refers methods in this paper

  • ...We therefore developed specific formulas to calculate water density from measured electrical conductivity and temperature, since standard formulas (e.g. Chen and Millero, 1986) did not apply (e.g., Hamblin et al., 1999)....

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Journal ArticleDOI
TL;DR: In this article, the diffusive regime of double-diffusive convection is discussed, with a particular focus on unresolved issues that are holding up the development of large-scale parameterizations.

174 citations