Journal ArticleDOI
Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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This article is published in Accounts of Chemical Research.The article was published on 1981-05-01. It has received 786 citations till now. The article focuses on the topics: Organic anion.read more
Citations
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Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions in total synthesis.
TL;DR: In this Review, highlights of a number of selected syntheses are discussed, demonstrating the enormous power of these processes in the art of total synthesis and underscore their future potential in chemical synthesis.
Journal ArticleDOI
Organic Reactions in Aqueous Media with a Focus on Carbon−Carbon Bond Formations: A Decade Update
TL;DR: Reaction of R,â-Unsaturated Carbonyl Compounds 3127: Reaction of R-UnSaturated Carbonies 3127 7.1.6.
Journal ArticleDOI
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
TL;DR: A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki coupling reactions over the last 15 years as mentioned in this paper, and there are now many suggestions in the literature that narrow the scope of types of precatalyst that may be considered true catalysts in these coupling reactions.
Journal ArticleDOI
Isolation and synthesis of biologically active carbazole alkaloids
Journal ArticleDOI
Atomic and molecular electron affinities: photoelectron experiments and theoretical computations.
Jonathan C. Rienstra-Kiracofe,Gregory S. Tschumper,Henry F. Schaefer,Sreela Nandi,G. Barney Ellison +4 more
TL;DR: Theoretical D determination of Electron Affinities and Statistical Analysis of DFT Results ThroughComparisons to Experiment and Other theoretical Methods and Specific Theoretical Successes 251E.
References
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Journal ArticleDOI
Gas-phase nucleophilic displacement reactions
Book ChapterDOI
Flowing Afterglow Measurements of Ion-Neutral Reactions
TL;DR: This chapter describes the experimental and analytical techniques that have been developed for flowing afterglow applications to the quantitative study of ion–neutral reaction processes, and the dc discharge was found to be advantageous.
Journal ArticleDOI
Ion-Neutral Reaction-Rate Constants Measured in Flow Reactors through 1977
TL;DR: The rate constants of ion-neutral reactions with flowing-after-glow, flow-drift, and selected-ion flow tubes have been compiled in this paper, where the data for both positive and negative ion reactions are included and arranged for access by the reactant ion, reactant neutral, and product ion.
Journal ArticleDOI
Ion Cyclotron Resonance Spectroscopy
TL;DR: Ion cyclotron resonance spectroscopy has met with such wide acceptance that research groups utilizing this relatively new experimental technique now likely outnumber research groups which have used more traditional techniques, such as high pressure mass spectrometry, for the study of ion-molecule reactions as discussed by the authors.
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