High-Performance All-Solid-State Lithium–Sulfur Batteries Enabled by Amorphous Sulfur-Coated Reduced Graphene Oxide Cathodes
Xiayin Yao,Ning Huang,Ning Huang,Fudong Han,Qiang Zhang,Hongli Wan,Jean Pierre Mwizerwa,Chunsheng Wang,Xiaoxiong Xu +8 more
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TLDR
In this paper, a conformal coating of 2 nm sulfur (S) onto reduced graphene oxide (rGO) nanocomposite is proposed to reduce the interface resistance and stress/strain of Li-S batteries.Abstract:
Safety and the polysulfide shuttle reaction are two major challenges for liquid electrolyte lithium–sulfur (Li–S) batteries. Although use of solid-state electrolytes can overcome these two challenges, it also brings new challenges by increasing the interface resistance and stress/strain. In this work, the interface resistance and stress/strain of sulfur cathodes are significantly reduced by conformal coating ≈2 nm sulfur (S) onto reduced graphene oxide (rGO). An Li–S full cell consisting of an rGO@S-Li10GeP2S12-acetylene black (AB) composite cathode is evaluated. At 60 °C, the all-solid-state Li–S cell demonstrates a similar electrochemical performance as in liquid organic electrolyte, with high rate capacities of 1525.6, 1384.5, 1336.3, 903.2, 502.6, and 204.7 mA h g−1 at 0.05, 0.1, 0.5, 1.0, 2.0, and 5.0 C, respectively. It can maintain a high and reversible capacity of 830 mA h g−1 at 1.0 C for 750 cycles. The uniform distribution of the rGO@S nanocomposite in the Li10GeP2S12-AB matrix generates uniform volume changes during lithiation/delithiation, significantly reducing the stress/strain, thus extending the cycle life. Minimization of the stress/strain of solid cells is the key for a long cycle life of all-solid-state Li–S batteries.read more
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Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
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Practical Challenges and Future Perspectives of All-Solid-State Lithium-Metal Batteries
TL;DR: In this paper, the fundamental understandings and technological innovations in lithium-ion batteries are essential for delivering high energy density, stable cyclability, and cost-effective energy storages with the growing demands in the applications of electrical vehicles and smart grid.
Journal ArticleDOI
Revisiting the Role of Polysulfides in Lithium-Sulfur Batteries.
TL;DR: The key roles of polysulfides are discussed, with regard to their status, behavior, and their corresponding impact on the lithium-sulfur system.
Journal ArticleDOI
Lithium-Sulfur Batteries under Lean Electrolyte Conditions: Challenges and Opportunities.
TL;DR: In this article, the impact of the electrolyte/sulfur ratio on the actual energy density and the economic cost of Li-S batteries is addressed, and challenges and recent progress are presented in terms of the sulfur electrochemical processes: the dissolution-precipitation conversion and the solid-solid multi-phasic transition.
Journal ArticleDOI
Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries
Kern Ho Park,Qiang Bai,Dong Hyeon Kim,Dong Hyeon Kim,Dae Yang Oh,Dae Yang Oh,Yizhou Zhu,Yifei Mo,Yoon Seok Jung +8 more
TL;DR: In this paper, Q.H.P. and Q.J.B. contributed equally to this work and were supported by the Technology Development Program to Solve Climate Changes and by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT a Future Planning.
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