Geochemistry of trace metals in the Gironde estuary
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...A Cd mid-estuary maximum has also been observed in other estuaries (ElbazPoulichet et al., 1987; Kraepiel et al., 1997)....
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...For instance, the range of Zn:Cd ratios for Gironde estuary is 40–60 (Kraepiel et al., 1997) whereas for Scheldt estuary is 38–308 (Duinker et al., 1982)....
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...A large mid-salinity maximum in dissolved Cd concentrations is a typical feature of many estuaries (ElbazPoulichet et al., 1996; Kraepiel et al., 1997; Zwolsman et al., 1997)....
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"Geochemistry of trace metals in the..." refers background or result in this paper
...As noted above, the large fraction of the total dissolved Fe that is actually colloidal precipitates at low salinity (S Sholkovitz, 1976; Figueres et al., 1978)....
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...This behavior of Fe undoubtedly reflects a loss of colloidal iron through coagulation, as noted by previous authors ( Sholkovitz, 1976; Figueres et al., 1978)....
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...Further, dissolved Cu is usually considered dominated by organic complexes in estuaries as in all natural waters (e.g., Coale and Bruland, 1988; Dai et al., 1995)....
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...This is a surprising result since there is now much evidence showing that Cd and Zn are usually bound to strong organic ligands, at least in seawater (see for example Bruland, 1989, 1992 )....
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