Dissertation•
Flexible membranes for nanoplasmonic applications
01 Jan 2015-
TL;DR: In this article, a general method to make nanoplasmonic devices on a flexible membrane structure, which can be free standing, extremely thin (less than the wavelength of visible light), but retains the ability to be manipulated without loss of optical function, is presented.
Abstract: Nanoplasmonics has provided a way to control light with extremely high precision, into nanoscale volumes. In many circumstances, the nanoplasmonic devices which can be realised are fabricated using processing techniques which rely on planar technologies. This thesis provides a general method to make nanoplasmonic devices on a flexible membrane structure, which can be free standing, extremely thin (less than the wavelength of visible light), but retains the ability to be manipulated without loss of optical function. These devices are very pliant and conformable. Flexibility allows the integration of nanoplasmonic devices into many new applications where curved surfaces or the ability to conform to another object is required, as well as providing a route for post-fabrication tunability. Two specific applications are considered: lab-on-fibre technology and surface enhanced Raman spectroscopy. Lab-on-fibre technologies have been advancing the ability to miniaturise experiments which would normally require a whole laboratory. Fabricating a membrane and then later applying it to the fibre decouples the choice of fibre from the design of the device. Surface enhanced Raman spectroscopy is a powerful diagnostic tool which can uniquely identify an optical fingerprint of different molecules. The technique has been held back from widespread clinical adoption because of the difficulty of reproducibility of the substrates used. A repeatable and reliable rigid substrate is demonstrated, which can identify the concentration of a three component mixture of physiologically relevant biomolecules. This same design is then shown in a flexible form factor, which is applied to a non-planar landscape where it can identify the locations where a molecule of interest has been deposited. This thesis details the development of the fabrication protocol, the construction of experimental apparatus for characterisation, and the use of numerical modelling to advance the flexible nanoplasmonic membrane platform. Candidate’s declarations: I, Peter Reader-Harris, hereby certify that this thesis, which is approximately 40,000 words in length, has been written by me, and that it is the record of work carried out by me, or principally by myself in collaboration with others as acknowledged, and that it has not been submitted in any previous application for a higher degree. I was admitted as a research student in September 2011 and as a candidate for the degree of Doctor of Philosophy in September 2011; the higher study for which this is a record was carried out in the University of St Andrews between 2011 and 2015. Date Signature of candidate Supervisor’s declaration: I hereby certify that the candidate has fulfilled the conditions of the Resolution and Regulations appropriate for the degree of Doctor of Philosophy in the University of St Andrews and that the candidate is qualified to submit this thesis in application for that degree. Date Signature of supervisor Permission for publication: In submitting this thesis to the University of St Andrews I understand that I am giving permission for it to be made available for use in accordance with the regulations of the University Library for the time being in force, subject to any copyright vested in the work not being affected thereby. I also understand that the title and the abstract will be published, and that a copy of the work may be made and supplied to any bona fide library or research worker, that my thesis will be electronically accessible for personal or research use unless exempt by award of an embargo as requested below, and that the library has the right to migrate my thesis into new electronic forms as required to ensure continued access to the thesis. I have obtained any third-party copyright permissions that may be required in order to allow such access and migration, or have requested the appropriate embargo below. The following is an agreed request by candidate and supervisor regarding the publication of this thesis: PRINTED COPY No embargo on print copy ELECTRONIC COPY No embargo on electronic copy Date Signature of candidate Signature of supervisor
Citations
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01 Jan 2002
TL;DR: In this article, a review of numerical and experimental studies of supercontinuum generation in photonic crystal fiber is presented over the full range of experimentally reported parameters, from the femtosecond to the continuous-wave regime.
Abstract: A topical review of numerical and experimental studies of supercontinuum generation in photonic crystal fiber is presented over the full range of experimentally reported parameters, from the femtosecond to the continuous-wave regime. Results from numerical simulations are used to discuss the temporal and spectral characteristics of the supercontinuum, and to interpret the physics of the underlying spectral broadening processes. Particular attention is given to the case of supercontinuum generation seeded by femtosecond pulses in the anomalous group velocity dispersion regime of photonic crystal fiber, where the processes of soliton fission, stimulated Raman scattering, and dispersive wave generation are reviewed in detail. The corresponding intensity and phase stability properties of the supercontinuum spectra generated under different conditions are also discussed.
360 citations
04 Nov 2009
TL;DR: In this paper, the authors report a new approach for scalable manufacturing of MetaMaterials fabricated through floating and rolling-up flexible metallodielectric stacks, which offers an efficient fabrication route for multi-layer structures, improving the uniformity and enabling unusual structural configurations.
Abstract: We report a new approach for scalable manufacturing of MetaMaterials fabricated through floating and rolling-up flexible metallodielectric stacks. This process offers an efficient fabrication route for multi-layer structures, improving the uniformity and enabling unusual structural configurations. Probing example metallic Bragg structures spectroscopically shows good agreement with transfer matrix simulations, demonstrating strong reflection and transmission resonances within the visible. These resonances arise from the Bragg nature of the multi-layer: at specific resonant frequencies the optical field of the light tunnels through the metal with a hundred-fold reduction in loss. Such structures have unusual nonlinear optical properties and many applications in sub-wavelength focusing and metamaterial activity.
28 citations
References
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TL;DR: In this paper, the optical constants for the noble metals (copper, silver, and gold) from reflection and transmission measurements on vacuum-evaporated thin films at room temperature, in the spectral range 0.5-6.5 eV.
Abstract: The optical constants $n$ and $k$ were obtained for the noble metals (copper, silver, and gold) from reflection and transmission measurements on vacuum-evaporated thin films at room temperature, in the spectral range 0.5-6.5 eV. The film-thickness range was 185-500 \AA{}. Three optical measurements were inverted to obtain the film thickness $d$ as well as $n$ and $k$. The estimated error in $d$ was \ifmmode\pm\else\textpm\fi{} 2 \AA{}, and that in $n$, $k$ was less than 0.02 over most of the spectral range. The results in the film-thickness range 250-500 \AA{} were independent of thickness, and were unchanged after vacuum annealing or aging in air. The free-electron optical effective masses and relaxation times derived from the results in the near infrared agree satisfactorily with previous values. The interband contribution to the imaginary part of the dielectric constant was obtained by subtracting the free-electron contribution. Some recent theoretical calculations are compared with the results for copper and gold. In addition, some other recent experiments are critically compared with our results.
17,509 citations
"Flexible membranes for nanoplasmoni..." refers methods in this paper
...6a, but using the real values for gold’s permittivity from Johnson and Christy [76]....
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...1 shows a comparison between this free electron model, with the parameters quoted for gold in the text, and the measured values from Johnson and Christy [76]....
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...Although these absorption effects can be included by further terms [77], it is not necessary for the work here as the Johnson and Christy [76] values are used for the modelling in the rest of the thesis....
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...As in the introduction, the values for the electric permittivity of gold used are those from Johnson and Christy [76]....
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...The circles use the permittivity for gold measured by Johnson and Christy [76]....
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TL;DR: The authors' simulations show that a version of the lens operating at the frequency of visible light can be realized in the form of a thin slab of silver, which resolves objects only a few nanometers across.
Abstract: Optical lenses have for centuries been one of scientists’ prime tools. Their operation is well understood on the basis of classical optics: curved surfaces focus light by virtue of the refractive index contrast. Equally their limitations are dictated by wave optics: no lens can focus light onto an area smaller than a square wavelength. What is there new to say other than to polish the lens more perfectly and to invent slightly better dielectrics? In this Letter I want to challenge the traditional limitation on lens performance and propose a class of “superlenses,” and to suggest a practical scheme for implementing such a lens. Let us look more closely at the reasons for limitation in performance. Consider an infinitesimal dipole of frequency v in front of a lens. The electric component of the field will be given by some 2D Fourier expansion,
10,974 citations
"Flexible membranes for nanoplasmoni..." refers background in this paper
...These are a wide body of materials and devices, which include cloaking devices [22], [58], [59], flat lenses [60]–[62], perfect lenses [63], beam shaping surfaces [64], [65], and optical materials to perform mathematical operations [66]....
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TL;DR: In this article, surface-enhanced Raman scattering was used to detect single molecules and single nanoparticles at room temperature with the use of surface enhanced Raman, and the intrinsic Raman enhancement factors were on the order of 10 14 to 10 15, much larger than the ensemble-averaged values derived from conventional measurements.
Abstract: Optical detection and spectroscopy of single molecules and single nanoparticles have been achieved at room temperature with the use of surface-enhanced Raman scattering. Individual silver colloidal nanoparticles were screened from a large heterogeneous population for special size-dependent properties and were then used to amplify the spectroscopic signatures of adsorbed molecules. For single rhodamine 6G molecules adsorbed on the selected nanoparticles, the intrinsic Raman enhancement factors were on the order of 10 14 to 10 15 , much larger than the ensemble-averaged values derived from conventional measurements. This enormous enhancement leads to vibrational Raman signals that are more intense and more stable than single-molecule fluorescence.
9,609 citations
Book•
03 Jul 1995
TL;DR: In this paper, the authors developed the theoretical tools of photonics using principles of linear algebra and symmetry, emphasizing analogies with traditional solid-state physics and quantum theory, and investigated the unique phenomena that take place within photonic crystals at defect sites and surfaces, from one to three dimensions.
Abstract: Since it was first published in 1995, Photonic Crystals has remained the definitive text for both undergraduates and researchers on photonic band-gap materials and their use in controlling the propagation of light. This newly expanded and revised edition covers the latest developments in the field, providing the most up-to-date, concise, and comprehensive book available on these novel materials and their applications. Starting from Maxwell's equations and Fourier analysis, the authors develop the theoretical tools of photonics using principles of linear algebra and symmetry, emphasizing analogies with traditional solid-state physics and quantum theory. They then investigate the unique phenomena that take place within photonic crystals at defect sites and surfaces, from one to three dimensions. This new edition includes entirely new chapters describing important hybrid structures that use band gaps or periodicity only in some directions: periodic waveguides, photonic-crystal slabs, and photonic-crystal fibers. The authors demonstrate how the capabilities of photonic crystals to localize light can be put to work in devices such as filters and splitters. A new appendix provides an overview of computational methods for electromagnetism. Existing chapters have been considerably updated and expanded to include many new three-dimensional photonic crystals, an extensive tutorial on device design using temporal coupled-mode theory, discussions of diffraction and refraction at crystal interfaces, and more. Richly illustrated and accessibly written, Photonic Crystals is an indispensable resource for students and researchers.Extensively revised and expanded Features improved graphics throughout Includes new chapters on photonic-crystal fibers and combined index-and band-gap-guiding Provides an introduction to coupled-mode theory as a powerful tool for device design Covers many new topics, including omnidirectional reflection, anomalous refraction and diffraction, computational photonics, and much more.
8,188 citations
"Flexible membranes for nanoplasmoni..." refers background in this paper
...Bloch’s theorem guarantees that if the operator, Ô, of a system commutes with the translation operator, T̂, then the eigenfunctions of that operator will generally be of the form v(r) = eik·ru(r) [91]....
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TL;DR: This work shows how electromagnetic fields can be redirected at will and proposes a design strategy that has relevance to exotic lens design and to the cloaking of objects from electromagnetic fields.
Abstract: Using the freedom of design that metamaterials provide, we show how electromagnetic fields can be redirected at will and propose a design strategy. The conserved fields-electric displacement field D, magnetic induction field B, and Poynting vector B-are all displaced in a consistent manner. A simple illustration is given of the cloaking of a proscribed volume of space to exclude completely all electromagnetic fields. Our work has relevance to exotic lens design and to the cloaking of objects from electromagnetic fields.
7,811 citations
"Flexible membranes for nanoplasmoni..." refers background in this paper
...These are a wide body of materials and devices, which include cloaking devices [22], [58], [59], flat lenses [60]–[62], perfect lenses [63], beam shaping surfaces [64], [65], and optical materials to perform mathematical operations [66]....
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...Transformation optics is a tool which gives unprecedented control over how light propagated through a system [22], [58]....
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