Giant magnetic-field-induced strain in NiMnGa seven-layered martensitic phase
TL;DR: In this paper, a magnetic-field-induced strain of about 9.5% was observed at ambient temperature in a magnetic field of less than 1 T in NiMnGa orthorhombic seven-layered martensitic phase.
Abstract: Giant magnetic-field-induced strain of about 9.5% was observed at ambient temperature in a magnetic field of less than 1 T in NiMnGa orthorhombic seven-layered martensitic phase. The strain proved to be caused by magnetic-field-controlled twin boundary motion. According to an analysis of x-ray diffraction data, the crystal structure of this phase is nearly orthorhombic, having lattice parameters a=0.619 nm, b=0.580 nm, and c=0.553 nm (in cubic parent phase coordinates) at ambient temperature. Seven-layer shuffling-type modulation along the (110)[110]p system was recorded. The results of mechanical tests and magnetic anisotropy property measurements are also reported.
Citations
More filters
IBM1
TL;DR: Heusler compounds as discussed by the authors are a remarkable class of intermetallic materials with 1:1:1 or 2:1-1 composition comprising more than 1500 members, and their properties can easily be predicted by the valence electron count.
1,675 citations
TL;DR: The magnetic-field-induced shape recovery of a compressively deformed NiCoMnIn alloy is reported, attributing this deformation behaviour to a reverse transformation from the antiferromagnetic (or paramagnetic) martensitic to the ferromagnetic parent phase in the Ni45Co5Mn36.7In13.3 single crystal.
Abstract: Large magnetic-field-induced strains1 have been observed in Heusler alloys with a body-centred cubic ordered structure and have been explained by the rearrangement of martensite structural variants due to an external magnetic field1,2,3. These materials have attracted considerable attention as potential magnetic actuator materials. Here we report the magnetic-field-induced shape recovery of a compressively deformed NiCoMnIn alloy. Stresses of over 100 MPa are generated in the material on the application of a magnetic field of 70 kOe; such stress levels are approximately 50 times larger than that generated in a previous ferromagnetic shape-memory alloy4. We observed 3 per cent deformation and almost full recovery of the original shape of the alloy. We attribute this deformation behaviour to a reverse transformation from the antiferromagnetic (or paramagnetic) martensitic to the ferromagnetic parent phase at 298 K in the Ni45Co5Mn36.7In13.3 single crystal.
1,581 citations
TL;DR: In this article, the authors examined the potential of artificial muscle-like materials for undersea applications, including dielectric elastomers, heat-memory alloys, ionic polymer/metal composites, conducting polymers and carbon nanotubes.
Abstract: The increasing understanding of the advantages offered by fish and insect-like locomotion is creating a demand for muscle-like materials capable of mimicking nature's mechanisms. Actuator materials that employ voltage, field, light, or temperature driven dimensional changes to produce forces and displacements are suggesting new approaches to propulsion and maneuverability. Fundamental properties of these new materials are presented, and examples of potential undersea applications are examined in order to assist those involved in device design and in actuator research to evaluate the current status and the developing potential of these artificial muscle technologies. Technologies described are based on newly explored materials developed over the past decade, and also on older materials whose properties are not widely known. The materials are dielectric elastomers, ferroelectric polymers, liquid crystal elastomers, thermal and ferroelectric shape memory alloys, ionic polymer/metal composites, conducting polymers, and carbon nanotubes. Relative merits and challenges associated with the artificial muscle technologies are elucidated in two case studies. A summary table provides a quick guide to all technologies that are discussed.
968 citations
TL;DR: The magnetocaloric effects of Ni-Mn-based Heusler alloys are surveyed and their relation with the magnetic shape-memory and magnetic superelasticity reported in these materials are discussed.
Abstract: Magnetic Heusler alloys which undergo a martensitic transition display interesting functional properties. In the present review, we survey the magnetocaloric effects of Ni-Mn-based Heusler alloys and discuss their relation with the magnetic shape-memory and magnetic superelasticity reported in these materials. We show that all these effects are a consequence of a strong coupling between structure and magnetism which enables a magnetic field to rearrange martensitic variants as well as to provide the possibility to induce the martensitic transition. These two features are respectively controlled by the magnetic anisotropy of the martensitic phase and by the difference in magnetic moments between the structural phases. The relevance of each of these contributions to the magnetocaloric properties is analysed.
886 citations
TL;DR: In this paper, the magnetic and structural transformations in the Heusler-based system were studied in the composition range $0.05, 0.16, and 0.25, respectively, and the magnetic coupling in both austenitic and martensitic states is ferromagnetic.
Abstract: The magnetic and structural transformations in the Heusler-based system ${\mathrm{Ni}}_{0.50}{\mathrm{Mn}}_{0.50\ensuremath{-}x}{\mathrm{In}}_{x}$ are studied in the composition range $0.05\ensuremath{\leqslant}x\ensuremath{\leqslant}0.25$. While the cubic phase is preserved in the range $0.165\ensuremath{\leqslant}x\ensuremath{\leqslant}0.25$, we find the presence of martensitic transformations in alloys with $x\ensuremath{\leqslant}0.16$. In a critical composition range $0.15\ensuremath{\leqslant}x\ensuremath{\leqslant}0.16$, the magnetic coupling in both austenitic and martensitic states is ferromagnetic. Magnetic field-induced structural transitions are also found in the $x=0.16$ alloy, whereby the structural transition temperature shifts by $42\phantom{\rule{0.3em}{0ex}}\mathrm{K}$ in a field of $50\phantom{\rule{0.3em}{0ex}}\mathrm{kOe}$.
563 citations
References
More filters
TL;DR: In this paper, the superelastic motion of twin boundaries in the martensitic phase of Ni2MnGa with magnetic fields of 8 kOe applied at 265 K was found to be associated with the staining.
Abstract: Strains of nearly 0.2% have been induced along [001] in unstressed crystals of Ni2MnGa with magnetic fields of 8 kOe applied at 265 K. These stains are associated with the superelastic motion of twin boundaries in the martensitic phase that is stable below about 274 K.
2,442 citations
TL;DR: In this paper, a simple model accounts quantitatively for the dependence of strain on magnetic field and external stress using as input parameters only measured quantities, and the strain versus field curves exhibit appreciable hysteresis associated with the motion of the twin boundaries.
Abstract: Field-induced strains of 6% are reported in ferromagnetic Ni–Mn–Ga martensites at room temperature. The strains are the result of twin boundary motion driven largely by the Zeeman energy difference across the twin boundary. The strain measured parallel to the applied magnetic field is negative in the sample/field geometry used here. The strain saturates in fields of order 400 kA/m and is blocked by a compressive stress of order 2 MPa applied orthogonal to the magnetic field. The strain versus field curves exhibit appreciable hysteresis associated with the motion of the twin boundaries. A simple model accounts quantitatively for the dependence of strain on magnetic field and external stress using as input parameters only measured quantities.
1,035 citations
TL;DR: In this article, a general strategy for inducing magnetostriction in ferromagnetic martensitic materials is described, and an analysis of domain redistribution caused by a magnetic field is given.
Abstract: A general strategy is described for inducing magnetostriction in ferromagnetic martensitic materials. An analysis of domain redistribution caused by a magnetic field is given, and certain relations...
669 citations
TL;DR: In this paper, a simple phenomenological model for the magnetization process and field-induced strain by twin-boundary and phaseboundary motion is proposed for both the strong and weak anisotropy cases.
Abstract: The large magnetic-field-induced strains observed in martensitic phases based on Ni2MnGa and in other magnetic shape memory alloys are believed to arise from a process of twin-boundary motion rather than magnetostriction. The dependence of strain on magnetization, e(M), generally shows a large component that is linear (rather than quadratic) in M below saturation (quadratic dependence being typical of magnetostrictive strain). A simple phenomenological model for the magnetization process and field-induced strain by twin-boundary and phase-boundary motion is proposed for both the strong and weak anisotropy cases. The model is shown to account for the nearly linear dependence of strain on magnetization in the martensitic phases of these materials. It shows the field dependence of the magnetization and strain to be functions of an effective stiffness constant, C, the transformation strain, e0, and the magnetic anisotropy of the martensitic phase, Ku, through two reduced field parameters, he=MsH/Ce02 and ha=M...
632 citations
TL;DR: The crystal structures of the different martensitic phases observed in a wide variety of Ni-Mn-Ga alloy compositions have been studied in detail as discussed by the authors, and two approaches taken from the literature are analysed and discussed.
606 citations