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Journal ArticleDOI

Geometries and materials for subwavelength surface plasmon modes.

TL;DR: In this paper, the authors show that a metal-insulator-metal geometry is necessary and sufficient condition for subwavelength confinement of the optical mode, and the resulting trade-off between propagation and confinement for surface plasmons is discussed.
Abstract: Plasmonic waveguides can guide light along metal-dielectric interfaces with propagating wave vectors of greater magnitude than are available in free space and hence with propagating wavelengths shorter than those in vacuum. This is a necessary, rather than sufficient, condition for subwavelength confinement of the optical mode. By use of the reflection pole method, the two-dimensional modal solutions for single planar waveguides as well as adjacent waveguide systems are solved. We demonstrate that, to achieve subwavelength pitches, a metal-insulator-metal geometry is required with higher confinement factors and smaller spatial extent than conventional insulator-metal-insulator structures. The resulting trade-off between propagation and confinement for surface plasmons is discussed, and optimization by materials selection is described.

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Citations
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Journal ArticleDOI
TL;DR: Recent advances at the intersection of plasmonics and photovoltaics are surveyed and an outlook on the future of solar cells based on these principles is offered.
Abstract: The emerging field of plasmonics has yielded methods for guiding and localizing light at the nanoscale, well below the scale of the wavelength of light in free space. Now plasmonics researchers are turning their attention to photovoltaics, where design approaches based on plasmonics can be used to improve absorption in photovoltaic devices, permitting a considerable reduction in the physical thickness of solar photovoltaic absorber layers, and yielding new options for solar-cell design. In this review, we survey recent advances at the intersection of plasmonics and photovoltaics and offer an outlook on the future of solar cells based on these principles.

8,028 citations

Book
15 May 2007
TL;DR: In this paper, the authors discuss the role of surface plasmon polaritons at metal/insulator interfaces and their application in the propagation of surfaceplasmon waveguides.
Abstract: Fundamentals of Plasmonics.- Electromagnetics of Metals.- Surface Plasmon Polaritons at Metal / Insulator Interfaces.- Excitation of Surface Plasmon Polaritons at Planar Interfaces.- Imaging Surface Plasmon Polariton Propagation.- Localized Surface Plasmons.- Electromagnetic Surface Modes at Low Frequencies.- Applications.- Plasmon Waveguides.- Transmission of Radiation Through Apertures and Films.- Enhancement of Emissive Processes and Nonlinearities.- Spectroscopy and Sensing.- Metamaterials and Imaging with Surface Plasmon Polaritons.- Concluding Remarks.

7,238 citations

Journal ArticleDOI
TL;DR: In plasmonics, the metal nanostructures can serve as antennas to convert light into localized electric fields (E-fields) or as waveguides to route light to desired locations with nanometer precision through a strong interaction between incident light and free electrons in the nanostructure.
Abstract: Coinage metals, such as Au, Ag, and Cu, have been important materials throughout history.1 While in ancient cultures they were admired primarily for their ability to reflect light, their applications have become far more sophisticated with our increased understanding and control of the atomic world. Today, these metals are widely used in electronics, catalysis, and as structural materials, but when they are fashioned into structures with nanometer-sized dimensions, they also become enablers for a completely different set of applications that involve light. These new applications go far beyond merely reflecting light, and have renewed our interest in maneuvering the interactions between metals and light in a field known as plasmonics.2–6 In plasmonics, the metal nanostructures can serve as antennas to convert light into localized electric fields (E-fields) or as waveguides to route light to desired locations with nanometer precision. These applications are made possible through a strong interaction between incident light and free electrons in the nanostructures. With a tight control over the nanostructures in terms of size and shape, light can be effectively manipulated and controlled with unprecedented accuracy.3,7 While many new technologies stand to be realized from plasmonics, with notable examples including superlenses,8 invisible cloaks,9 and quantum computing,10,11 conventional technologies like microprocessors and photovoltaic devices could also be made significantly faster and more efficient with the integration of plasmonic nanostructures.12–15 Of the metals, Ag has probably played the most important role in the development of plasmonics, and its unique properties make it well-suited for most of the next-generation plasmonic technologies.16–18 1.1. What is Plasmonics? Plasmonics is related to the localization, guiding, and manipulation of electromagnetic waves beyond the diffraction limit and down to the nanometer length scale.4,6 The key component of plasmonics is a metal, because it supports surface plasmon polariton modes (indicated as surface plasmons or SPs throughout this review), which are electromagnetic waves coupled to the collective oscillations of free electrons in the metal. While there are a rich variety of plasmonic metal nanostructures, they can be differentiated based on the plasmonic modes they support: localized surface plasmons (LSPs) or propagating surface plasmons (PSPs).5,19 In LSPs, the time-varying electric field associated with the light (Eo) exerts a force on the gas of negatively charged electrons in the conduction band of the metal and drives them to oscillate collectively. At a certain excitation frequency (w), this oscillation will be in resonance with the incident light, resulting in a strong oscillation of the surface electrons, commonly known as a localized surface plasmon resonance (LSPR) mode.20 This phenomenon is illustrated in Figure 1A. Structures that support LSPRs experience a uniform Eo when excited by light as their dimensions are much smaller than the wavelength of the light. Figure 1 Schematic illustration of the two types of plasmonic nanostructures discussed in this article as excited by the electric field (Eo) of incident light with wavevector (k). In (A) the nanostructure is smaller than the wavelength of light and the free electrons ... In contrast, PSPs are supported by structures that have at least one dimension that approaches the excitation wavelength, as shown in Figure 1B.4 In this case, the Eo is not uniform across the structure and other effects must be considered. In such a structure, like a nanowire for example, SPs propagate back and forth between the ends of the structure. This can be described as a Fabry-Perot resonator with resonance condition l=nλsp, where l is the length of the nanowire, n is an integer, and λsp is the wavelength of the PSP mode.21,22 Reflection from the ends of the structure must also be considered, which can change the phase and resonant length. Propagation lengths can be in the tens of micrometers (for nanowires) and the PSP waves can be manipulated by controlling the geometrical parameters of the structure.23

2,421 citations

Journal ArticleDOI
TL;DR: The design and realization of metallic nanostructures with tunable plasmon resonances has been greatly advanced by combining a wealth of nanofabrication techniques with advances in computational electromagnetic design.
Abstract: The design and realization of metallic nanostructures with tunable plasmon resonances has been greatly advanced by combining a wealth of nanofabrication techniques with advances in computational electromagnetic design. Plasmonics — a rapidly emerging subdiscipline of nanophotonics — is aimed at exploiting both localized and propagating surface plasmons for technologically important applications, specifically in sensing and waveguiding. Here we present a brief overview of this rapidly growing research field.

2,090 citations

Journal ArticleDOI
10 Jun 2009
TL;DR: The current performance and future demands of interconnects to and on silicon chips are examined and the requirements for optoelectronic and optical devices are project if optics is to solve the major problems of interConnects for future high-performance silicon chips.
Abstract: We examine the current performance and future demands of interconnects to and on silicon chips. We compare electrical and optical interconnects and project the requirements for optoelectronic and optical devices if optics is to solve the major problems of interconnects for future high-performance silicon chips. Optics has potential benefits in interconnect density, energy, and timing. The necessity of low interconnect energy imposes low limits especially on the energy of the optical output devices, with a ~ 10 fJ/bit device energy target emerging. Some optical modulators and radical laser approaches may meet this requirement. Low (e.g., a few femtofarads or less) photodetector capacitance is important. Very compact wavelength splitters are essential for connecting the information to fibers. Dense waveguides are necessary on-chip or on boards for guided wave optical approaches, especially if very high clock rates or dense wavelength-division multiplexing (WDM) is to be avoided. Free-space optics potentially can handle the necessary bandwidths even without fast clocks or WDM. With such technology, however, optics may enable the continued scaling of interconnect capacity required by future chips.

1,959 citations

References
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Book
12 Jul 1985
TL;DR: In this paper, E.D. Palik and R.R. Potter, Basic Parameters for Measuring Optical Properties, and W.W.Hunter, Measurement of Optical Constants in the Vacuum Ultraviolet Spectral Region.
Abstract: VOLUME ONE: Determination of Optical Constants: E.D. Palik, Introductory Remarks. R.F. Potter, Basic Parameters for Measuring Optical Properties. D.Y. Smith, Dispersion Theory, Sum Rules, and Their Application to the Analysis of Optical Data. W.R. Hunter, Measurement of Optical Constants in the Vacuum Ultraviolet Spectral Region. D.E. Aspnes, The Accurate Determination of Optical Properties by Ellipsometry. J. Shamir, Interferometric Methods for the Determination of Thin-Film Parameters. P.A. Temple, Thin-Film Absorplance Measurements Using Laser Colorimetry. G.J. Simonis, Complex Index of Refraction Measurements of Near-Millimeter Wavelengths. B. Jensen, The Quantum Extension of the Drude--Zener Theory in Polar Semiconductors. D.W. Lynch, Interband Absorption--Mechanisms and Interpretation. S.S. Mitra, Optical Properties of Nonmetallic Solids for Photon Energies below the Fundamental Band Gap. Critiques--Metals: D.W. Lynch and W.R. Hunter, Comments of the Optical Constants of Metals and an Introduction to the Data for Several Metals. D.Y. Smith, E. Shiles, and M. Inokuti, The Optical Properties of Metallic Aluminum. Critiques--Semiconductors: E.D. Palik, Cadium Telluride (CdTe). E.D. Palik, Gallium Arsenide (GaAs). A. Borghesi and G. Guizzetti, Gallium Phosphide (GaP). R.F. Potter, Germanium (Ge). E.D. Palik and R.T. Holm, Indium Arsenide (InAs). R.T. Holm, Indium Antimonide (InSb). O.J. Glembocki and H. Piller, Indium Phosphide (InP). G. Bauer and H. Krenn, Lead Selenide (PbSe). G. Guizzetti and A. Borghesi, Lead Sulfide (PbS). G. Bauer and H. Krenn, Lead Telluride (PbTe). D.F. Edwards, Silicon (Si). H. Piller, Silicon (Amorphous) (-Si). W.J. Choyke and E.D. Palik, Silicon Carbide (SiC). E.D. Palik and A. Addamiano, Zinc Sulfide (ZnS). Critiques--Insulators: D.J. Treacy, Arsenic Selenide (As 2 gt Se 3 gt ). D.J. Treacy, Arsenic Sulfide (As 2 gt S 3 gt ). D.F. Edwards and H.R. Philipp, Cubic Carbon (Diamond). E.D. Palik and W.R. Hunter, Litium Fluoride (LiF). E.D. Palik, Lithium Niobote (LiNbO 3 gt ). E.D. Palik, Potassium Chloride (KCl). H.R. Philipp, Silicon Dioxide (SiO 2 gt ), Type ( (Crystalline). H.R. Philipp, Silicon Dioxide (SiO 2 gt ) (Glass). gt H.R. Philipp, Silicon Monoxide (SiO) (Noncrystalline). H.R. Philipp, Silicon Nitride (Si 3 gt N 4 gt ) (Noncrystalline). J.E. Eldridge and E.D. Palik, Sodium Chloride (NaCl). M.W. Ribarsky, Titanium Dioxide (TiO 2 gt ) (Rutile).

17,491 citations

Journal ArticleDOI
14 Aug 2003-Nature
TL;DR: By altering the structure of a metal's surface, the properties of surface plasmons—in particular their interaction with light—can be tailored, which could lead to miniaturized photonic circuits with length scales that are much smaller than those currently achieved.
Abstract: Surface plasmons are waves that propagate along the surface of a conductor. By altering the structure of a metal's surface, the properties of surface plasmons--in particular their interaction with light--can be tailored, which offers the potential for developing new types of photonic device. This could lead to miniaturized photonic circuits with length scales that are much smaller than those currently achieved. Surface plasmons are being explored for their potential in subwavelength optics, data storage, light generation, microscopy and bio-photonics.

10,689 citations

Journal ArticleDOI
TL;DR: Observations of electromagnetic energy transport from a localized subwavelength source to a localized detector over distances of about 0.5 μm in plasmon waveguides consisting of closely spaced silver rods are presented.
Abstract: Achieving control of light-material interactions for photonic device applications at nanoscale dimensions will require structures that guide electromagnetic energy with a lateral mode confinement below the diffraction limit of light. This cannot be achieved by using conventional waveguides or photonic crystals. It has been suggested that electromagnetic energy can be guided below the diffraction limit along chains of closely spaced metal nanoparticles that convert the optical mode into non-radiating surface plasmons. A variety of methods such as electron beam lithography and self-assembly have been used to construct metal nanoparticle plasmon waveguides. However, all investigations of the optical properties of these waveguides have so far been confined to collective excitations and direct experimental evidence for energy transport along plasmon waveguides has proved elusive. Here we present observations of electromagnetic energy transport from a localized subwavelength source to a localized detector over distances of about 0.5 μm in plasmon waveguides consisting of closely spaced silver rods. The waveguides are excited by the tip of a near-field scanning optical microscope, and energy transport is probed by using fluorescent nanospheres.

2,305 citations

Journal ArticleDOI
TL;DR: In this article, the dispersion relations for surface plasma oscillations in normal metals are investigated for single-and multiple-film systems taking retardation effects into account, and two types of possible modes of oscillation are found.
Abstract: The dispersion relations for surface plasma oscillations in normal metals are investigated for single- and multiple-film systems taking retardation effects into account. The simple dielectric function $\ensuremath{\epsilon}(\ensuremath{\omega})=1\ensuremath{-}\frac{{{\ensuremath{\omega}}_{p}}^{2}}{{\ensuremath{\omega}}^{2}}$ is found to be adequate for the high-frequency region in which oscillations remain undamped. Two types of possible modes of oscillation are found. One type corresponds to dispersion relations which behave linearly for not-so-high frequency, with a phase velocity always smaller than the velocity of light in the dielectric, but at least ten times larger than the Fermi velocity, while the other type consists of high-frequency modes ($\ensuremath{\omega}\ensuremath{\sim}{\ensuremath{\omega}}_{p}$). The role of these oscillations in the problem of transition radiation is reexamined. In the case of a thin metal film, a new interpretation is proposed for the peak observed in the transition radiation spectrum. Finally, the work is extended to superconducting metals where, in the frequency range $\ensuremath{\hbar}\ensuremath{\omega}l2\ensuremath{\Delta}$ ($2\ensuremath{\Delta}$ is the superconducting energy gap), we have justified the use of a dielectric function of the same functional form as given above but with ${{\ensuremath{\omega}}_{p}}^{2}$ replaced by an almost frequency-independent quantity ${{\ensuremath{\omega}}_{\mathrm{ps}}}^{2}$, where ${\ensuremath{\omega}}_{\mathrm{ps}}=\frac{c}{{\ensuremath{\lambda}}_{\mathrm{ps}}}$ and ${\ensuremath{\lambda}}_{\mathrm{ps}}$ is the actual penetration depth. In this frequency range, the oscillations are essentially undamped and play an important role in the electromagnetic properties of the multiple-film systems, and particularly when the systems exhibit the ac Josephson effect.

1,258 citations

Journal ArticleDOI
TL;DR: The idea of a subwavelength-sized light guide represented by a linear chain of spherical metal nanoparticles in which light is transmitted by electrodynamic interparticle coupling may be useful for subwa wavelength transmission lines within integrated optics circuits and for near-field optical microscopy.
Abstract: We propose the idea of a subwavelength-sized light guide represented by a linear chain of spherical metal nanoparticles in which light is transmitted by electrodynamic interparticle coupling. The light-transport properties of this system are investigated by use of model calculations based on generalized Mie theory. Considering Ag particles of 50-nm diameter, we find optimum guiding conditions for an interparticle spacing of 25 nm, and a corresponding 1/e signal-damping length of 900 nm is evaluated. The proposed principle of optical energy transport may be useful for subwavelength transmission lines within integrated optics circuits and for near-field optical microscopy.

1,024 citations