Formation and characterization of borohydride reduced electroless nickel deposits
TL;DR: In this article, the formation of electroless Ni-B deposits and evaluation of their characteristic properties were studied. And the corrosion resistance of Ni-b deposits, in 3.5% sodium chloride solution, both in as-plated and heat-treated (450°C/1 h) conditions, was also evaluated by potentiostatic polarization and electrochemical impedance studies.
About: This article is published in Journal of Alloys and Compounds.The article was published on 2004-02-25. It has received 136 citations till now. The article focuses on the topics: Electroless nickel & Nickel boride.
Citations
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TL;DR: In this article, Ni-B coatings have been deposited directly on commercial purity magnesium and AZ91D alloy and characterized using glow discharge optical emission spectroscopy, scanning electron microscopy, X-ray diffraction and, for tribological and mechanical evaluation, dry sliding wear and friction testing and microhardness measurement.
68 citations
TL;DR: In this paper, the effects of both treatments were compared: after the treatment carried out under lowered pressure, the coatings are dense, present signs of solution hardening and are characterized by a high hardness (close to 1600 hv100).
67 citations
TL;DR: In this paper, the authors have reported on the development of a biodegradable electroless Ni-B bath and evaluated its characteristic properties, and the influence of bath constituents, temperature and pH on the rate of deposition was studied.
Abstract: Electroless deposition process has undergone numerous changes to meet the challenging needs for a variety of industrial applications ever since the invention of the process during 1947. Among the various metals that can be electrolessly plated, electroless nickel has proved its supremacy for producing coatings with high corrosion resistance, hardness, wear resistance and uniformity. Electroless nickel can be deposited from a variety of baths and the coating properties depends upon the type of reducing agents and other deposition conditions. Electroless nickel–boron coatings have received considerable interest nowadays because of the superior hardness, corrosion and wear resistance characteristics. In this paper, the authors have reported on the development of a biodegradable electroless Ni–B bath and evaluated its characteristic properties. The influence of bath constituents, temperature and pH on the rate of deposition was studied. Scanning electron microscopy, X-ray diffraction, X-ray fluoresce...
67 citations
TL;DR: In this paper, the experiments are carried out to reduce the friction and improve corrosion resistant properties of Ni-B coating by PTFE impregnation, and it is found that Ni-b coating after impregnated by an aqueous solution containing 40 ¼wt% pTFE nanoparticles is able to withstand a rubbing test duration of 3600 s with the coefficient of friction as low as
Abstract: Electroless nickel boron (Ni-B) coatings are finding their applications in the aerospace, automotive, chemical and electrical industries due to their properties such as high hardness and high wear resistance. However, Ni-B coatings generally show high friction. They also suffered from severe attacks in aqueous solution containing Cl− ion. In this paper, the experiments are carried out to reduce the friction and improve corrosion resistant properties of Ni-B coating by PTFE impregnation. It is found that Ni-B coating after impregnated by an aqueous solution containing 40 wt% PTFE nanoparticles is able to withstand a rubbing test duration of 3600 s with the coefficient of friction as low as
65 citations
TL;DR: In this paper, an electroless nickel-boron-aluminum alloy was plated with nickelboron coatings by the electroless deposition method and the wear track was examined by SEM and roughness measurement.
Abstract: Al–Cu–Mg (Grade 2024) aluminum alloy was plated with nickel–boron coatings by the electroless deposition method. Some of the coatings were submitted to a hardening heat treatment specifically designed for electroless nickel coated aluminum alloys, with the following conditions: 180 °C — 4 h; in an atmosphere containing 95% Ar and 5% H 2 . Uncoated aluminum, treated and untreated samples were submitted to the Taber abrasion test to assess their wear resistance. The wear track was then examined by SEM and roughness measurement. The wear resistance of the coated samples was quite good, with a Taber Wear Index of 28.5 before heat treatment and 24 after (obtained with CS-17 wheels). The corrosion resistance of the samples was investigated by the way of polarization and electrochemical impedance spectroscopy (EIS) and the influence of the heat treatment was observed. Corrosion resistance of the system is good, with a corrosion potential close to − 250 mV, and heat treatment improves it slightly. Taber abrasion tests were used to simulate erosion of the coatings during use. Worn coatings were then submitted to electrochemical tests to assess conservation of corrosion resistance during use of coated samples. Only a slight decrease of the corrosion resistance was observed.
64 citations
References
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Book•
01 Jan 1990
TL;DR: The Electroless Plating: Fundamentals and Applications (ESPA) as discussed by the authors is a comprehensive text that covers both fundamental and applied aspects of electroless deposition, and was first introduced at SUR/FIN '91.
Abstract: Many texts have been written on surface finishing over the years that deal with electroless deposition as a sidelight. Through the talents and efforts of Glenn Mallory and Juan Hajdu, a comprehensive text, entitled Electroless Plating: Fundamentals and Applications, is available through AESF Headquarters. The editors have combined the efforts of 27 contributing authors to produce a wide-ranging text that covers both fundamental and applied aspects of the subject. Published by the AESF, the book was first introduced at SUR/FIN ‘91—Toronto.
963 citations
Patent•
23 Sep 1968
TL;DR: HIGH STABILITY, AUTOCATALYTIC ELECTROLESS NICKEL PLATING BATH COMPRISING an AQUEOUS SOLUTION CONTAINing about 0.08-016 MOLE/LITER NICKels IONS, about 019-0.38 MOLE / LITER HYPOPHOSPHITE IONS and ESSENTIALLY about 035-3.14 MOLE or Liter CITRATE IONS as discussed by the authors.
Abstract: HIGH STABILITY, AUTOCATALYTIC ELECTROLESS NICKEL PLATING BATH COMPRISING AN AQUEOUS SOLUTION CONTAINING ABOUT 0.08-016 MOLE/LITER NICKEL IONS, ABOUT 0.19-0.38 MOLE/ LITER HYPOPHOSPHITE IONS, AND ESSENTIALLY ABOUT 0.35-3.68 MOLE/LITER AMMONIUM IONS, ABOUT 0.0.-1.07 MOLE/LITER ACETATE ION AND ABOUT 0.007-0.14 MOLE/LITER CITRATE IONS, THE SOLUTION HAVING A PH IN THE RANGE OF ABOUT 7.0 TO ABOUT 9.5 THE AMMONIUM IONS COMPLEX PALLADOUS IONS INTRODUCED INTO THE PLATING BATH BY "DRAG OUT" FROM THE ACTIVATOR SOLUTION TO FORM A SOLUBLE AMMONIUM-PALLADIUM COMPLEX, WHICH INHIBITS REDUCTION OF PALLADOUS ION TO ZERO VALENT CATALYTIC PALLADIUM BY THE HYPOPHOSPHITE OF THE BATH. BY THE REMOVAL OF POTENTIAL CATALYST SITES FROM THE BATH OR BY RENDERING THE POTENTIAL SITES RELATIVELY CATALYTICALLY INACTIVE, RANDOM DEPOSITION OF THE NICKEL AND PREMATURE LOSS OF THE BATH IS AVOIDED.
154 citations
TL;DR: In this paper, the same fundamental reaction is occurring on all the coatings of the present study but over a different effective area in each case, which can be attributed to the decrease in the effective metallic area prone to corrosion.
Abstract: Electroless Ni-P composite coatings have gained a good deal of popularity and acceptance in recent years as they provide considerable improvement of desirable qualities such as hardness, wear, abrasion resistance, etc. The disagreement among researchers on the corrosion behaviour of these coatings warrants a thorough investigation. Among the various techniques available for the determination of corrosion resistance, electrochemical impedance spectroscopy (EIS) is considered to be superior as it provides not only an assessment of the corrosion resistance of different deposits but also enables the mechanistic pathway by which the deposits become corroded to be determined. The present investigation focuses on the evaluation of the corrosion resistance of electroless Ni-P and Ni-P-Si3N4, Ni-P-CeO2 and Ni-P-TiO2 composite coatings produced using an acidic hypophosphite-reduced electroless nickel bath, using EIS. The study makes evident that the same fundamental reaction is occurring on all the coatings of the present study but over a different effective area in each case. The charge transfer resistance of electroless Ni-P and Ni-P composite deposits are in the range 32,253–90,700 Ω cm2, whereas the capacitances of these coatings are in the range 11–17 µF/cm2. The improved corrosion resistance obtained for electroless Ni-P and Ni-P composite coatings is due to the enrichment of phosphorus on the electrode surface, which enables the preferential hydrolysis of phosphorus over that of nickel. The better corrosion resistance obtained for electroless Ni-P composite coatings can be ascribed to the decrease in the effective metallic area prone to corrosion. Among the three electroless Ni-P composite coatings, the corrosion resistance is in the following order: Ni-P-CeO2=Ni-P-Si3N4>Ni-P-TiO2.
119 citations
TL;DR: In this paper, the effect of phosphorus on the corrosion behavior of electroless nickel-plated mild steel in deaerated 40 w/o NaOH solution was examined using potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) techniques.
Abstract: Electroless Ni-P deposits with phosphorus content ranging from 4.8 to 12.8 weight percent (w/o) were examined using potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) techniques to characterize the effect of phosphorus on the corrosion behavior of electroless nickel-plated mild steel in deaerated 40 w/o NaOH solution. Anodic polarization of the electroless Ni-P alloys in caustic NaOH solution shows that the passive current density decreases with increasing phosphorus content in the deposits. At an applied potential of -1.2 V vs. saturated calomel electrode (V SCE ) (close to their E corr ), EIS data indicate that the R ct for Ni-P alloys in NaOH solution increases with increasing phosphorus content. X-ray photoelectron spectroscopy (XPS) results suggest that the primary constituent formed on the Ni-P surface after EIS measurement in 40 w/o NaOH solution at an applied potential of -0.4 V SCE (in the passive region) is Ni(OH) 2 , which is responsible for the passivity of the Ni-P alloys. The polarization resistance of Ni-P alloys in NaOH solution at -0.4 V SCE also increases with increasing phosphorus content
111 citations