Fe3O4@dopa (dopa = dopamine hydrochloride) functionalized Mn(III) Schiff base complex: A promising magnetically separable heterogeneous catalyst for oxidative transformations
TL;DR: A chiral Schiff base complex has been prepared by treating (R)-1,2-diaminopropane with 3,5-dichlorosalicylaldehyde in ethanol, followed by addition of manganese chloride hexahydrate to generate a h... as discussed by the authors.
Abstract: A chiral Schiff base complex has been prepared by treating (R)-1,2-diaminopropane with 3,5-dichlorosalicylaldehyde in ethanol, followed by addition of manganese chloride hexahydrate to generate a h...
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TL;DR: In this article, a new method to synthesize heterogeneous catalyst by dispersion of Silver nanoparticles onto Alumina supported cobalt and copper Schiff base complexes (AgNPs-Al2O3@ML) was developed.
20 citations
TL;DR: In this work, magnetic nanoparticles are categorized according to their preparation procedures and structures in an attempt to unravel the structure-function relationship and to guide the future study of MNPs' design for olefin epoxidations.
Abstract: Epoxidation of olefins stands out as a crucial class of reactions and is of great interest in academic research and industry due to the production of various important fine chemicals and intermediates. Manganese complexes have the potential to catalyze the epoxidation of olefins with high efficiency. Magnetic nanocatalysts have attracted significant attention for immobilizing homogeneous transition metal complexes. Easy separation by external magnetic fields, nontoxicity, and a core shell structure are the main advantages of magnetic nanocatalysts over other heterogeneous catalysts. The method of functionalizing magnetic nanoparticles and of anchoring homogeneous metal complexes has significant effects on catalytic performance. Therefore, a critical review of recent research progress on manganese complexes’ immobilization on magnetic nanoparticles for liquid phase olefin epoxidation is necessary. In this work, magnetic nanoparticles are categorized according to their preparation procedures and structures. The physical/chemical properties, catalytic performance for olefin epoxidation, reusability and plausible reaction mechanisms will be discussed, in an attempt to unravel the structure–function relationship and to guide the future study of MNPs’ design for olefin epoxidations.
13 citations
TL;DR: Magnetically recoverable MgFe2O4@SiO2-PrNH2/Pd/bimenthonoxime nanoparticles were prepared and characterized by SEM, EDX, TEM, XRD, XPS, ICP, VSM and FT-IR as mentioned in this paper.
Abstract: Magnetically recoverable MgFe2O4@SiO2-PrNH2/Pd/bimenthonoxime nanoparticles were prepared and characterized by SEM, EDX, TEM, XRD, XPS, ICP, VSM and FT-IR. The nanocatalyst was used for Suzuki cros...
13 citations
TL;DR: A simpler cost-effective method for the isolation of magnetically separable self-doped iron oxide nanocarbons (FeO-NC) from waste printer ink (used as a carbon source material which is available free of cost) is discussed in this paper.
13 citations
02 Jul 2019
TL;DR: It is worthy of mention that the synthesized CTAB-coated magnetically separable nanocatalysts can be magnetically recovered from the aqueous reaction mixture after more than five cycles, which renders this approach as a sustainable and accessible one.
Abstract: Cetrimonium bromide (CTAB)-coated water disperse magnetically separable nanocatalysts CTAB/Fe3O4@dopa@ML (M = Fe or Mn, L = cyclohexane-1,2-diylbis(azanylylidene)bis(methanylylidene)bis(2,4-diXphenol; X = Cl, Br, and I) have been synthesized using a simple synthetic strategy. This approach provides a new fruitful strategy to reduce the leaching of the active metal complex from the catalyst surface to the aqueous media. The synthesized catalysts have been found to be excellent for oxidation of alcohols in aqueous medium at room temperature. A probable catalytic pathway involving the generation of hydroperoxo intermediates has been assumed, and these intermediates have been characterized using density functional theory and several spectroscopic techniques. It is worthy of mention that the synthesized CTAB-coated magnetically separable nanocatalysts can be magnetically recovered from the aqueous reaction mixture after more than five cycles, which renders this approach as a sustainable and accessible one.
10 citations
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TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
Abstract: An account is given of the development of the SHELX system of computer programs from SHELX-76 to the present day. In addition to identifying useful innovations that have come into general use through their implementation in SHELX, a critical analysis is presented of the less-successful features, missed opportunities and desirable improvements for future releases of the software. An attempt is made to understand how a program originally designed for photographic intensity data, punched cards and computers over 10000 times slower than an average modern personal computer has managed to survive for so long. SHELXL is the most widely used program for small-molecule refinement and SHELXS and SHELXD are often employed for structure solution despite the availability of objectively superior programs. SHELXL also finds a niche for the refinement of macromolecules against high-resolution or twinned data; SHELXPRO acts as an interface for macromolecular applications. SHELXC, SHELXD and SHELXE are proving useful for the experimental phasing of macromolecules, especially because they are fast and robust and so are often employed in pipelines for high-throughput phasing. This paper could serve as a general literature citation when one or more of the open-source SHELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
81,116 citations
TL;DR: L Lists of software presented and~or reviewed in the Journal of Applied Crystallography are available on the World Wide Web at the above address, together with information about the availability of the software where this is known.
Abstract: Computer Program Abstracts The category Computer Program Abstracts provides a rapid means of communicating up-to-date information concerning both new programs or systems and significant updates to existing ones. Following normal submission, a Computer Program Abstract will be reviewed by one or two members of the IUCr Commission on Crystallographic Computing. It should not exceed 500 words in length and should follow the standard format given on page 189 of the June 1985 issue of the Journal [J. Appl. CrysL (1985). 18, 189190] and on the World Wide Web at http://www.iucr. ac. uk/journals/jac/software/. Lists of software presented and~or reviewed in the Journal of Applied Crystallography are available on the World Wide Web at the above address, together with information about the availability of the software where this is known. J. App/. CrysL (1997). 30, 565 ORTEP-3 for Windows a version of ORTEP-III with a Graphical User Interface (GUI)
19,468 citations
TL;DR: The category Computer Program Abstracts provides a rapid means of communicating up-to-date information concerning both new programs or systems and signi®cant updates to existing ones.
Abstract: The category Computer Program Abstracts provides a rapid means of communicating up-to-date information concerning both new programs or systems and signi®cant updates to existing ones. Following normal submission, a Computer Program Abstract will be reviewed by one or two members of the IUCr Commission on Crystallographic Computing. It should not exceed 500 words in length and should follow the standard format given on page 189 of the June 1985 issue of the Journal [J. Appl. Cryst. (1985). 18, 189± 190] and on the World Wide Web at http://www.iucr. org/journals/jac/software/. Lists of software presented and/or reviewed in the Journal of Applied Crystallography are available on the World Wide Web at the above address, together with information about the availability of the software where this is known.
18,151 citations
TL;DR: Advances in characterization methods have led to a molecular-level understanding of the relationships between nanoparticle properties and catalytic performance, and this knowledge is contributing to the design and development of new catalysts.
Abstract: Most catalysts consist of nanometer-sized particles dispersed on a high-surface-area support. Advances in characterization methods have led to a molecular-level understanding of the relationships between nanoparticle properties and catalytic performance. Together with novel approaches to nanoparticle synthesis, this knowledge is contributing to the design and development of new catalysts.
2,243 citations
TL;DR: This Review concludes with a conclusion that further research is needed into the determinants of infectious disease and the immune system in order to treat these diseases and provide effective treatments.
Abstract: We gratefully acknowledge funding and support from King Abdullah University of Science and Technology (KAUST). Thanks are also due to the KAUST communication department for designing several images for this Review.
1,497 citations