Generalized model of the surface layer for the case of adsorption of organic molecules on the electrode
TL;DR: In this article, an equation for the electrode charge in the presence of adsorbed organic molecules is suggested and analyzed; from this Frumkin's, Hansen's and Parsons' models, discussed earlier in the literature, can be derived under particular conditions.
About: This article is published in Journal of Electroanalytical Chemistry.The article was published on 1970-11-01. It has received 82 citations till now.
Citations
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TL;DR: In this article, the significance of adsorption isotherms is discussed and several experimental examples taken from the literature illustrate the possible behaviour of the various parameters and constitute the basis for the establishment of diagnostic criteria to help interpret experimental adsoreption data.
166 citations
TL;DR: In this paper, the adsorption parameters of pyridine on an Au(111) single crystal electrode surface have been determined as a function of the electrode potential and surface charge density.
142 citations
TL;DR: In this paper, it was found that at a negatively charged surface, pyridine adsorbs in the flat orientation, reaching a limiting surface concentration of 3 × 10 −10 mol cm −2.
105 citations
TL;DR: In this article, the Gibbs energies of adsorption, electrosorption valencies, potentials and charges of pyridine were determined for the flat and the vertical orientation of Pyridine.
93 citations
TL;DR: In this article, the capacity of the inner layer has been also determined at constant amount adsorbed, and hypotheses have been made on the detailed structure of inner layer in the presence of ACN.
77 citations
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296 citations
TL;DR: In this paper, a quantitative Theorie der Beeinflussung der Adsorption von Neutralmolekulen durch das elektrische Feld an der Oberflache is presented.
Abstract: Es wird eine quantitative Theorie der Beeinflussung der Adsorption von Neutralmolekulen durch das elektrische Feld an der Oberflache entwickelt, die die Deutung der Form der in Gegenwart von kapillaraktiven organischen Substanzen beobachteten Elektrokapillarkurven gestattet
283 citations
TL;DR: In this paper, a number of different isotherms have been used to describe the adsorption of ions and molecules at metal electrodes, with the object of assessing their usefulness for this purpose.
155 citations
TL;DR: In this paper, the criticisms of a, recent paper made by F rumkin 2 and D amaskin 3 are discussed and a discussion of the shortcomings of the paper is presented.
131 citations
TL;DR: In this paper, the assumption of the congruence of the adsorption isotherm with respect to the electrode potential or charge is supplemented by the assumption that the double-layer capacity in the supporting electrolyte solution, C0, does not differ from the capacity, C′, at complete surface coverage with adsorbed substance.
94 citations