Geochemistry of eocene calc-alkaline volcanic rocks from the Kastamonu area, Northern Turkey
TL;DR: In this paper, the Pontic eocene volcanic rocks cropping out in the Kastamonu area, Pontic chain of Northern Turkey were analyzed and the SiO2% versus K2O% relationship showed that the analyzed samples belong to two major groups: the basaltic andesitic and the andesite ones.
Abstract: Analytical data for Sr, Rb, Cs, Ba, Pb, rare earth elements, Y, Th, U, Zr, Hf, Sn, Nb, Mo, Ni, Co, V, Cr, Sc, Cu and major elements are reported for eocene volcanic rocks cropping out in the Kastamonu area, Pontic chain of Northern Turkey. SiO2% versus K2O% relationship shows that the analyzed samples belong to two major groups: the basaltic andesitic and the andesitic ones. High-K basaltic andesites and low-K andesites occur too. Although emplaced on continental type basement (the North Anatolian Crystalline Swell), the Pontic eocene volcanics show elemental abundances closely comparable with typical island arc calc-alkaline suites, e.g. low SiO2% range, low to moderate K2O% and large cations (Cs, Rb, Sr, Ba, Pb) contents and REE patterns with fractionated light and almost flat heavy REE patterns. ΣREE and highly charged cations (Th, U, Hf, Sn, Zr) are slightly higher than typical calc-alkaline values. Ferromagnesian elements show variable values. Within the basaltic andesite group the increase of K%, large cations, ΣREE, La/Yb ratio and high valency cations and the decrease of ferromagnesian element abundances with increasing SiO2% content indicate that the rock types making up this group developed by crystalliquid fractionation of olivine and clinopyroxene from a basic parent magma. Trace element concentration suggest that the andesite group was not derived by crystal-liquid fractionation processes from the basaltic andesites, but could represent a distinct group of rocks derived from a different parent magma.
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TL;DR: In this article, a data bank containing over 600 high quality trace element analyses of granites from known settings was used to demonstrate using ORG-normalized geochemical patterns and element-SiO2 plots that most of these granite groups exhibit distinctive trace element characteristics.
Abstract: Granites may be subdivided according to their intrusive settings into four main groups—ocean ridge granites (ORG), volcanic arc granites (VAG), within plate granites (WPG) and collision granites (COLG)—and the granites within each group may be further subdivided according to their precise settings and petrological characteristics. Using a data bank containing over 600 high quality trace element analyses of granites from known settings, it can be demonstrated using ORG-normalized geochemical patterns and element-SiO2 plots that most of these granite groups exhibit distinctive trace element characteristics. Discrimination of ORG, VAG, WPG and syn-COLG is most effective in Rb-Y-Nb and Rb-Yb-Ta space, particularly on projections of Y-Nb, Yb-Ta, Rb-(Y + Nb) and Rb—(Yb + Ta). Discrimination boundaries, though drawn empirically, can be shown by geochemical modelling to have a theoretical basis in the different petrogenetic histories of the various granite groups. Post-collision granites present the main problem of tectonic classification, since their characteristics depend on the thickness and composition of the lithosphere involved in the collision event and on the precise timing and location of magmatism. Provided they are coupled with a consideration of geological constraints, however, studies of trace element compositions in granites can clearly help in theelucidation of post-Archaean tectonic settings.
7,144 citations
TL;DR: In this paper, a table of mineral-liquid distribution coefficients for Ti, Zr, Y, and Nb for basic, intermediate and acid melt compositions were used to interpret variations of these elements, first in basalts and second during fractional crystallization from basic to acid magmas.
Abstract: Data from experimental runs, coexisting phases in ultramafic rocks and phenocryst-matrix pairs in volcanic rocks have been used to compile a table of mineral-liquid distribution coefficients for Ti, Zr, Y, and Nb for basic, intermediate and acid melt compositions. These values have then been used to interpret variations of these elements, first in basalts and second, during fractional crystallization from basic to acid magmas. For basalts, petrogenetic modelling of Zr/Y, Zr/Ti, and Zr/Nb ratios, when used in conjunction with REE, Cr and isotopic variations, suggests that: (1) the increase in Zr/Y ratio from mid-ocean ridge to within plate basalts and the low Zr/Nb ratios of alkalic basalts are due to (fluid controlled) source heterogeneities; (2) the low Zr and Zr/Y ratio of volcanic arc basalts results from high degree of partial melting of a depleted source; and (3) the high Zr and similar Zr/Y ratio of basalts from fast spreading relative to slow spreading ridges results from open-system fractional crystallization. Modelling of fractionation trends in more evolved rocks using Y-Zr, Ti-Zr and Nb-Zr diagrams highlights in particular the change in crystallizing mafic phases from island arcs (clinopyroxene-dominated) to Andean-type arcs (amphibole±biotite-dominated). These methods can be applied to altered lavas of unknown affinities to provide additional information on their genesis and eruptive environment.
2,680 citations
TL;DR: Agarwal et al. as mentioned in this paper presented a comprehensive geochemical data set for the most recent volcanics from the Mariana Islands, which provides new constraints on the timing and nature of fluxes from the subducting slab.
Abstract: We present a comprehensive geochemical data set for the most recent volcanics from the Mariana Islands, which provides new constraints on the timing and nature of fluxes from the subducting slab. The lavas display many features typical of island arc volcanics, with all samples showing large negative niobium anomalies and enrichments in alkaline earth elements and lead (e.g., high Ba/La and Pb/Ce). Importantly, many of these key ratios correlate with a large range in 238U excesses, (238U/230Th) = 0.97–1.56. Geochemical features show island to island variations; lavas from Guguan have the largest 238U-excesses, Pb/Ce and Ba/La ratios, while Agrigan lavas have small 238U excesses, the least radiogenic 143Nd/144Nd, and the largest negative cerium and niobium anomalies. These highly systematic variations enable two discrete slab additions to the subarc mantle to be identified. The geochemical features of the Agrigan lavas are most consistent with a dominant subducted sediment contribution. The added sedimentary component is not identical to bulk subducted sediment and notably shows a marked enrichment of Th relative to Nb. This is most readily explained by melt fractionation of the sediment with residual rutile and transfer of sedimentary material as a melt phase. For most of the highly incompatible elements, the sedimentary contribution dominates the total elemental budgets of the lavas. The characteristics best exemplified by the Guguan lavas are attributed to a slab-derived aqueous fluid phase, and Pb and Sr isotope compositions point toward the subducted, altered oceanic crust as a source of this fluid. Variable addition of the sedimentary component, but near-constant aqueous fluid flux along arc strike, can create the compositional trends observed in the Mariana lavas. High field strength element ratios (Ta/Nb and Zr/Nb) of the sediment poor Guguan lavas are higher than those of most mid-oceanic ridge basalts and suggest a highly depleted subarc mantle prior to any slab additions. The 238U-230Th systematics indicate >350 kyr between sediment and mantle melting but <30 kyr between slab dehydration and eruption of the lavas. This necessitates rapid magma migration rates and suggests that the aqueous fluid itself may trigger major mantle melting.
1,221 citations
TL;DR: In this article, a geodynamic evolution model was proposed to depict when and how the Indian continental lithospheric mantle started thrusting under Asia by involving rollback and breakoff of the subducted Neo-Tethyan slab followed by removal of the thickened Lhasa root.
1,196 citations
Cites background from "Geochemistry of eocene calc-alkalin..."
...Rock suite c Maitre (2002) and Peccerillo and Taylor (1976), respectively....
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TL;DR: In this paper, the authors used petrologic diagrams applied to analyses of volcanic rocks for construction of discriminant lines between rock series and provided coordinates for sufficient points to enable accurate plotting of the boundary lines within seven diagrams, viz.
1,150 citations
References
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TL;DR: A detailed assembly of the outlines of the continents around the North and central Atlantic, before the initial dispersion of Gondwanaland in Early Jurassic times, is presented in this paper.
Abstract: It is contended that the Late Triassic to present-day gross evolution of the Alpine system in the Mediterranean region has been the result of activity along an evolving network of accreting, transform, and subducting plate boundaries between the large stable cratons of Europe and Africa. A refined assembly of the outlines of the continents around the North and central Atlantic, before the initial dispersion of Gondwanaland in Early Jurassic times, is presented. By considering geologic facies, structural fabric, and paleomagnetic criteria, the smaller continental fragments now found within the Alpine system are restored to their proposed initial positions relative to each other in the reconstruction offered. The motion of the major plate of Africa relative to Europe, commencing with the initial continental fragmentation, is documented by analysis of the sea-floor spreading history of the Atlantic Ocean, with the assumption that plate accretion there has occurred between torsionally rigid lithospheric plates. By the computerized fitting of well-defined and well-dated key pairs of symmetric magnetic anomaly lineations back together by a series of finite rotations, the relative position of North America to both Europe and Africa has been determined for the following times: 180 m.y. (Toarcian Stage, Early Jurassic); 148 m.y. (Kimmeridgian Stage, Late Jurassic); 80 m.y. (Santonian Stage, Late Cretaceous); 63 m.y. (Danian Stage, Paleocene); 53 m.y. (Ypresian Stage, Eocene); and 9 m.y. (Tortonian Stage, Miocene). From these positions, a series of rotation poles presumed to describe the stepwise motion of Africa relative to Europe were computed. The motions of the smaller intervening microplates have been inferred from the style of tectonic deformation on their borders, and these motions have been constrained to satisfy both changes in paleo-latitude with time and progressive rotations relative to the large macroplates that can be deduced from paleomagnetic measurements. The evolution of Tethys does not involve a single simple plate boundary between Europe and Africa, as has been envisioned previously, but, instead, a constantly evolving mosaic of subsiding continental margins, migrating mid-oceanic ridges, transform faults, trenches, island arcs, and marginal seas (back-arc basins). The periods of passive-continental margin development are recognized by a transgressive facies of platform carbonate rocks and thick prisms of continental-rise type sedimentation; accreting ridges by ultramafic rocks, gabbro, pillow basalt, deep-sea pelagic ooze, and abyssal red clay of the ophiolite suite; trenches by a migrating series of progressively younger linear flysch troughs whose immature mineral composition reflects nearby andesitic and metamorphic source terrains; the arcs themselves by calc-alkaline volcanism and the intrusion of silicic to intermediate plutons; the polarities of these arcs by the direction of overthrust nappe sheets and gradients in the ratio of potash to silica in the extrusives; their orientation by paired belts of high T and P and high P-T metamorphics; and finally the spreading back-arc basins by outpourings of basaltic magmas and evidence of flipping Benioff planes. A compilation of eight phases or chapters in Atlantic spreading history are outlined, which are based on the recognition of discrete differences and (or) relative motion between the continents bordering the Atlantic. All of these changes are reflected in the Tethys by reorganizations of the intervening plate boundaries and, we believe, are most explicitly recorded in the deformational history of the subducting zones. A montage of geometrically assembled plate-boundary interpretations are pictorially displayed as time-lapse frames of the evolving Alpine system. The montage begins with the Late Triassic (pre-Atlantic) setting of the Tethys 1 Ocean and extends to the present through nine phases of Tethyan history. Each phase is recognized on the basis of the age of intrusion and extrusion of basic lavas in ophiolite complexes, which mark the creation of new oceanic areas by both axial accretion in rift valleys of mid-oceanic ridges between rigid plates or by a more uncertain type of spreading in basins behind active island arcs. All the schemes presented are best estimates of the gross geometrical arrangements at discrete time intervals and should be treated as merely educated guesses. Despite the fact that we only have rigorous constraints for the relative positions of the nondeformed forelands of Europe and Africa, our models nevertheless imply that the motions of the larger plates will, by and large, dictate the general behavior of the smaller microplates through the particular styles of deformation set up along the adjoining plate boundaries. The Tethys 1 Ocean, located between Africa and Europe in Triassic times, has been almost entirely swallowed up in subduction zones of the Major Caucasus Mountains along its former northern margin and in similar zones of the Pontides and Minor Caucasus along its southern margin. The only remnants of Tethys 1 are the areas of oceanic crust in the Black and South Caspian Seas. There is considerable evidence to suggest that the Tethys 1 Ocean had an actively spreading ridge. Some tens of millions of years prior to the opening of the central North Atlantic, a branch of this ridge system entered into the Vardar Zone of eastern Greece and broke off fragments of northeast North Africa to initiate the development of the present-day Ionian and Levantine Basins of the eastern Mediterranean. Additional fragments (the Moroccan and Oranaise Meseta) were ruptured from northwest Africa following its separation from North America. The intervening Jurassic Atlas, seaway developed along an accreting plate boundary extending from the eastern Tethys to the crest of the embryonic Mid-Atlantic Ridge where it formed a migrating triple junction whose trace, we believe, follows the trend of the New England seamount chain. The western Mediterranean basins of the Alboran, Balearic, and Tyrrhenian Seas are very much younger, being initially opened in the early Miocene as a string of back-arc marginal seas behind the developing Apennine, Tel Atlas, and Rif suture zone that today marks the sites of subduction of Jurassic and Lower Cretaceous oceanic crust. The contemporary Alpine system displays a spectrum of stages in the building of mountain belts. Embryonic nappes within the Mediterranean Ridge in proximity to melange zones of the inner wall of the Hellenic Trench are, perhaps, signs of the initial deformation of sedimentary passengers on oceanic crust arriving at a subduction zone. Total closure of an ocean followed by the partial consumption of a passive continental margin leads to events such as the tectonic emplacement of crystalline basement nappes of the European “chaine calcaire” onto northwest Africa. Arc-continent collisions of this type which have then been succeeded by total destruction of marginal back-arc basins are recognizable in the Hellenides and Pontides. There are, as well, collisions that have not involved the disappearance of large oceanic areas; these are most apparent in the particular tectonic style of the Pyrenees and High Atlas Mountains.
1,538 citations
TL;DR: In this paper, solid-liquid partition coefficients between phenocrysts and the host lavas have been measured for rare-earth elements by an isotope dilution technique and the consistency of much of the data suggests that most of the phenocryst crystallized under equilibrium, or quasi-equilibrium, conditions.
720 citations
TL;DR: In this paper, the composition of island-arc volcanic rocks in relation to their geographic and stratigraphic relations is discussed and the differences in composition between volcanic rocks and those in continental margins are pointed out.
Abstract: The composition of recent island-arc volcanic rocks in relation to their geographic and stratigraphic relations is discussed. The differences in composition between volcanic rocks and those in continental margins are pointed out. Trace elements and major elements are shown to suggest a continuous gradational sequence from tholeiites through calc-alkaline rocks to shoshonites.
463 citations
"Geochemistry of eocene calc-alkalin..." refers background or result in this paper
...The basaltic andesites have Rb, Ba and Sr averages close to the values of the basic members of the island arc calc-alkaline series given by Jakeg and White ([ 18 ], Table 2b)....
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...Th and U averages are slightly higher than the values given by Jakeg and White [ 18 ] for average calc-alkaline rocks....
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...All the high valency cations, as already pointed out, have high abundances compared to average andesitic values [9, 18 ] at any SiO2 content....
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TL;DR: The island arc tholeiitic series as mentioned in this paper is the most dominant in many western Pacific and Atlantic Island arcs and represents the earliest stages in arc evolution. But it is chemically inappropriate to call many of the rocks in island arcs calc-alkaline and they suggest they be known as the "island arc thoeitic series" and they differ from normal thoeiitic features by having a higher percentage of intermediate and acid members and too little normative olivine, for example, to have been in equilibrium with peridotite.
455 citations
TL;DR: In this paper, rare earth, alkali and alkaline earth elements content of phenocrysts and acidic igneous magma are found in igneous coal and igneous rock.
314 citations
"Geochemistry of eocene calc-alkalin..." refers background in this paper
...Since plagioclase is the only mineral which is believed to produce significant Eu anomalies in the rocks [16, 17 ] it can be inferred that separation and accumulation of plagioclase has been important in the genesis of several members of the Kastamonu series....
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